Poly(vinylalcohol)/reduced graphite oxide nanocomposites have been synthesised by reducing graphite oxide in the presence of the polymer matrix and coagulating the system with 2-propanol. It has been observed that some interactions occur between the polymer and the reduced graphite oxide layers, mainly by hydrogen bonding. These interactions are responsible for a remarkable change in the thermal behaviour of the nanocomposites. In addition, high electrical conductivity has been achieved at concentrations beyond 7.5 wt% of reduced graphite oxide (∼0.1 S cm⁻¹), with a percolation threshold between 0.5 and 1 wt%.

The performance of chemical sensors based on polymer nanocomposites with CNTs and graphene is revised, highlighting the role of the polymeric material.