Anouar Hajjaji

Dr. Anouar Hajjaji


Research Focus & Metrics

Academic Career Length

13Years (2014-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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16 February 2022 in Materials
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AAAssadi Achraf Amir
Assadi Achraf Amir
SKSarra Karoui
Sarra Karoui
KTKhaled Trabelsi
Khaled Trabelsi
AHAnouar Hajjaji
Anouar Hajjaji
Walid ElfallehWalid Elfalleh
Walid Elfalleh
Aymen Amin ASSADIAymen Amin ASSADI
Aymen Amin ASSADI
In this work, we present the influence of the decoration of TiO2 nanotubes (TiO2-NTs) with Ag silver nanoparticles (Ag-NPs) on the photocatalysis of emerging pollutants such as the antibiotic diclofenac sodium. The Ag-NPs were loaded onto the TiO2-NTs by the anodization of metallic titanium foils. Diclofenac sodium is an emerging pollutant target of the pharmaceutical industry because of its negative environmental impact (high toxicity and confirmed carcinogenicity). The obtained Ag-NP/TiO2-NT nanocomposites were characterized by X-ray diffraction (XRD), photoluminescence spectroscopy (PL), scanning electron microscopy (SEM), transmission spectroscopy (TEM), and X-ray photoelectron spectroscopy (XPS). In order to study the photocatalytic behavior of Ag-NPs/TiO2-NTs with visible cold LEDs, the possible photocatalytic mechanism of antibiotic degradation with reactive species (O2°− and OH°) was detailed. Moreover, the Langmuir–Hinshelwood model was used to correlate the experimental results with the optimized catalyst. Likewise, reuse tests showed the chemical stability of the catalyst.

21 July 2023 in Coatings
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HDHafedh Dhiflaoui
Hafedh Dhiflaoui
SSSarra Ben Salem
Sarra Ben Salem
Mohamed SalahMohamed Salah
Mohamed Salah
YDyoussef Dabaki
youssef Dabaki
SCSlah Chayoukhi
Slah Chayoukhi
Hicham BENHAYOUNEHicham BENHAYOUNE
Hicham BENHAYOUNE
Titanium oxides and their alloys are widely used in medical applications because of their biocompatibility. However, they are characterized by their low resistance to corrosion. The HaP + TiO2 nanocomposites’ coating was applied in different experiments, especially on a Ti-6Al-4V substrate with the spray pyrolysis process to deal with such weakness. The TiO2 content effects on the surface morphology and the phase composition were investigated using a scanning electron microscopy, X-ray microanalysis (SEM-EDXS) and X-ray diffraction (XRD). The mechanical properties were determined with nanoindentation. The potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and simulated body fluid (SBF) solution environment tests were carried out to investigate the corrosion resistance of HaP + TiO2/Ti6Al4V systems. The experimental findings revealed that sprayed thin films possessed uniform morphology. The coatings’ nanoindentations proved that the HaP + 20% TiO2 coating hardness (252.77 MPa) and the elastic modulus (52.48 GPa) overtopped those of the pure hydroxyapatite coatings. The corrosion test demonstrated that the corrosion current density of about 36.1 µA cm−2 and the corrosion potential of the order of −392.7 mV of HaP + 20% TiO2 was lower compared to the pure HaP coating.

6 April 2025 in Catalysts
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AMAbidi Mabrouk
Abidi Mabrouk
Aymen Amin ASSADIAymen Amin ASSADI
Aymen Amin ASSADI
SASelma Aouida
Selma Aouida
HTHICHEM Tahraoui
HICHEM Tahraoui
LKLotfi Khezami
Lotfi Khezami
AHAnouar Hajjaji
Anouar Hajjaji
This research investigates the enhanced photocatalytic activity of cuprous oxide (Cu2O) nanoparticles (NPs)-titanium dioxide (TiO2) nanotube (NT) composites for air purification, focusing on the removal of volatile organic compounds (VOCs) and Escherichia coli (E. coli) bacteria under simulated sunny light. Cu2O-NPs were successfully deposited onto TiO2-NTs via the successive ionic layer adsorption and reaction method. The resulting p- and n-type semiconductor heterojunction nanocomposites were characterized using various techniques, including scanning electron microscopy, transmission electron microscopy, ultraviolet–visible-light spectroscopy, and chlorinated radicals. The photocatalytic activity was evaluated for different VOCs present in indoor air (butadione, chloroform, and butyraldehyde) in the presence of E. coli bacteria. The results showed that the Cu2O-NPs/TiO2-NTs composites exhibited enhanced photocatalytic activity compared to pure TiO2-NTs. The Langmuir–Hinshelwood model was used to describe the degradation kinetics, revealing that Cu2O loading and the nature of the target pollutant influence the photocatalytic efficiency. This study has also highlighted the role of chlorinated radicals in the degradation process, especially for chloroform. The degradation process of chloroform generated chlorine radicals, which not only contributed to the degradation of other VOCs, but also enhanced the overall oxidative capacity of the system. This synergistic effect was observed to accelerate pollutant removal and improve the antibacterial efficacy against E. coli. The Cu2O-NPs/TiO2-NTs composites demonstrated significant reusability and antibacterial properties, highlighting their potential for sustainable indoor air purification applications.

8 July 2024 in Inorganics
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SSSyrine Sassi
Syrine Sassi
Amal BouichAmal Bouich
Amal Bouich
AHAnouar Hajjaji
Anouar Hajjaji
LKLotfi Khezami
Lotfi Khezami
BBBrahim Bessais
Brahim Bessais
Bernabé MaríBernabé Marí
Bernabé Marí
Cu-doped TiO2 films were synthesized directly on FTO glass with a spin coating method. With a variation in copper amount, samples were prepared with 0%, 1%, 2%, 4% and 8% of dopant concentrations. Morphological and structural characterization of undoped and Cu-doped TiO2 samples were investigated and the obtained results showed the small, spherical shapes of the nanoparticles forming a thin film on top of FTO glass and their preferred orientation of TiO2 anatase (101), which is the same for each sample. However, this peak exhibited a slight shift for the 2% sample, related to the inflation of the microstrain compared to the other samples. For the optical properties, the 4% sample displayed the highest transmittance whereas the 2% sample exhibited the lowest band gap energy of 2.96 eV. Moreover, the PL intensity seems to be at its highest for the 2% sample due to the present peaking defects in the structure, whereas the 8% sample shows a whole new signal that is related to copper oxide. These properties make this material a potential candidate to perform as an electron transport layer (ETL) in solar cells and enhance their power conversion efficiency.

17 July 2022 in Materials
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FAFaisal Algethami
Faisal Algethami
KTKhaled Trabelsi
Khaled Trabelsi
AHAnouar Hajjaji
Anouar Hajjaji
Mohamed Ben RabhaMohamed Ben Rabha
Mohamed Ben Rabha
LKLotfi Khezami
Lotfi Khezami
My Ali El KhakaniMy Ali El Khakani
My Ali El Khakani
The present work aims to study the photocatalytic properties of nanohybrids composed of silicon nanowires (SiNWs) decorated with PbS nanoparticles (NPs). The elaborated material was intended to be utilized in wastewater treatment. The SiNWs were elaborated from the Metal Assisted Chemical Etching route (MACE), while the PbS NPs were deposited at room temperature onto SiNWs using the pulsed laser deposition (PLD) technique. The influence of decorating SiNWs (having different lengths) with PbS-NPs on their structural, morphological, optoelectronic, and photocatalytic properties was scrutinized. PbS/SiNWs nanohybrids exhibited enhanced photocatalytic degradation towards Black Amido (BA) dye for 20 µm SiNWs length and 0.2% of BA volume concentration. These optimized conditions may insinuate that this nanocomposite-like structure is a promising efficient photocatalytic systems contender, cost-effective, and recyclable for organic compound purification from wastewaters.

30 November 2021 in Materials
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LKLotfi Khezami
Lotfi Khezami
ILImen Lounissi
Imen Lounissi
AHAnouar Hajjaji
Anouar Hajjaji
AGahlem Guesmi
ahlem Guesmi
Aymen Amin ASSADIAymen Amin ASSADI
Aymen Amin ASSADI
BBBrahim Bessais
Brahim Bessais
This work reports on the effect of TiO2 nanotubes (TiO2-NTs), decorated wih platinum nanoparticles (Pt-NPs), on the removal of bacteria and volatile organic compounds (VOCs). The Pt-NPs were loaded onto the TiO2-NTs using the electrodeposition method at four decoration times (100, 200, 300, and 600 s). The realized Pt-NPs/TiO2-NTs nanocomposites were used for the degradation of cyclohexane, a highly toxic and carcinogenic VOC pollutant in the chemical industry. The achieved Pt-NPs/TiO2-NTs nanocomposites were characterized using X-ray diffraction (XRD), photoluminescence (PL), diffuse reflectance spectroscopy (UV–Vis), and scanning (SEM) and transmission (TEM) electron microscopy. To understand the photocatalytic and antibacterial behavior of the Pt-NPs/TiO2-NTs, simultaneous treatment of Escherichia coli and cyclohexane was conducted while varying the catalyst time decoration. We noticed a complete bacterial inactivation rate with 90% VOC removal within 60 min of visible light irradiation. Moreover, the Langmuir–Hinshelwood model correlated well with the experimental results of the photocatalytic treatment of indoor air.