With the development of fiber optic sensing technology, optical fiber sensors have been widely used in online monitoring of power transformers. To investigate the influence of aging fiber sheaths on transformer oil, two kinds of special optical fibers with thermoplastic polyester elastomer (TPEE) and poly tetra fluoroethylene (PTFE) as sheaths underwent thermally accelerated aging in transformer oil at 130 °C. The volume resistivity, dielectric dissipation factor (DDF), and breakdown voltage of the oil were measured to indicate insulation strength. The water content and acid value of the oil were measured and fitted to predict the aging tends. The thermal aging characteristics of the oil were quantitatively compared and results showed two kinds of optical fibers could exacerbate all the physical and chemical parameters of oil, and the TPEE sheath had a more significant impact on the oil. The reasons contributing to such phenomenon were analyzed using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Both TPEE and PTFE were depolymerized in high-temperature transformer oils, producing water and small molecule hydrocarbon groups. The accumulation of small hydrocarbon groups promoted positive feedback of pyrolysis in the oil. The free hydrogen produced by oil pyrolysis increased the acidity of the oil, which in turn increased the solubility of the water produced by sheath depolymerization. The chain depolymerization of TPEE was more severe than that of PTFE, further exacerbating the deterioration of TPEE-containing oil.

In this paper, smog meteorological conditions in the natural environment is simulated by the salt fog method. The study of the alternating current (AC) discharge characteristics of rod-plane short air gaps in salt fog environments has important guiding significance for how to strengthen the external insulation strength of ultra-high voltage (UHV) transmission lines and electrical equipment in smog environments. The rod-plane short air gap is selected as the model to simulate the extremely uneven electric field. The AC discharge test is carried out in the salt fog environment with different conductivity, and the finite element method (FEM) is used to simulate the distribution of electric field in air gap under salt fog environment conditions. The results show that under clean fog conditions the AC discharge voltage in the air gap increased by 15.1% to 35.5% compared to that under dry conditions. With the increased conductivity of salt fog, the AC discharge voltage in air gap decreased by 4.1% to 9.2% compared to that under clean fog conditions, and the reduction is within 10%. The distortion of the electric field and the adsorption of free electrons in the gap by droplets lead to the decrease of the electric field intensity in the air gap. With the increase of the conductivity, the electric field intensity in the air gap increases slightly. Meanwhile, the influence of salt fog and its conductivity on the AC discharge voltage of rod-plane short air gap is examined, becoming saturated with the increase of the gap distance and the conductivity of salt fog.