Graphene’s outstanding properties make it a potential material for reinforced cementitious composites. However, its shortcomings, such as easy agglomeration and poor dispersion, severely restrict its application in cementitious materials. In this paper, a highly dispersible graphene (TiO₂-RGO) with better dispersibility compared with graphene oxide (GO) is obtained through improvement of the graphene preparation method. In this study, both GO and TiO₂-RGO can improve the pore size distribution of cement mortars. According to the results of the mercury intrusion porosity (MIP) test, the porosity of cement mortar mixed with GO and TiO₂-RGO was reduced by 26% and 40%, respectively, relative to ordinary cement mortar specimens. However, the TiO₂-RGO cement mortars showed better pore size distribution and porosity than GO cement mortars. Comparative tests on the strength and durability of ordinary cement mortars, GO cement mortars, and TiO₂-RGO cement mortars were conducted, and it was found that with the same amount of TiO₂-RGO and GO, the TiO₂-RGO cement mortars have nearly twice the strength of GO cement mortars. In addition, it has far higher durability, such as impermeability and chloride ion penetration resistance, than GO cement mortars. These results indicate that TiO₂-RGO prepared by titanium dioxide (TiO₂) intercalation can better improve the strength and durability performance of cement mortars compared to GO.

Improving coal resource mining rates has long been a focus of coal industry research. The gob-side entry retaining by roof cutting (GERRC) is a new coal mining technology that has gained popularity in China due to its high mining rate and safety. Based on the GERRC technology, the precise technical procedure is elaborated, and the fundamental idea of pressure relief is explored through creating a structural mechanics model of the surrounding rock in this paper. The results of mechanical analysis show that the primary mechanism of roof pressure release is to weaken the integrity of the roof, thereby reducing the ultimate bending moment of the rock stratum. In addition, an additional strategy for pressure release is suggested in this research, involving the weakening of the roof rock by the creation of dense pressure-released holes. The results of the engineering field experimentation demonstrate that the dense pressure-released holes can completely replace the conventional blasting technology of the past to achieve the effect of releasing the roof pressure, thus avoiding the use of hazardous and challenging-to-obtain explosives and demonstrating safety, reliability, and feasibility.

In fracture zones, tunneling with a double-shield Tunnel Boring Machine (TBM) presents significant challenges, including deformation overrun of the surrounding rock, TBM jamming, and excavation face collapse. To assure the tunnel construction safety and efficiency, it is necessary and crucial to conduct a stability analysis of the tunnel surrounding rock when a TBM passes through the fracture zones. The tunnels from Jiadingshan Road Station to Anshan Road Station in Qingdao Metro Line 8 are constructed by double-shield TBMs. It inevitably passes through fracture zones with different deterioration levels and dip angles. In this study, based on this construction section, numerical models of fracture zones with different deterioration levels and dip angles were developed to analyze the displacements of tunnel vaults, inverts, and haunches. In addition, the maximum shear stresses of the surrounding rock were analyzed. Finally, the displacement and shear stress variation patterns of the surrounding rock with different deterioration levels and dip angles were obtained. The findings reveal the stability behavior of tunnels under various fracture zones. They can serve as a valuable reference and theoretical foundation for future tunnel construction projects utilizing double-shield TBMs in areas with fracture zones.

The concrete lining in subway tunnels often undergoes cracking damage in coastal cities. The combination of cracked tunnel lining structures and high concentrations of corrosive ions in the groundwater (e.g., chlorine) can accelerate concrete erosion, reduce the mechanical performance of the lining structures and shorten the tunnel service life. This paper investigates the chloride ion concentration in the groundwater of several subway tunnels in the coastal city of Qingdao, China. Indoor experiments and numerical simulations are conducted to investigate the chloride ion transport behaviour and service performance of cracked concrete linings. The results are applied to predict the service life of lining structures. The crack depth in concrete linings is found to have the most significant effect on the transport rate of chloride ions, followed by the crack width. The numerical simulations are carried out using COMSOL software to study the chloride transport behaviour in cracked specimens and predict the service lifetimes of lining structures of different thicknesses, and the results correspond well with the experimental data. The durability of a concrete lining can be enhanced by increasing the thickness of the protective concrete layer. Additional measures are proposed for treating cracked concrete linings to resist chloride ion attack in subway tunnels.