Fe-Al-Si alloys have been recently developed in order to obtain excellent high-temperature mechanical properties and oxidation resistance. However, their production by conventional metallurgical processes is problematic. In this work, an innovative processing method, based on ultra-high energy mechanical alloying, has been tested for the preparation of these alloys. It has been found that the powders of low-silicon alloys (up to 10 wt. %) consist of FeAl phase supersaturated by Si after mechanical alloying. Fe₂Al₅ phase forms as a transient phase at the initial stage of mechanical alloying. The alloy containing 20 wt. % of Si and 20 wt. % of Al is composed mostly of iron silicides (Fe₃Si and FeSi) and FeAl ordered phase. Thermal stability of the mechanically alloyed powders was studied in order to predict the sintering behavior during possible compaction via spark plasma sintering or other methods. The formation of Fe₂Al₅ phase and Fe₃Si or Fe₂Al₃Si₃ phases was detected after annealing depending on the alloy composition. It implies that the powders after mechanical alloying are in a metastable state; therefore, chemical reactions can be expected in the powders during sintering.

Hot working tool steel (AISI H13) is one of the most common die materials used in casting industries. A die suffers from damage due to friction and wear during its lifetime. Therefore, various methods have been developed for its repair to save costs to manufacture a new one. A great benefit of laser additive manufacturing (cladding) is the 3D high production rate with minimal influence of thermal stresses in comparison with conventional arc methods. Residual stresses are important factors that influence the performance of the product, especially fatigue life. Therefore, the aim of this contribution is to correlate the wide range of results for multilayer cladding of H13 tool steel. X-ray and neutron diffraction experiments were performed to fully describe the residual stresses generated during cladding. Additionally, in-situ tensile testing experiments inside a scanning electron microscope were performed to observe microstructural changes during deformation. The results were compared with local hardness and wear measurements. Because laser cladding does not achieve adequate accuracy, the effect of necessary post-grinding was investigated. According to the findings, the overlapping of beads and their mutual tempering significantly affect the mechanical properties. Further, the outer surface layer, which showed tensile surface residual stresses and cracks, was removed by grinding and surface compressive residual stresses were described on the ground surface.