We propose a ‘Waste to Carbon’ thermal transformation of sewage sludge (SS) via torrefaction to a valuable product (fuel) with a high content of carbon. One important, technological aspect to develop this concept is the determination of activation energy needed for torrefaction. Thus, this research aimed to evaluate the kinetics of SS torrefaction and determine the effects of process temperature on fuel properties of torrefied products (biochars). Torrefaction was performed using high ash content SS at six (200~300 °C) temperatures and 60 min residence (process) time. Mass loss during torrefaction ranged from 10~20%. The resulting activation energy for SS torrefaction was ~12.007 kJ·mol⁻¹. Initial (unprocessed) SS higher heating value (HHV) was 13.5 MJ·kg⁻¹. However, the increase of torrefaction temperature decreased HHV from 13.4 to 3.8 MJ·kg⁻¹. Elemental analysis showed a significant decrease of the H/C ratio that occurred during torrefaction, while the O/C ratio fluctuated with much smaller differences. Although the activation energy was significantly lower compared with lignocellulosic materials, low-temperature SS torrefaction technology could be explored for further SS stabilization and utilization (e.g., dewatering and hygienization).

Sewage sludge (SS) recycling is an important part of the proposed ‘circular economy’ concept. SS can be valorized via torrefaction (also known as ‘low-temperature pyrolysis’ or ‘roasting’). SS can, therefore, be considered a low-quality fuel or a source of nutrients essential for plant growth. Biochar produced by torrefaction of SS is a form of carbonized fuel or fertilizer. In this research, for the first time, we tested the feasibility of torrefaction of SS with high ash content for either fuel or organic fertilizer production. The research was conducted in 18 variants (six torrefaction temperatures between 200~300 °C, and three process residence times of 20, 40, 60 min) in 5 repetitions. Fuel and fertilizer properties and multiple regression analysis of produced biochar were conducted. The higher heating value (HHV) of raw SS was 21.2 MJ·kg⁻¹. Produced biochar was characterized by HHV up to 12.85 MJ·kg⁻¹ and lower H/C and O/C molar ratio. Therefore, torrefaction of SS with high ash content should not be considered as a method for improving the fuel properties. Instead, the production of fertilizer appears to be favorable. The torrefaction increased C, N, Mg, Ca, K, Na concentration in relation to raw SS. No significant (p < 0.05) influence of the increase of temperature and residence time on the increase of biogenic elements in biochar was found, however the highest biogenic element content, were found in biochar produced for 60 min, under the temperature ranging from 200 to 240 °C. Obtained biochars met the Polish regulatory criteria for mineral-organic fertilizer. Therefore SS torrefaction may be considered a feasible waste recycling technology. The calculation of torrefaction energy and the mass balance shows energy demand <2.5 GJ∙Mg⁻¹ w.m., and the expected mass yield of the product, organic fertilizer, is ~178 kg∙Mg⁻¹ w.m of SS. Further investigation should consider the scaling-up of the SS torrefaction process, with the application of other types of SSs.

The influence of sewage sludge torrefaction temperature on fuel properties was investigated. Non-lignocellulosic waste thermal treatment experiment was conducted within 1 h residence time, under the following temperatures: 200, 220, 240, 260, 280 and 300°C. Sawdust was used as lignocellulosic reference material. The following parameters of biochar have been measured: moisture, higher heating value, ash content, volatile compounds and sulfur content. Sawdust biochar has been confirmed to be a good quality solid fuel. High ash and sulfur content may be an obstacle for biochar energy reuse. The best temperature profile for sawdust torrefaction and fuel production for 1 h residence time was 220°C. At this temperature the product contained 84% of initial energy while decreased the mass by 25%. The best temperature profile for sewage sludge was 240°C. The energy residue was 91% and the mass residue was 85%. Higher temperatures in both cases caused excessive mass and energy losses.

Digestate from a biogas plant can be a valuable organic and mineral fertilizer. Quantitative proportions of co-substrates used in three agricultural biogas plants in Poland were analyzed. The composition of digestates was examined and large differences in the content of macronutrients were found,...

Energy production from renewable sources is one of the main ways to fight against global warming. Anaerobic digestion process can be used to produce biogas containing methane. In the light of the growing demand for substrates, a variety of raw materials are required. These substrates should be suitable for anaerobic digestion, and processing them need to provide the desired amount of energy. This paper aims to discuss the agricultural biogas market in Poland, its current state, and the possibility of development during energy transformation, in particular in terms of using waste as a substrate for energy production. In February 2022, there were 130 agricultural biogas plants registered in Poland. On the other hand, in 2020, 4,409,054.898 Mg of raw materials were used to produce agricultural biogas in Poland. Among all the substrates used, waste played a special role. With the right amount of raw materials and proper management of a biogas plant, it is possible to produce electricity and provide stable and predictable heat supply. Bearing in mind the development of the Polish and European biogas markets, attention should be paid to ensure access to raw materials from which chemical energy in the form of biogas can be generated. Due to limited access to farmland and the increasing demand for food production, one should expect that waste will be increasingly often used for biogas production, especially that with high energy potential, such as waste related to animal production and the meat industry.