The integration of conductive materials in textiles is key for detecting temperature in the wearer´s environment. When integrating sensors into textiles, properties such as their flexibility, handle, and stretch must stay unaffected by the functionalization. Conductive materials are difficult to integrate into textiles, since wires are stiff, and coatings show low adhesion. This work shows that various substrates such as cotton, cellulose, polymeric, carbon, and optical fiber-based textiles are used as support materials for temperature sensors. Suitable measurement principles for use in textiles are based on resistance changes, optical interferences (fiber Bragg grating), or thermoelectric effects. This review deals with developments in the construction of temperature sensors and the production of thermocouples for use in textiles. The operating principle of thermocouples is based on temperature gradients building up between a heated and a cold junction of two conductors, which is converted to a voltage output signal. This work also summarizes integration methods for thermocouples and other temperature-sensing techniques as well as the manufacture of conductive materials in textiles. In addition, textile thermocouples are emphasized as suitable and indispensable elements in sensor concepts for smart textiles.

Integration of sensors in textile garments requires the development of flexible conductive structures. In this work, cellulose-based woven lyocell fabrics were coated with copper during an electroless step, produced at 0.0284 M copper sulfate pentahydrate, 0.079 M potassium hydrogen L-tartrate, and 0.94 M formaldehyde concentrations. High concentrations led to high homogeneous copper reaction rates and the heterogeneous copper deposition process was diffusion controlled. Thus, the rate of copper deposition did not increase on the cellulose surface. Conductivity of copper coatings was investigated by the resistance with a four probe technique during fabric deformation. In cyclic tensile tests, the resistance of coated fabric (19 × 1.5 cm²) decreased from 13.2–3.7 Ω at 2.2% elongation. In flex tests, the resistance increased from 5.2–6.6 Ω after 5000 bending cycles. After repeated wetting and drying cycles, the resistance increased by 2.6 × 10⁵. The resistance raised from 11–23 Ω/square with increasing relative humidity from 20–80%, which is likely due to hygroscopic expansion of fibers. This work improves the understanding of conductive copper coating on textiles and shows their applicability in flexible strain sensors.

Development of colored surfaces by formation of nano-structured aggregates is a widely used strategy in nature to color lightweight structures (e.g. butterflies) without the use of dye pigments. The deposition of nanoscale particles mimics nature in it’s approach coloring surfaces. This work presents sol-gel modification of cellulose surfaces used to form a template for growth of Cu/Cu₂O core-shell particles with defined size-distributions. Besides improving the adhesion of the deposited particulate material, the sol-gel matrix serves as a template for the control of particle sizes of the Cu/Cu₂O structures, and as a consequence of particle size variation the surface color is tunable. As an example, red color was achieved with an average particle size of 35 nm, and shifts gradually to blue appearance when particles have grown to 80 nm on the sol-gel modified fabric. The copper concentration on representative fabrics is kept low to avoid modifying the textile characteristics and were all in the range of 150–170 mg per g of cellulose material. As a result of copper deposition on the surface of the material, the cellulose fabric also became electrically conductive. Remarkably, the electrical conductivity was found to be dependent on the average particle sizes of the deposits and thus related to the change in observed color. The generation of color by growth of nano-sized particles on sol-gel templates provides a highly promising approach to stain surfaces by physical effects without use of synthetic colorants, which opens a new strategy to improve environmental profile of coloration.