In the past few decades, several methods concerning optical thin films have been established to facilitate the development of integrated optics. This paper provides a brief depiction of different techniques for implementing optical waveguide thin films that involve chemical, physical, and refractive index modification methods. Recent advances in these fabrication methods are also been presented. Most of the methods developed for the realization of the thin-films are quite efficient, but they are expensive and require sophisticated equipment. The major interest of the scientists is to develop simple and cost-effective methods for mass production of optical thin films resulting in the effective commercialization of the waveguide technology. Our research group is focused on developing a silica-titania optical waveguide platform via the sol-gel dip-coating method and implementing active and passive optical elements via the wet etching method. We are also exploring the possibility of using nanoimprint lithography (NIL) for patterning these films so that the fabrication process is efficient and economical. The recent developments of this platform are discussed. We believe that silica-titania waveguide technology developed via the sol-gel dip-coating method is highly attractive and economical, such that it can be commercialized for applications such as sensing and optical interconnects.
Zinc oxide layers on soda-lime glass substrates were fabricated using the sol-gel method and the dip-coating technique. Zinc acetate dihydrate was applied as the precursor, while diethanolamine as the stabilizing agent. This study aimed to determine what effect has the duration of the sol aging process on the properties of fabricated ZnO films. Investigations were carried out with the sol that was aged during the period from 2 to 64 days. The sol was studied using the dynamic light scattering method to determine its distribution of molecule size. The properties of ZnO layers were studied using the following methods: scanning electron microscopy, atomic force microscopy, transmission and reflection spectroscopy in the UV-Vis range, and the goniometric method for determination of the water contact angle. Furthermore, photocatalytic properties of ZnO layers were studied by the observation and quantification of the methylene blue dye degradation in an aqueous solution under UV illumination. Our studies showed that ZnO layers have grain structure, and their physical–chemical properties depend on the duration of aging. The strongest photocatalytic activity was observed for layers produced from the sol that was aged over 30 days. These layers have also the greatest porosity (37.1%) and the largest water contact angle (68.53°). Our studies have also shown that there are two absorption bands in studied ZnO layers, and values of optical energy band gaps determined from positions of maxima in reflectance characteristics are equal to those determined using the Tauc method. Optical energy band gaps of the ZnO layer fabricated from the sol aged over 30 days are EgI = 4.485 eV and EgII = 3.300 eV for the first and second bands, respectively. This layer also showed the highest photocatalytic activity, causing the pollution to degrade 79.5% after 120 min of UV irradiation. We believe that ZnO layers presented here, thanks to their attractive photocatalytic properties, may find application in environmental protection for the degradation of organic pollutants.
The sol–gel dip-coating method is a cost-efficient way for the realization of thin films on a planar substrate. In this work, high-quality, low-loss, and low-surface roughness silica–titania thin films are deposited on a glass substrate with the sol–gel dip-coating method. This platform works in the visible to near-IR wavelength ranges and can be useful for several eye-catching photonic components. The paper is comprised of two parts: the first part deals with the development of a low-cost silica–titania waveguide system, whereas the second part provides detail on the numerical modeling of the SWG waveguide filter and SWG waveguide FP-sensor design. The SWG waveguide NIR-stopband filter can achieve an ER of >40 dB and 3-dB bandwidth of 110 nm designed at optimized parameters. The SWG waveguide-FP structure proposed in this work act as a refractive index sensor where the sensitivity is ~120 nm/RIU by reducing the width of the waveguide. This sensitivity can be further enhanced by reducing the waveguide height. We believe that this work is quite important for the realization of low-cost integrated photonic devices based on the silica–titania platform developed via the sol–gel dip-coating method.
The aim of the presented investigations was to develop a technique of producing Bragg’s grating couplers on planar waveguides. Waveguides are obtained by means of the sol-gel technology. The introduction of a light beam into the structure of the waveguide is in the case of planar or strip optical systems always an essential technical problem, requiring simple and reproducible solutions without extending excessively the waveguide structure. The paper presents a technology of producing grating couplers by impressing the pattern of the network while forming the planar waveguide structure applying the sol-gel method. Some remarks concerning the sol-gel technology are also presented. The results of investigations on grating couplers obtained in such a way have been discussed, too.Attention has been drawn to the possibility of using such structures in optoelectronic sensors, particularly gas sensors, including sensors of water vapour as well as toxic gases.