The disposal of industrial waste poses a significant environmental challenge, often leading to pollution and degradation of surrounding and terrestrial ecosystems. This study investigates the sustainable valorization of such wastes through the development of one-part geopolymer mortars. Solid sodium silicate was employed as a dry alkali activator for binary blends comprising ground granulated blast-furnace slag (GGBS), clay brick powder (CBP), steel slag (SS), and fly ash (FA), with all mixtures cured under ambient conditions. The mortars were evaluated in terms of fresh properties (flow and setting time) and hardened characteristics, including compressive strength, density, water absorption, and porosity. Durability performance was assessed through mass loss, visual degradation, and compressive strength retention following exposure to acidic (H₂SO₄, HCl) and sulfate environments. Microstructural characterization using XRD, SEM, and FTIR provided insight into the mechanisms of gel formation and degradation in aggressive media. The results revealed that incorporating 5% FA into GGBS-based mortars enhanced 28-day compressive strength by 21.7% compared with the control mix. The inclusion of industrial by-products promoted the formation of C–S–H and C–(A)–S–H gels, contributing to a denser and more refined microstructure. Overall, the findings demonstrate that one-part geopolymer mortars offer a promising, eco-efficient, and durable alternative to traditional cementitious systems, while also addressing safety and handling concerns associated with liquid alkaline activators used in conventional two-part geopolymer formulations.

This study evaluates crushed bamboo as a coarse aggregate for structural–thermal wall composites, comparing its performance against mixes with wood sawdust and rice husk. Crushed bamboo was used in both smooth and surface-roughened conditions, where particle morphology and surface features were characterized by SEM and AFM methods. The roughened bamboo aggregate exhibited greater surface roughness, thereby improving interfacial adhesion with cement. Surface roughening increased 28-day compressive strength by ~39–44% relative to smooth particles. Incorporating fine plant-based fillers into cement–bamboo composites increased their compressive strength by ~33–75% and reduced thermal conductivity by ~12–18%, compared with the analogues without fine particles. Water-absorption tests on bamboo aggregate showed rapid uptake in the first 24 h (43–45%) and saturation after 7 days of ~65–70%, values lower than typical wood by-products, thereby helping to limit mix water demand. Findings indicate that crushed, surface-roughened bamboo, especially with fine bio-fillers, can produce sustainable wall materials with a strong balance between strength and insulation.