Atmospheric corrosion is one of the major sources of hydrogen in a high-strength-steel product in service. Even low concentrations of absorbed hydrogen can cause a hydrogen embrittlement-related material degradation. The extent of atmospheric corrosion and thus the related hydrogen entry is highly dependent on the environmental parameters, such as the relative humidity. The present work focused on the hydrogen entry at low relative humidity, where atmospheric corrosion rates are expected to be low. Hydrogen insertion and distribution in CP1000 steel induced by corrosion under dried and rewetted single droplets of aqueous NaCl and MgCl₂ solution were studied using the Scanning Kelvin Probe (SKP) and the resulting amounts of diffusible hydrogen were analyzed using thermal desorption mass spectrometry (TDMS). Corrosion product analyses were carried out with SEM/EDX, XRD, and Mössbauer spectroscopy. The results revealed the strong impact of salt type and concentration on the hydrogen entry into steel. The hygroscopic effect of MgCl₂ and the formed corrosion products were responsible for the prolonged insertion of hydrogen into the steel even at very low levels of relative humidity.

This study evaluates the tribological properties of lean medium manganese advanced high-strength steel (AHSS) subjected to five different heat treatment processes. The tests were conducted under dry reciprocating conditions using the ball-on-flat method, with a G40 steel ball, a 10 N load, and 1000 cycles at room temperature. Friction behavior, wear resistance, nanoindentation hardness, surface roughness, and microstructural changes were examined. The results showed that heat treatment significantly influenced the microstructure and hardness of the samples. The Mn-Q sample, with fresh martensite, achieved the highest hardness (483 HV5), while the Mn-Q&P 500 °C sample had the lowest (336 HV5), with a 30% reduction due to tempering. The Mn-HR 500 °C sample showed the highest surface roughness (Sa = 1.876 μm) due to microstructural heterogeneity. Despite similar coefficients of friction across all samples (0.55–0.57), the Mn-Q&P 500 °C sample exhibited the best wear resistance, 18% higher than the Mn-HR 500 °C variant. Wear mechanisms were identified as a combination of abrasion and oxidation, where the latter slightly reduced the coefficient of friction (COF) but increased surface degradation. These findings highlight the potential of lean medium Mn AHSS for tribological applications, offering a favorable balance of wear resistance and frictional stability.

Grain boundary wetting as a preliminary stage for zinc-induced grain boundary weakening and embrittlement in a Zn-coated press-hardened 20MnB8 steel was analyzed using electron backscatter diffraction, Auger electron spectroscopy, energy dispersive X-ray analysis, atom probe tomography and transmission electron microscopy. Microcracks at prior austenite grain boundaries were observed. Structures that developed after microcrack formation were identified: for example, Zn/Fe intermetallic phases with grain sizes smaller than 100 nm were present at the crack surfaces and the wedge-shaped crack tips. An electrolytically coated reference sample that underwent the same heat treatment as the press-hardened material but without the application of tensile stress was investigated in order to find the initial cause of the microcracks. On this sample, Zn, in the order of one atomic layer, was found along prior austenite grain boundaries several micrometers away from the actual Zn/Fe phases in the coating. The resulting grain boundary weakening with the Zn wetting of prior austenitic grain boundaries during austenitization and/or hot forming is a necessary precondition for microcrack formation.