Underwater artefacts are vulnerable to damage and loss of archaeological information during the extraction process. To solve this problem, it is necessary to apply temporary consolidation materials to fix the position of marine artifacts. A cross-linked network hydrogel composed of polyvinyl alcohol (PVA), tannic acid (TA), borax, and calcium chloride has been created. Four hydrogels with varying concentrations of tannic acid were selected to evaluate the effect. The hydrogel exhibited exceptional strength, high adhesion, easy removal, and minimal residue. The PVA/TA hydrogel and epoxy resin were combined to extract waterlogged wooden artifacts and marine archaeological ceramics from a 0.4 m deep tank. This experiment demonstrates the feasibility of using hydrogel for the extraction of marine artifacts.

The presence of calcareous concretions on the surface of marine archaeological ceramics is a frequently observed phenomenon. It is necessary to remove these materials when the deposits obscure the feature of ceramics. Unfortunately, calcareous concretions provide distinctive documentation of the burning history of ceramics. The interaction of acid solution or detachment of the deposit layers in physical ways leads to the loss of archeological information. To prevent the loss of archeological information and to achieve precise and gentle concretion removal, responsive hydrogel cleaning systems have been developed. The hydrogels synthesized are composed of networks of poly(vinyl acetate)/sodium alginate that exhibit desirable water retention properties, are responsive to Ca²⁺ ions, and do not leave any residues after undergoing cleaning treatment. Four distinct compositions were selected. The study of water retention properties involved quantifying the weight changes. The composition was obtained from Fourier transform infrared spectra. The microstructure was obtained from scanning electron microscopy. The mechanical properties were obtained from rheological measurements. To demonstrate both the efficiency and working mechanism of the selected hydrogels, a representative study of mocked samples is presented first. After selecting the most appropriate hydrogel composite, a cleaning process was implemented on the marine archaeological ceramics. This article demonstrates the advantages of stimuli-responsive hydrogels in controlling the release of acid solution release, thereby surpassing the limitations of traditional cleaning methods.

Due to compatibility issues between traditional reinforcing materials and the substrate of museum wooden artifacts, interface failure occurs after crack reinforcement, particularly under dry and wet cycling conditions. This significantly compromises the durability of reinforcement. To resolve this issue, dealkalized lignin was grafted onto epoxy acrylate (LEA) to synthesize a novel consolidant with both humidity responsiveness and mechanical compatibility. The resulting LEA exhibited excellent multilayer adsorption capability and demonstrated synchronous and uniform hygroscopic expansion behavior, closely matching that of archeological wood. DMA revealed that LEA2 has an elastic modulus of 261.58 MPa and a Poisson’s ratio of 0.35, comparable to artificially degraded wood, effectively mitigating interface stress caused by rigidity differences. Furthermore, LEA effictively reinforced micron-scale cracks while maintaining the original microstructure of the wooden artifact. This material provides a promising solution to the compatibility challenges of traditional consolidants under humidity fluctuations and offers a new approach for the stable preservation of museum wooden artifacts.

The use of epoxy resin/carbon fiber multilayer materials can effectively prevent damage to artifacts during underwater archaeological artifact extraction. However, the high viscosity of epoxy resin limits the coating ability and curing quality. To solve this problem, propylene carbonate (PC) was used as a diluent to reduce the viscosity and improve the properties. This study investigated the gel time, curing time, curing degree, and mechanical strength of the cured products by varying PC concentrations. It was found that the PC significantly enhanced the flowability of epoxy resin blends, extending the gel time from 22 min to 38 min, with minimal impact on the curing time. The glass transition temperature (Tg) ranged from 25.80 °C to 12.28 °C. Compared to E44/PC0, PC reduced the CTE values in the weft direction. The multilayer materials exhibited good temperature stability. The cured product had good mechanical properties and toughness, and could wrap irregular artifacts. The E44/PC10 formulation was used to prepare the epoxy resin/carbon fiber multilayer material. Waterlogged wooden artifacts were successfully extracted from 13 m deep calm water, using the multilayer material.