Graphene’s outstanding properties make it a potential material for reinforced cementitious composites. However, its shortcomings, such as easy agglomeration and poor dispersion, severely restrict its application in cementitious materials. In this paper, a highly dispersible graphene (TiO2-RGO) with better dispersibility compared with graphene oxide (GO) is obtained through improvement of the graphene preparation method. In this study, both GO and TiO2-RGO can improve the pore size distribution of cement mortars. According to the results of the mercury intrusion porosity (MIP) test, the porosity of cement mortar mixed with GO and TiO2-RGO was reduced by 26% and 40%, respectively, relative to ordinary cement mortar specimens. However, the TiO2-RGO cement mortars showed better pore size distribution and porosity than GO cement mortars. Comparative tests on the strength and durability of ordinary cement mortars, GO cement mortars, and TiO2-RGO cement mortars were conducted, and it was found that with the same amount of TiO2-RGO and GO, the TiO2-RGO cement mortars have nearly twice the strength of GO cement mortars. In addition, it has far higher durability, such as impermeability and chloride ion penetration resistance, than GO cement mortars. These results indicate that TiO2-RGO prepared by titanium dioxide (TiO2) intercalation can better improve the strength and durability performance of cement mortars compared to GO.
With the increasing operation time of tunnels, the drainage system cannot fulfil its proper function as a result of the deterioration of traditional waterproof and drainage systems (TWDS), such as the blockage of drainage blind pipes and the failure of drainage boards. Therefore, the lining bears a high water pressure and even causes disasters such as tunnel leakage and lining cracking. An effective solution to mitigate these issues is to adjust the tunnel drainage scheme. In view of this, a composite waterproof and drainage system (CWDS) is proposed in this paper. To verify the effectiveness of the proposed system, a series of model experiments were conducted to study the change law of the seepage field of two drainage systems under different blockage conditions. The study results showed that longitudinal blind pipe blockage caused a more significant increase in water pressure than circular blind pipe blockage. In the case of blind pipe blockage, the water pressure of the TWDS tunnels rise rapidly, while the CWDS tunnels could effectively drain and reduce pressure.
Microcapsules have received considerable attention owing to their excellent self-healing properties, and many researchers have attempted to modify their microcapsules’ characteristics to meet the requirements of various applications. Owing to their excellent physical and chemical properties, nanomaterial-modified (nanomodified) microcapsules can be used to protect surface coatings and internal structures of cement-based materials. This paper summarizes the progress in theoretical research and practical application of nanomodified microcapsules in coatings and cement-based materials, focusing on preparation processes and performance enhancements. The advantages and necessity of using nanomaterials are highlighted by clarifying the effects of nanomodified microcapsules on the performances of coatings and cement-based materials. In addition, the bottlenecks in the application of nanomodified microcapsules to coatings and cement-based materials are comprehensively examined, and the challenges and future development directions are specified. This review provides technical guidance for the preparation of smart nanomodified microcapsules and novel ideas for enhancing the functionality of protective coatings and the durability and safety of cement-based materials.
Pipeline leakage can induce ground surface settlements and structural responses in existing tunnels. A thorough understanding of pipeline–tunnel interactions is crucial for optimizing urban underground design and establishing construction guidelines. As urban underground spaces undergo rapid, large-scale development, their layouts have grown increasingly complex. Previous studies have mainly focused on the leakage propagation range and the resulting strata instability during tunnel excavation, while paying limited attention to the effects of pipeline leakage on existing tunnels. This study systematically investigated the mechanical response of existing tunnel structures to pipeline leakage under different layout configuration conditions using numerical modeling. A two-dimensional numerical model was developed to simulate the pipeline leakage process and its impact on adjacent tunnels. The research established a correlation between surrounding rock strength parameters and the saturation degree while examining the evolution patterns of leakage effects in various tunnel–pipeline arrangements. The analysis specifically focused on the mechanical influence of horizontal pipeline–tunnel distance, quantitatively determining the relationships among pipeline–tunnel spacing, leakage duration, and structural internal force. The horizontal pipeline–tunnel distance did not influence the development of the leakage zone above the tunnel vault but significantly altered the seepage path length and interface contact area. The complete encapsulation of the tunnel periphery by the leakage zone required progressively longer durations with increasing horizontal offsets: 16 days (0 m), 20 days (3 m), and 33 days (6 m). Corresponding circumferential contact ratios at 10 days were measured at 68.9%, 56.4%, and 30.6%, respectively. Furthermore, prolonged seepage duration led to increased ground subsidence with expanded affected areas, while the maximum settlement decreased proportionally with greater horizontal separation from the tunnel. These findings provide valuable insights for planning, designing, and maintaining “old tunnel-new pipeline” systems in urban underground development.
To reduce downtime of the Tunnel Boring Machine and improve construction efficiency of subway tunnels, the tunnel–station synchronous construction method was implemented in the Qingdao metro. In this method, the TBM advanced continuously through the station, while the upper station was excavated in stages using the primary support arch covering technique. Focusing on a construction scheme with low-grade temporary segments, this study develops a three-dimensional numerical model to investigate the mechanical response of shield lining during the simultaneous construction of a subway station and tunnel. The Mohr–Coulomb model and the Elastic model were employed to represent the mechanical behavior of the surrounding rock and support structure, respectively. The deformation, bending moment, axial force, and residual bearing capacity coefficients of the shield lining were systematically examined across six distinct construction stages. The results showed that asymmetric gradual unloading of the surrounding rock at the arch part caused the vertical displacement of the shield lining to be predominantly upward, with a maximum heave of 1.51 mm. Horizontal displacement exhibited significant asymmetry. During station arch excavation, asymmetric unloading led to an increase and clockwise shift in the bending moments of the shield lining. The axial forces transitioned from compression to tension at specific locations (40° and 240°), whereas the removal of temporary supports had only a minor influence. The maximum tensile stress of the shield lining increased by 3.35 times in Stage III and reached 0.69 MPa in Stage V, representing a 1.65-fold increase compared to the previous stage. Although the residual bearing capacity coefficient generally satisfied safety requirements throughout the construction process, it decreased to a minimum of 0.88 in Stage V, a 7% reduction relative to Stage IV, necessitating close monitoring. This study not only confirmed the safety of using temporary segments made of lower-grade concrete (C30) in tunnel–station synchronous construction but also provided valuable insights for optimizing construction schemes and controlling key risks, such as structural deformation, in similarly complex urban environments.
Subway tunnels excavated in soil–rock composite strata face great challenges due to the prevalence of inner defects. The instability of tunnels in these strata poses significant risks to construction safety. In this paper, indoor experiments are adopted to study the instability process of a subway tunnel in soil–rock composite strata influenced by inner cavities. A total of six groups of tests are designed based on the location of the cavity and the distance of the cavity from the tunnel. High-resolution monitoring techniques are employed to capture the real-time deformation and failure process of strata. The results show that a cavity in the strata significantly affects the stability of the strata after the tunnel excavation. The existence of a cavity increases ground deformation, and a cavity at different locations affects ground deformation. The strata around the cavity are the first to experience failure by the upper loads applied after the tunnel is excavated. The location of the cavity changes the stress distribution state of the strata and thus alters the emergence of cracks, which finally disturbs the collapse process and pattern of the composite strata. The probability and collapse range increase when the tunnel excavation impact zone is connected with the cavity weakening zone. The findings can provide technical support for the collapse prevention and safety control of subway tunnels in composite strata with internal defects.