Low-toxicity solar concentrator systems represent an important challenge for outstanding photovoltaic (PV) applications. Particularly, multiplexed holographic lenses (MHL) as Holographic Solar Concentrators (HSC) provide insight into promising possibilities for Building-Integrated Concentrating PVs. This technology does not affect crucial ecosystems, and can convert buildings from energy consumers into energy suppliers. They can be used in windows, roofs, or walls, and a high diffraction efficiency and wide acceptance angle are desired. In this work, we presented several designs of MHL of low spatial frequency 525 lines mm⁻¹, based on a low-toxicity photopolymer and supported on a window glass. The average diffraction efficiency of these HSC was evaluated at 633 nm, whereas the acceptance angle was evaluated by measuring the short-circuit current under solar illumination at different incident angles. Versatile and high-efficiency holographic elements have been used to concentrate sunlight from different relative positions during the day, avoiding the need for expensive tracking systems. To the best of our knowledge, this is the best trade-off between high diffraction efficiency (85 % ) and wide acceptance angle (104^∘) in a low-toxicity holographic solar concentrator.

Diffractive optical elements (DOEs) are essential components in optical and photonic technologies, motivating the need for rapid mass production with high-precision fabrication methods. Photopolymers are particularly attractive for DOEs production because their optical phase can be modified via both surface and refractive index modulations. In this work, we report the fabrication of DOEs on PVA/AA photopolymers using ultrafast laser direct writing. By combining surface topography measurements with a phase depth model, we extract the surface and bulk phase depth contributions and demonstrate a transition from surface-dominated modulation at 1 kHz to bulk refractive index modification under cumulative conditions at 100 kHz. These outcomes highlight ultrafast laser direct writing as a powerful, rapid and controlled method for the high-quality and rapid fabrication of DOEs.

This work introduces a novel computational approach based on Principal Component Analysis (PCA) for dimensionality reduction of the solution space in optimisation problems with known linear interdependencies among solution variables. By creating synthetic datasets with deliberately engineered properties and applying PCA, the solution space’s remapping significantly reduces its dimensionality, leading to faster computation and more robust convergence in optimisation processes. We demonstrate this method by integrating it with a Genetic Algorithm (GA) for solving the optimal director distribution in liquid crystal (LC) devices, specifically addressing 2D and complex 3D spatial light modulator (SLM) structures such as twisted nematic liquid crystals (TN-LC) and parallel-aligned liquid crystal on silicon (PA-LCoS), respectively. The phase profiles obtained from the director vector distributions for horizontal and vertical high-frequency binary phase gratings closely match the theoretical values derived from minimising the traditional elastic Frank–Oseen functional via Euler–Lagrange equations. Beyond this specific application, our method offers a general framework for reducing computational complexity in optimisation problems by directly reducing the dimensionality of the solution space. This approach is applicable across various optimisation scenarios with well-known linear interdependencies among solution variables, enabling significant reductions in computational costs and improvements in robustness and convergence.

Multidisciplinary technologies are truly driving major transformations in industries, innovating to become more efficient. The need for more efficient renewable energy systems, such as solar energy, has recently been addressed with the innovation of using holographic photonic devices to avoid solar tracking devices as much as possible. In this work, a multiplexed holographic device is created and characterized for use in front of a photocell, thereby eliminating the need for tracking systems due to its wide acceptance angle and high diffraction efficiency. Commercial Bayfol^® HX121 photopolymer was used as the holographic recording material to manufacture holograms, achieving high performance and facilitating the industrial scaling of this technique. Results obtained using the multiplexing technique enable low-frequency holograms (478 lines/mm) with a 43° acceptance angle. Using three of these devices, a 129° angular sweep is possible without the need for tracking.

Ensuring the structural stability and optical performance of holographic gratings in photopolymerizable hydrogels is essential for their integration into advanced photonic and biosensing platforms. Here, we investigate unslanted volume transmission holograms recorded in acrylamide‐based photohydrogels and establish how grating bending and internal attenuation govern diffraction efficiency. By fitting a physical model to experimental data, we report, for the first time to our knowledge, a three‐dimensional visualization of refractive index profiles in stored holograms, offering insights that are otherwise inaccessible with conventional imaging techniques. By using this tool, this work also reveals the role of radiant exposure and spatial frequency in defining recording quality, achieving diffraction efficiencies up to 75%, among the highest reported for hydrogel‐based holographic materials. In addition, as a novel feature, an LED curing process has been implemented for this type of material that significantly enhances the mechanical and optical stability of the gratings in aqueous environments. This work provides a new characterization methodology for holographic systems and offers guidelines for developing high‐performance holograms in hydrogel materials for use as reliable detection devices.