This paper investigates the emission characteristics of hydrogen-enriched gasoline (95G5H₂) under dynamic driving situations in order to fulfill the growing need for cleaner and more efficient automobile fuels. This study aimed to investigate the impact of hydrogen addition on pollutant-specific emissions, including CO, CO₂, HC, and NO_x, using a Nissan Qashqai that ran on both pure gasoline (100G) and 95G5H₂. Emission statistics were obtained by computer simulations of the Worldwide Harmonized Light Vehicles Test Cycle (WLTC) applied using AVL CRUISE software. The paper presents a method of comparing the characteristics of pollutants emitted by the combustion engine and comparing the pollutants emitted when powered by regular fuel and fuel with hydrogen. The tests were performed in real conditions, and the presented method shows the amount of pollutants emitted when the vehicle is directly in motion, which allows for effective comparison of the amount of pollutants emitted for different fuels. 95G5H₂ sharply reduces CO-, CO₂-, and HC-specific emissions by 22.19%, 14.55%, and 35.46%, respectively, when compared to 100G. However, NO_x-specific emissions increased by 20.17%, suggesting a compromise between higher combustion efficiency and higher burning temperatures. The study shows that 95G5H₂ fuel performs better in urban driving cycles, including plenty of acceleration and deceleration, which usually results in incomplete combustion. Although additional refinement is needed to cut NO_x-specific emissions, the results demonstrate that hydrogen-enriched fuels have considerable potential to lower vehicle-specific emissions. The significant conclusions of the study on the advantages of hydrogen-enriched fuels, both practically and environmentally, will help in the future development of environmentally friendly transportation solutions.

This study investigates the impact of hydrogen supplementation on the performance, efficiency, and emissions of a spark-ignition internal combustion engine, with a specific focus on knock phenomena. A Nissan HR16DE engine was modified to operate in a dual-fuel mode using gasoline (E95) and high-purity hydrogen. Hydrogen was injected via secondary manifold injectors and managed through a reprogrammable MoTeC ECU, allowing precise control of ignition timing and fuel delivery. Experiments were conducted across various engine speeds and loads, with hydrogen mass fractions ranging from 0% to 30%. Results showed that increasing hydrogen content enhanced combustion intensity, thermal efficiency, and stability. Brake specific fuel consumption decreased by up to 43.4%, while brake thermal efficiency improved by 2–3%. CO, HC, and CO₂ emissions were significantly reduced. However, NO_x emissions increased with higher hydrogen concentrations due to elevated combustion temperatures. Knock tendency was effectively mitigated by retarding ignition timing, ensuring peak in-cylinder pressure occurred at 14–15° CAD aTDC. These findings demonstrate the potential of hydrogen supplementation to reduce fossil fuel use and greenhouse gas emissions in spark ignition engines, while highlighting the importance of precise combustion control to address challenges such as knock and NO_x formation.

Natural gas stands out as a promising alternative fuel, and utilizing late intake valve close (LIVC) can further enhance its potential by improving internal combustion engine performance. The present study investigated the effect of LIVC on the performance of a Nissan Qashqai J10 four-cylinder internal combustion ignition engine (ICE) operating on gasoline (G) and natural gas (NG), with a focus on both energy and ecological aspects at stoichiometric points. Experimental tests were performed under the usual engine operating conditions, with engine speeds of 2000 and 3000 rpm and brake mean effective pressures (BMEPs) of 0.31, 0.55, and 0.79 MPa, while the intake valve closing moment was delayed at 24°, 31°, 38°, 45°, 52°, and 59° after bottom dead center (aBDC). The software AVL BOOST™ (version R2021.2) and its utility BURN were used to calculate the rate of heat release (ROHR), mass fraction burned (MFB), in-cylinder temperature, and the rate of temperature rise. The substitution of natural gas for gasoline substantially decreases CO₂ and NO_x emissions while enhancing the engine’s energy efficiency. Implementing a LIVC strategy can further boost brake thermal efficiency and reduce CO₂, though it negatively impacts CO, HC, and NO_x emissions. Optimal performance necessitates balancing efficiency improvements and CO₂ reduction against the control of other pollutants, potentially through combining LIVC with alternative engine control methodologies.

Hybrid electric vehicles (HEVs) frequently cycle their internal combustion engines (ICE), potentially cooling the three-way catalyst (TWC). This challenges the use of compressed natural gas (CNG), as methane (CH₄) requires high temperatures for TWC oxidation. This study experimentally investigates the performance, engine-out emissions (CO, NO_x, CH₄, NMHC, CO₂), and catalyst temperatures of a Toyota RAV4 hybrid vehicle on gasoline (G), CNG, and dual fuel (MIX) during the WLTC. Engine-out emissions were measured upstream of the TWC. Results showed similar engine work output (~17.8 kWh/100 km), while CNG significantly reduced fuel mass consumption (−18.7%) and CO₂ emissions (−27.5%) compared to gasoline, driven by both its higher LHV and higher average BTE. CO (−32.3%) and NO_x (−34.0%) emissions were lower with CNG, linked to leaner operation and significantly retarded ignition timing for NO_x control. However, CH₄ emissions drastically increased with CNG. This study reveals a synergy between the same retarded ignition timing strategy used to successfully control engine-out NO_x (−34.0%) and created a positive secondary effect, raising pre-TWC temperatures by 4.5%. Higher thermal condition is essential for the aftertreatment of chemically stable methane, highlighting a direct link between the engine’s NO_x control logic and the potential to mitigate methane slip.

The utilization of “green” hydrogen in transportation areas gives rise to production- and supply infrastructure-related challenges; therefore, its wider application in automotive transport would lead to higher demand with cost reduction and a faster expansion of the hydrogen refuelling network. This study presents energy and environmental performance indicators analyses of a Nissan Qashqai J10 engine during the Worldwide Harmonised Light Vehicles Test Cycle (WLTC), replacing conventional fossil gasoline with dual-fuel (D-F) gasoline and hydrogen. Numerical modelling was conducted using AVL Cruise™ (Version R2022.2) software, utilizing the torque, fuel consumption, and environmental performance data of the HR16DE engine obtained through experimental testing across a wide range of loads and speeds on an engine test bench. The experimental investigation was carried out in two stages: using pure gasoline (G100); injecting a hydrogen additive into the intake air, constituting 5% of the gasoline mass (G95H5). Following similar stages, numerical modelling was conducted using the vehicle’s technical specifications to calculate engine load and speed throughout the WLTC range. Instant fuel consumption and pollutant emissions (CO, CH, NO_x) were determined for various driving modes using experimental data maps. CO₂ emissions were calculated considering fuel composition and consumption. By integrating the instant values, the total and specific fuel consumption and emissions were calculated. As a result, this study identified the effect of a 5% hydrogen additive in improving engine energy efficiency, reducing incomplete combustion products and lowering greenhouse gas (CO₂) emissions under various driving modes. Finally, the results were compared with the requirements of EU standards.