High quality long-term data sets of altitude-resolved measurements of the atmospheric composition are important because they can be used both to study the evolution of the atmosphere and as a benchmark for future missions. For the final ESA reprocessing of MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) on ENVISAT (ENViromental SATellite) data, numerous improvements were implemented in the Level 2 (L2) processor Optimised Retrieval Model (ORM) version 8.22 (V8) and its auxiliary data. The implemented changes involve all aspects of the processing chain, from the modelling of the measurements with the handling of the horizontal inhomogeneities along the line of sight to the use of the optimal estimation technique to retrieve the minor species, from a more sensitive approach to detecting the spectra affected by clouds to a refined method for identifying low quality products. Improvements in the modelling of the measurements were also obtained with an update of the used spectroscopic data and of the databases providing the a priori knowledge of the atmosphere. The HITRAN_mipas_pf4.45 spectroscopic database was finalised with new spectroscopic data verified with MIPAS measurements themselves, while recently measured cross-sections were used for the heavy molecules. The Level 2 Initial Guess (IG2) data set, containing the climatology used by the MIPAS L2 processor to generate the initial guess and interfering species profiles when the retrieved profiles from previous scans are not available, was improved taking into account the diurnal variation of the profiles defined using climatologies from both measurements and models. Horizontal gradients were generated using the ECMWF ERA-Interim data closest in time and space to the MIPAS data. Further improvements in the L2 V8 products derived from the use of the L1b V8 products, which were upgraded to reduce the instrumental temporal drift and to handle the abrupt changes in the calibration gain. The improvements introduced into the ORM V8 L2 processor and its upgraded auxiliary data, together with the use of the L1b V8 products, lead to the generation of the MIPAS L2 V8 products, which are characterised by an increased accuracy, better temporal stability and a greater number of retrieved species.

The observations acquired during the full mission of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument, aboard the European Space Agency Environmental Satellite (Envisat), have been analysed with version 8.22 of the Optimised Retrieval Model (ORM), originally developed as the scientific prototype of the ESA level-2 processor for MIPAS observations. The results of the analyses have been included into the MIPAS level-2 version 8 (level2-v8) database containing atmospheric fields of pressure, temperature, and volume mixing ratio (VMR) of MIPAS main targets H₂O, O₃, HNO₃, CH₄, N₂O, and NO₂, along with the minor gases CFC-11, ClONO₂, N₂O₅, CFC-12, COF₂, CCl₄, CF₄, HCFC-22, C₂H₂, CH₃Cl, COCl₂, C₂H₆, OCS, and HDO. The database covers all the measurements acquired by MIPAS in the nominal measurement mode of the full resolution (FR) part of the mission (from July 2002 to March 2004) and all the observation modes of the optimised resolution (OR) part (from January 2005 to April 2012). The number of species included in the MIPAS level2-v8 dataset makes it of particular importance for the studies of stratospheric chemistry. The database is considered by ESA the final release of the MIPAS level-2 products. The ORM algorithm is operated at the vertical grid coincident to the tangent altitudes of the observations or to a subset of them, spanning (in the nominal mode) the altitude range from 6 to 68 km in the FR phase and from 6 to 70 km in the OR period. In the latitude domain, FR profiles are spaced by about 4.7^∘, while the OR profiles are spaced by about 3.7^∘. For each retrieved species, the auxiliary data and the retrieval choices are described. Each product is characterised in terms of the retrieval error, spatial resolution, and “useful” vertical range in both phases of the MIPAS mission. These depend on the characteristics of the measurements (spectral and vertical resolution of the measurements), the retrieval choices (number of spectral points included in the analyses, number of altitudes included in the vertical retrieval grid), and the information content of the measurements for each trace species. For temperature, water vapour, ozone, and nitric acid, the number of degrees of freedom is significantly larger in the OR phase than in the FR one, mainly due to the finer vertical measurement grid. In the FR phase, some trace species are characterised by a smaller retrieval error with respect to the OR phase, mainly due to the larger number of spectral points used in the analyses, along with the reduced vertical resolution. The way of handling possible caveats (negative VMR, vertical grid representation) is discussed. The quality of the retrieved profiles is assessed through four criteria, two providing information on the successful convergence of the retrieval iterations, one on the capability of the retrieval to reproduce the measurements, and one on the presence of outliers. An easy way to identify and filter the problematic profiles with the information contained in the output files is provided. MIPAS level2-v8 data are available to the scientific community through the ESA portal (https://doi.org/10.5270/EN1-c8hgqx4).

With the launch of the Sentinel-5 Precursor (S-5P, lifted-off on 13 October 2017), Sentinel-4 (S-4) and Sentinel-5 (S-5)(from 2021 and 2023 onwards, respectively) operational missions of the ESA/EU Copernicus program, a massive amount of atmospheric composition data with unprecedented quality will become available from geostationary (GEO) and low Earth orbit (LEO) observations. Enhanced observational capabilities are expected to foster deeper insight than ever before on key issues relevant for air quality, stratospheric ozone, solar radiation, and climate. A major potential strength of the Sentinel observations lies in the exploitation of complementary information that originates from simultaneous and independent satellite measurements of the same air mass. The core purpose of the AURORA (Advanced Ultraviolet Radiation and Ozone Retrieval for Applications) project is to investigate this exploitation from a novel approach for merging data acquired in different spectral regions from on board the GEO and LEO platforms. A data processing chain is implemented and tested on synthetic observations. A new data algorithm combines the ultraviolet, visible and thermal infrared ozone products into S-4 and S-5(P) fused profiles. These fused products are then ingested into state-of-the-art data assimilation systems to obtain a unique ozone profile in analyses and forecasts mode. A comparative evaluation and validation of fused products assimilation versus the assimilation of the operational products will seek to demonstrate the improvements achieved by the proposed approach. This contribution provides a first general overview of the project, and discusses both the challenges of developing a technological infrastructure for implementing the AURORA concept, and the potential for applications of AURORA derived products, such as tropospheric ozone and UV surface radiation, in sectors such as air quality monitoring and health.

The Far-Infrared Radiation Mobile Observation System (FIRMOS) is a Fourier transform spectroradiometer developed to support the Far-infrared Outgoing Radiation Understanding and Monitoring (FORUM) satellite mission by validating measurement methods and instrument design concepts, both in the laboratory and in field campaigns. FIRMOS is capable of measuring the downwelling spectral radiance emitted by the atmosphere in the spectral band from 100 to 1000 cm⁻¹ (10–100 µm in wavelength), with a maximum spectral resolution of 0.25 cm⁻¹. We describe the instrument design and its characterization and discuss the geophysical products obtained by inverting the atmospheric spectral radiance measured during a campaign from the high-altitude location of Mount Zugspitze in Germany, beside the Extended-range Atmospheric Emitted Radiance Interferometer (E-AERI), which is permanently installed at the site. Following the selection of clear-sky scenes, using a specific algorithm, the water vapour and temperature profiles were retrieved from the FIRMOS spectra by applying the Kyoto protocol and Informed Management of the Adaptation (KLIMA) code. The profiles were found in very good agreement with those provided by radiosondes and by the Raman lidar operating from the Zugspitze Schneefernerhaus station. In addition, the retrieval products were validated by comparing the retrieved integrated water vapour values with those obtained from the E-AERI spectra.

The new platforms for Earth observation from space are characterized by measurements made at great spatial and temporal resolutions. While this abundance of information makes it possible to detect and study localized phenomena, it may be difficult to manage this large amount of data for the study of global and large-scale phenomena. A particularly significant example is the use by assimilation systems of Level 2 products that represent gas profiles in the atmosphere. The models on which assimilation systems are based are discretized on spatial grids with horizontal dimensions of the order of tens of kilometres in which tens or hundreds of measurements may fall in the future. A simple procedure to overcome this problem is to extract a subset of the original measurements, but this involves a loss of information. Another option is the use of simple averages of the profiles, but this approach also has some limitations that we will discuss in the paper. A more advanced solution is to resort to the so-called fusion algorithms, capable of compressing the size of the dataset while limiting the information loss. A novel data fusion method, the Complete Data Fusion algorithm, was recently developed to merge a set of retrieved products in a single product a posteriori. In the present paper, we apply the Complete Data Fusion method to ozone profile measurements simulated in the thermal infrared and ultraviolet bands in a realistic scenario. Following this, the fused products are compared with the input profiles; comparisons show that the output products of data fusion have smaller total errors and higher information contents in general. The comparisons of the fused products with the fusing products are presented both at single fusion grid box scale and with a statistical analysis of the results obtained on large sets of fusion grid boxes of the same size. We also evaluate the grid box size impact, showing that the Complete Data Fusion method can be used with different grid box sizes even if this possibility is connected to the natural variability of the considered atmospheric molecule.

Atmospheric emissions of carbon tetrachloride (CCl₄) are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule has been the subject of recent increased interest as a consequence of the so-called mystery of CCl₄, the discrepancy between atmospheric observations and reported production and consumption. Surface measurements of CCl₄ atmospheric concentrations have declined at a rate almost 3 times lower than its lifetime-limited rate, suggesting persistent atmospheric emissions despite the ban. In this paper, we study CCl₄ vertical and zonal distributions in the upper troposphere and lower stratosphere (including the photolytic loss region, 70–20 hPa), its trend, and its stratospheric lifetime using measurements from the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), which operated onboard the ENVISAT satellite from 2002 to 2012. Specifically, we use the MIPAS data product generated with Version 7 of the Level 2 algorithm operated by the European Space Agency. The CCl₄ zonal means show features typical of long-lived species of anthropogenic origin that are destroyed primarily in the stratosphere, with larger quantities in the troposphere and a monotonic decrease with increasing altitude in the stratosphere. MIPAS CCl₄ measurements have been compared with independent measurements from other satellite and balloon-borne remote sounders, showing a good agreement between the different datasets. CCl₄ trends are calculated as a function of both latitude and altitude. Negative trends of about −10 to −15 pptv decade⁻¹ (−10 to −30 % decade⁻¹) are found at all latitudes in the upper troposphere–lower stratosphere region, apart from a region in the southern midlatitudes between 50 and 10 hPa where the trend is positive with values around 5–10 pptv decade⁻¹ (15–20 % decade⁻¹). At the lowest altitudes sounded by MIPAS, we find trends consistent with those determined on the basis of long-term ground-based measurements (−10 to −13 pptv decade⁻¹). For higher altitudes, the trend shows a pronounced asymmetry between the Northern and Southern hemispheres, and the magnitude of the decline rate increases with altitude. We use a simplified model assuming tracer–tracer linear correlations to determine CCl₄ lifetime in the lower stratosphere. The calculation provides a global average lifetime of 47 (39–61) years, considering CFC-11 as the reference tracer. This value is consistent with the most recent literature result of 44 (36–58) years.