As the industry develops and energy demand increases, wind turbines are increasingly being used to generate electricity, resulting in an increasing number of obsolete turbine blades that need to be properly recycled or used as a secondary raw material in other industries. The authors of this work propose an innovative technology not yet studied in the literature, where the wind turbine blades are mechanically shredded and micrometric fibers are formed from the obtained powder using plasma technologies. As shown by SEM and EDS studies, the powder is composed of irregularly shaped microgranules and the carbon content in the obtained fiber is lower by up to seven times compared with the original powder. Meanwhile, the chromatographic studies show that no hazardous to the environment gases are formed during the fiber production. It is worth mentioning that this fiber formation technology can be one of the additional methods for recycling wind turbine blades, and the obtained fiber can be used as a secondary raw material in the production of catalysts, construction materials, etc.
In this study, alumina coatings were formed using atmospheric plasma spraying, increasing the torch power from 29.4 to 45.1 kW. The surface morphology of the coatings was determined using scanning electron microscopy; the elemental composition was examined using energy-dispersive X-ray spectroscopy (EDS); phase composition was investigated using X-ray diffraction; and surface roughness was determined using a profilometer. The steel surface temperature was measured using a type-K thermocouple, and the plasma jet temperature, at a distance of 70 mm, using a type-B thermocouple. Alumina particle velocity was calculated by analyzing high-speed camera footage using ImageJ software. The results indicate that plasma jet temperature, speed, and in-flight particle velocity increased with plasma torch power. Furthermore, the amount of γ-Al2O3 phase in the coating increased, and the α-Al2O3 decreased with increasing plasma power. The surface roughness (Rq) of the Al2O3 coatings decreased from 7.13 to 5.54 μm, with an increase in torch power. The EDS measurements indicate that the increase in torch power did not affect the elemental composition of as-sprayed coatings. The results provide a wider understanding of an atmospheric plasma spray technique, optimizing and controlling the parameters using air as a primary gas.
Modern industrial systems and biomass-fired furnaces require surface treatments that can withstand aggressive chemical, thermal, and corrosive environments. This study investigates the corrosion and thermal resistance of plasma-sprayed Al2O3-TiO2 coatings produced using a DC air–hydrogen plasma spray process. Coatings of compositions of Al2O3, Al2O3-3 wt.% TiO2, Al2O3-13 wt.% TiO2, and Al2O3-40 wt.% TiO2 were deposited on steel substrates with a Ni/Cr bond layer by plasma spraying. The coatings were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) to evaluate their morphology, elemental composition, and crystalline phases. Electrochemical tests were performed in a naturally aerated 0.5 mol/L NaCl solution and cyclic thermal–chemical exposure tests (500 °C using 35% KCl) to assess their corrosion kinetics and thermal stability. The results indicate that pure Al2O3 and low TiO2 (3 wt.%) coatings exhibit fine barrier properties, while coatings with a higher TiO2 content develop additional phases (e.g., Ti3O5, Al2TiO5) that improve thermal resistance but reduce chemical durability.
This study presents the thermal and chemical resistance of plasma-sprayed Al2O3 and Al2O3 doped with 13 wt.% of TiO2 coatings and their suitability for the fire grate of straw pellet furnaces. Coatings were deposited on steel substrates using direct current atmospheric pressure plasma spraying. The surface structure, elemental, and phase composition of formed coatings were analyzed before and after the thermal treatment, imitating natural application conditions. For the experiment, the annealing temperature was 500 °C for twenty-five cycles (80 min each). It was found that the steel substrate oxidized after five thermal cycles, and the formation of iron oxides was observed. The elemental composition of the Al2O3 and Al2O3-13 wt.% TiO2 coatings remained unchanged even after 25 cycles of heat treatment. The X-ray diffraction (XRD) results revealed that the alpha-Al2O3 to gamma-Al2O3 phase ratio in the Al2O3-TiO2 coating was reduced by only 8.7% after 25 cycles.
This study has been performed to reveal the main characteristics of operating a direct current (DC) plasma-chemical reactor (PChR) designed for hazardous waste treatment. The PChR employs thermal plasma as the operating environment. The investigations presented in this paper were conducted to study the electrical and energy characteristics of the plasma torch and plasma-chemical reactor during the destruction of inorganic waste. The PChR is equipped with a plasma torch with a nominal capacity of 50 kW and a free-burning arc. The zone of heat release from the atmospheric pressure DC arc cathode and arc anode (melted waste) spot is combined with the area of chemical reactions. The plasma torch (PT) parameters vary in the range of arc current I = 120–180 A, arc voltage U = 250–280 V, arc length x = 0–100 mm, and gas flow rate G = 1–3 g/s at atmospheric pressure, using air as the plasma-forming gas. The experimental results confirmed that plasma technology has several advantages over conventional incineration, including higher temperatures, heat source independence from the waste being processed or additional fuel, and a shorter exposure time in the high-temperature area. It was determined that the arc current increases with increasing arc length. With increasing arc length, the initial part begins to operate in a turbulent regime. This study determines the dependence on the heat flux transferred by electrons to the anode on the arc current. The convective heat flux density distribution over the anode heating spot was measured and discussed.
As the world’s population grows and resource consumption rises, there will be an increase in household waste and, consequently, the fly ash and slag from after the incineration of this waste need to be properly recycled or used as secondary raw materials in other industries. The authors of this work propose an innovative technology that has not yet been studied much in the literature; the obtained slag and fly ash are processed by plasma technology, and from those, fiber is formed. As shown by SEM studies, the raw material (before plasma–chemical treatment) consists of irregularly shaped granules or rod-shaped microforms. EDS studies show that both the original material and the products obtained after plasma–chemical processing are composed of various metal elements, but they make up a significantly small part, as the predominant elements are C, O, Cl, Si, and Ca. BET studies show that when the fiber is obtained with a plasma torch power of 55.5; 55.6 and 74 kW, respectively, the specific surface area is 11.9; 8.5 and 3 m2/g. It is worth noting that the raw material obtained after plasma–chemical processing is sufficiently clean and harmless to the environment, so it can be used as a secondary raw material, e.g., for the production of thermal insulation, in the production of catalysts, as a component in the production of concrete, or in other industries.