Condensate-liquid accumulation in the vicinity of a well is known to curtail gas production up to 80%. Numerous approaches are employed to mitigate condensate banking and improve gas productivity. In this work, a field-scale simulation is presented for condensate damage removal in tight reservoirs using a thermochemical treatment strategy where heat and pressure are generated in situ. The impact of thermochemical injection on the gas recovery is also elucidated. A compositional simulator was utilized to assess the effectiveness of the suggested treatment on reducing the condensate damage and, thereby, improve the gas recovery. Compared to the base case, represented by an industry-standard gas injection strategy, simulation studies suggest a significantly improved hydrocarbon recovery performance upon thermochemical treatment of the near-wellbore zone. For the scenarios investigated, the application of thermochemicals allowed for an extension of the production plateau from 104 days, as determined for the reference gas injection case, to 683 days. This represents a 6.5-fold increase in production plateau time, boosting gas recovery from 25 to 89%. The improved recovery is attributed to the reduction of both capillary pressure and condensate viscosity. The presented work is crucial for designing and implementing thermochemical treatments in tight-gas reservoirs.

The process of well cleanup involves the removal of an impermeable layer of filter cake from the face of the formation. The inefficient removal of the filter cake imposes difficulty on fracturing operations. Filter cake’s impermeable features increase the required pressure to fracture the formation. In this study, a novel method is introduced to reduce the required breakdown pressure to fracture the formation containing the water-based drilling fluid filter cake. The breakdown pressure was tested for five samples of similar properties using different solutions. A simulated borehole was drilled in the core samples. An impermeable filter cake using barite-weighted drilling fluid was built on the face of the drilled hole of each sample. The breakdown pressure for the virgin sample without damage (filter cake) was 6.9 MPa. The breakdown pressure increased to 26.7 MPa after the formation of an impermeable filter cake. Partial removal of filter cake by chelating agent reduced the breakdown pressure to 17.9 MPa. Complete dissolution of the filter cake with chelating agents resulted in the breakdown pressure approximately equivalent to the virgin rock breakdown pressure, i.e., 6.8 MPa. The combined thermochemical and chelating agent solution removed the filter cake and reduced the breakdown pressure to 3.8 MPa. Post-treatment analysis was carried out using nuclear magnetic resonance (NMR) and scratch test. NMR showed the pore size redistributions with good communication between different pores after the thermochemical removal of filter cake. At the same time, there was no communication between the different pores due to permeability impairment after filter cake formation. The diffusion coupling through NMR scans confirmed the higher interconnectivity between different pores systems after the combined thermochemical and chelating agent treatment. Compressive strength was measured from the scratch test, confirming that filter cake formation caused added strength to the rock that impacts the rock breakdown pressure. The average compressive strength of the original specimen was 44.5 MPa that increased to 73.5 MPa after the formation of filter cake. When the filter cake was partially removed, the strength was reduced to 61.7 MPa. Complete removal with chelating agents removed the extra strength that was added due to the filter cake presence. Thermochemical and chelating agents resulted in a significantly lower compressive strength of 25.3 MPa. A numerical model was created to observe the reduction in breakdown pressure due to the thermochemical treatment of the filter cake. The result presented in this study showed the engineering applications of thermochemical treatment for filter cake removal.

The distribution of acid over all layers of interest is a critical measure of matrix acidizing efficiency. Chemical and mechanical techniques have been widely adapted for enhancing acid diversion. However, it was demonstrated that these often impact the formation with damage after the acid job is completed. This study introduces, for the first time, a novel solution to improve acid diversion using thermochemical fluids. This method involves generating nitrogen gas at the downhole condition, where the generated gas will contribute in diverting the injected acids into low-permeability formations. In this work, both lab-scale numerical and field-scale analytical models were developed to evaluate the performance of the proposed technique. In addition, experimental measurements were carried out in order to demonstrate the application of thermochemical in improving the acid diversion. The results showed that a thermochemical approach has an effective performance in diverting the injected acids into low-permeability rocks. After treatment, continuous wormholes were generated in the high-permeability rocks as well as in low-permeability rocks. The lab-scale model was able to replicate the wormholing impact observed in the lab. In addition, alternating injection of thermochemical and acid fluids reduced the acid volume 3.6 times compared to the single stage of thermochemical injection. Finally, sensitivity analysis indicates that the formation porosity and permeability have major impacts on the acidizing treatment, while the formations pressures have minor effect on the diversion performance.

Unconventional reservoirs have shown tremendous potential for energy supply for long-term applications. However, great challenges are associated with hydrocarbon production from these reservoirs. Recently, injection of thermochemical fluids has been introduced as a new environmentally friendly and cost-effective chemical for improving hydrocarbon production. This research aims to improve gas production from gas condensate reservoirs using environmentally friendly chemicals. Further, the impact of thermochemical treatment on changing the pore size distribution is studied. Several experiments were conducted, including chemical injection, routine core analysis, and nuclear magnetic resonance (NMR) measurements. The impact of thermochemical treatment in sustaining gas production from a tight gas reservoir was quantified. This study demonstrates that thermochemical treatment can create different types of fractures (single or multistaged fractures) based on the injection method. Thermochemical treatment can increase absolute permeability up to 500%, reduce capillary pressure by 57%, remove the accumulated liquids, and improve gas relative permeability by a factor of 1.2. The findings of this study can help to design a better thermochemical treatment for improving gas recovery. This study showed that thermochemical treatment is an effective method for sustaining gas production from tight gas reservoirs.

Deformational and breakage behaviors of concrete and cement mortar greatly influence various engineering structures, such as dams, river bridges, ports, tunnels, and offshore rig platforms. The mechanical and petrophysical properties are very sensitive to water content and are controlled by the liquid part in pore spaces to a large extent. The objective of this paper is to investigate the water saturation effect on the strength characteristics and deformability of cement mortar under two loading conditions, static and dynamic compression. A set of cement mortar samples was prepared and tested to study the mechanical behavior in dry and saturated states. The first part of the research incorporates the study of static mechanical properties for dry and brine-saturated cement mortar through uniaxial compressive strength tests (UCS). Second, drop-weight impact experiments were carried out to study the dynamic mechanical properties (impact resistance, deformation pattern, and fracture geometry) for dry and saturated cases. The comparative analysis revealed that water saturation caused substantial changes in compressive strength and other mechanical characteristics. Under static loading, water saturation caused a reduction in strength of 36%, and cement mortar tended to behave in a more ductile manner as compared to dry samples. On the contrary, under dynamic loading conditions, water saturation resulted in higher impact resistance and fracture toughness as compared to dry conditions. In addition, fractures could propagate to smaller depths as compared to dry case. The study will help resolve many civil, mining, and petroleum engineering problems where cement structures undergo static as well as dynamic compression, especially in a hydraulic environment where these structures interact with the water frequently. To the best of our knowledge, the effect of water saturation on the dynamic mechanical properties of cement mortar has not been well understood and reported in the literature.