Using ZnAl2O4@ZnO as a catalyst, an environmentally friendly and very effective method has been developed to selectively add a ring to 1,3-dicarbonyl compounds and aromatic, aliphatic primary amines. A wide variety of bis(β-enaminones) and bis(β-enaminoesters) can be synthesized using this highly versatile method, which provides good yields. This procedure can be carried out at room temperature, which is environmentally advantageous as it utilizes ZnAl2O4@ZnO as a heterogeneous, recyclable and stable catalyst under free solvent conditions. A co-precipitation reaction at constant pH was used to prepare this catalyst, and spectral analysis (X-ray diffraction, FTIR) and morphological characterization techniques (SEM, EDX) confirmed its morphological structure.

Considering the growing need for developing ecological materials, this study investigates the acoustic, mechanical, and thermal properties of wood composites reinforced with beech or oak wood fibres. Scanning electron microscopy (SEM) revealed a complex network of interconnected pores within the composite materials, with varying pore sizes contributing to the material’s overall properties. Acoustic characterization was conducted using a two-microphone impedance tube. The results revealed that the fibre size significantly impacts the sound absorption coefficient, demonstrating that the highest sound absorption coefficient of 0.96 corresponds to the composites reinforced with oak wood fibres with a size of 2 mm in the low-frequency range of 1000–2500 Hz. Mechanical testing revealed a significant reduction in compressive strength as fibre size increased from 0.4 mm to 2 mm, correlating with the observed changes in sound absorption and thermal properties. Thermal analysis indicated thermal conductivity (λ) values ranging from 0.14 to 0.2 W/m·K, with a notable increase in conductivity as fibre size decreased. It was shown that composites reinforced with beech or oak wood fibres with a size of 2 mm are recommendable for insulation materials due to the lowest thermal conductivity of 0.14 W/(m·K). Oak wood composites with a fibre size of 0.4 mm recorded the highest heat capacity, which is 54.4% higher than the one corresponding to the composites reinforced with the largest fibres. The results regarding heat diffusion rates are also reported. The findings about the effects of fibre size and pores on thermal, acoustic and mechanical properties provide valuable insights for designing sustainable materials, offering potential applications in industries where balanced performance across multiple properties is required.

The materials used as corrosion inhibitors are [Zn-Al-Cl], [Mg-Al-Cl], [Ni-Fe-Cl], and [Co-Fe-Cl] layered double hydroxides (LDHs). They were synthesized by coprecipitation and characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), and thermal anal-yses. The efficiency of these corrosion inhibitors on mild steel in concentrated hydrochloric acid (18.5%) at 60°C (chemical pickling conditions of steel) was studied using electrochemical and gravimetric methods for different concentrations. The surface morphology and composition were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. The inhibitory efficiency in the case of 1.2 g.L-1 LDH was found to be 83.33%, 83.65%, 68.38%, and 74.73% for [Ni- Fe-Cl], [Zn-Al-Cl], [Co-Fe-Cl], and [Mg-Al-Cl], respectively.