Transparent binder is used to substitute conventional black asphalt binder and to provide light-colored pavements, whereas nano-TiO₂ has the potential to promote photocatalytic and self-cleaning properties. Together, these materials provide multifunction effects and benefits when the pavement is submitted to high solar irradiation. This paper analyzes the physicochemical and rheological properties of a transparent binder modified with 0.5%, 3.0%, 6.0%, and 10.0% nano-TiO₂ and compares it to the transparent base binder and conventional and polymer modified binders (PMB) without nano-TiO₂. Their penetration, softening point, dynamic viscosity, master curve, black diagram, Linear Amplitude Sweep (LAS), Multiple Stress Creep Recovery (MSCR), and Fourier Transform Infrared Spectroscopy (FTIR) were obtained. The transparent binders (base and modified) seem to be workable considering their viscosity, and exhibited values between the conventional binder and PMB with respect to rutting resistance, penetration, and softening point. They showed similar behavior to the PMB, demonstrating signs of polymer modification. The addition of TiO₂ seemed to reduce fatigue life, except for the 0.5% content. Nevertheless, its addition in high contents increased the rutting resistance. The TiO₂ modification seems to have little effect on the chemical functional indices. The best percentage of TiO₂ was 0.5%, with respect to fatigue, and 10.0% with respect to permanent deformation.

The utilization of Reclaimed Asphalt (RA) in the road construction sector induces considerable economic and ecological benefits. The blending of the recycled material with new components is believed to be of great importance for the mixture’s properties. An extensive knowledge of the blending of the materials is crucial in optimizing the use of RA, especially at higher recycling rates. In this paper, the applicability of Fourier transform infrared (FTIR) microscopy in attenuated total reflectance (ATR) mode to study the bituminous coating of RA granulates is investigated. This method is a promising alternative to trace heterogeneous areas within the coating compared to methods that require extraction and recovery of bitumen. A method for sample preparation and FTIR spectra analysis is proposed. Four different samples were analyzed: a reference RA granulate, two types of RA granulates mixed with neat bitumen, and a RA granulate with rejuvenator. The results show that the use of ATR-FTIR microscope allows the tracing of different components, indications of blending, as well as proof of rejuvenation of the aged bituminous area.

The fatigue performance and healing ability of asphalt pavements are important for mixture design, rehabilitation, and maintenance of the roads. By analyzing these parameters in an asphalt mixture, it is possible to predict the crack formation and propagation in asphalt pavements and healing of these cracks during the rest periods. The healing effect in asphalt mixtures has been observed and verified by many researchers and different methods exist to evaluate this phenomenon. However, current methods are still inadequate to fully observe and quantify the healing phenomenon in asphalt mixtures. In this study, a digital image correlation (DIC) method is used to calculate the strain map on the surface of cylindrical asphalt specimens during the indirect tensile fatigue test. This strain map is used to detect the location of crack initiations and development of the microcracks during the experiments. Next, the specimens are unloaded and the temperature of the climate chamber is increased to 60 °C for 18 h to investigate the healing phenomenon on the surface of the specimens. It is observed that the strain reduces near the microcrack areas especially at the tip of the microcracks. Furthermore, using DIC it is possible to observe the healing rate and the minimum time required to heal the microcracks on the surface of the specimens.

Incorporating reclaimed asphalt (RA) in surface layer mixtures is still limited due to performance concerns, and it becomes even more challenging when combining aged polymer-modified bitumen (PMB) with virgin PMB. This study aims to evaluate, from a binder perspective, the feasibility of incorporating reclaimed polymer-modified binder (RPMB) in new surface layer mixtures. To address this challenge, blends of RPMB and virgin PMB were investigated at three replacement rates (20%, 40% and 60%) with and without a tall oil-based rejuvenator. First, the viscoelastic behaviour of the blends was assessed using a dynamic shear rheometer. Moreover, physicochemical changes were tracked using infrared spectroscopy and fluorescence microscopy. The experimental investigation revealed that, due to polymer degradation of the RMPB, only the blends with 20% RMPB exhibited polymer activity. Finally, the use of the rejuvenator compensated for the rheological properties of the aged RPMB and reduced the susceptibility to non-load-associated cracking.

Rheological characterisation methods are important when it comes to a performance-based selection system for bituminous binders for road applications. Standardised methods exist for the determination of bitumen rheological behaviour based on a dynamic shear rheometer (DSR) at intermediate and high service temperatures and a bending beam rheometer (BBR) at low temperatures. Recently, a dynamic shear rheometer with 4 mm parallel plates (4-mm DSR), has been proposed by Western Research Institute (WRI), as a promising method to determine the rheological behaviour at low temperatures. Clear advantages of the 4-mm DSR are related to the small sample size, especially important for recovered and aged binders, and the ability to work with adequate stresses at very low temperatures. Furthermore, if 4-mm DSR can be used to assess the low temperature behaviour of bitumen, then the performance of a binder in the whole range of service temperatures, could be assessed by just one equipment, a DSR. This paper focuses on the challenges related to 4-mm DSR tests regarding equipment preparation, with a specific attention to the temperature assessment and calibration. Furthermore, a sample preparation method, assuring good adhesion to both plates is proposed and the repeatability and reproducibility of 4-mm DSR tests is evaluated.