Deep eutectic solvents (DESs) are a potentially high-value lignin extraction methodology. DESs prepared from choline chloride (ChCl) and three hydrogen-bond donors (HBD)—lactic acid (Lac), glycerol, and urea—were evaluated for isolation of willow (Salix matsudana cv. Zhuliu) lignin. DESs types, mole ratio of ChCl to HBD, extraction temperature, and time on the fractionated DES-lignin yield demonstrated that the optimal DES-lignin yield (91.8 wt % based on the initial lignin in willow) with high purity of 94.5% can be reached at a ChCl-to-Lac molar ratio of 1:10, extraction temperature of 120 °C, and time of 12 h. Fourier transform infrared spectroscopy (FT-IR) , ¹³C-NMR, and ³¹P-NMR showed that willow lignin extracted by ChCl-Lac was mainly composed of syringyl and guaiacyl units. Serendipitously, a majority of the glucan in willow was preserved after ChCl-Lac treatment.

The poor barrier properties and hygroscopic nature of cellulosic paper impede the wide application of cellulosic paper as a packaging material. Herein, a polyvinyl alcohol (PVA)-based polymer coating was used to improve the barrier performance of paper through its good ability to form a film. Alkyl ketene dimer (AKD) was used to enhance the water resistance. The effect of the absorptive characteristics of the base paper on the barrier properties was explored, and it was shown that surface-sized base paper provides a better barrier performance than unsized base paper. Nanoclay (Cloisite Na⁺) was used in the coating formulation to further enhance the barrier performance. The results show that the coating of PVA/AKD/nanoclay dispersion noticeably improved the barrier performance of the paper. The water vapor transmission rate of the base paper was 533 g/m²·day, and it decreased sharply to 1.3 g/m²·day after the application of a double coating because of the complete coverage of the base paper by the PVA-based polymer coating. The coated paper had excellent water resistance owing to its high water contact angle of around 100°. The grease resistance and mechanical properties of the base paper also improved after coating. This work may provide inspiration for improving the barrier properties of packaging paper through the selection of a suitable base paper and coating formulation.

Lignin nanomaterials have wide application prospects in the fields of cosmetics delivery, energy storage, and environmental governance. In this study, we developed a simple and sustainable synthesis approach to produce uniform lignin nanoparticles (LNPs) by dissolving industrial lignin in deep eutectic solvents (DESs) followed by a self-assembling process. LNPs with high yield could be obtained through nanoprecipitation. The LNPs were characterized by dynamic light scattering (DLS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and gel permeation chromatography (GPC). Distinct LNPs could be produced by changing the type of DES, lignin sources, pre-dropping lignin concentration, and the pH of the system. Their diameter is in the range of 20–200 nm and they show excellent dispersibility and superior long-term stability. The method of preparing LNPs from lignin–DES with water as an anti-solvent is simple, rapid, and environmentally friendly. The outcome aids to further the advancement of lignin-based nanotechnology.

Flexible Zn–air batteries are typically constrained by their sluggish oxygen electrocatalysis, unstable electrochemical interface, and consequently restricted operational temperature range. Accordingly, in this work, we propose the fabrication of wide-temperature flexible Zn–air batteries using wood. Specifically, lignin in wood could be converted into Fe-cluster-enhanced asymmetric single-atom catalysts, acting as an air cathode. Additionally, cellulose in wood underwent interpenetrating polymerization with polyvinyl alcohol for the preparation of an organohydrogel electrolyte. The optimized catalyst sample exhibited an exceptional oxygen reduction reaction performance (E_1/2 = 0.9 V) and endowed Zn–air batteries with long-term stability of over 425 h at 20 mA cm⁻². Furthermore, benefiting from the cellulose-based organohydrogel electrolyte, the wide-temperature flexible Zn–air batteries could be cycled stably for over 115 h (5 mA cm⁻²) at 25 °C. In addition, the adaptability of these batteries was explored over a wide temperature range (−60 °C to 50 °C). This approach, i.e., the fabrication of wood-derived wide-temperature flexible Zn–air batteries, holds promise for the preparation of high-performance electrocatalysts and solid electrolytes intended for future energy storage.