Environmental pollution, particularly from heavy metal ions in the wastewater, is one of the most serious concerns of the world. In the pursuit of remedial action, various conventional methods such as ion exchange, chemical precipitation, coagulation, membrane separation, reverse osmosis, and adsorption methods have so far been used for the removal of heavy metal ions. A good variety of adsorbents have been developed to remove different heavy metal ions from wastewater in particular those which have been detrimental to living organisms. Adsorption processes have been very demanding for high removal efficiency of heavy metal ions even at trace levels and they are low cost as compared to conventional methods. It has therefore been crucial to develop low cost and readily available adsorbents for the adsorption of heavy metal ions from wastewater. The adsorbents may be collected from agricultural and animal waste and industrial by-products. All adsorbents, by their intrinsic nature, have functional groups to play the key role in metal ion adsorption. Generally, chemically modified adsorbents enhance the surface area of the adsorbent and exhibit higher adsorption capacity than unmodified adsorbents. In this review, a series of natural waste materials and their modified forms have been evaluated for the removal of various metals from potable and wastewater. The major focus has been an accumulation of comprehensive knowledge on of the use of the low-cost adsorbents for removal of heavy metal ions.
Nanotechnology is defined as the branch of science dealing with extremely small-sized particles with a size in the range of 1–100 nm, which are termed nanoparticles. Due to the extremely small size of nanoparticles, they display unique electronic and optical properties, which differentiate them from their bulk form. Thus, due to the unique properties of nanoparticles, they play a crucial role in a variety of fields, including the biomedical, environmental, agricultural, and industrial fields. Selenium belongs to Group 16 of the periodic table with an atomic number of 34 and its nanoparticles have been highlighted as a potential material to alleviate several problems due to the formation of biofilms, production of ROS, low redox activity, etc. These nanoparticles can be synthesized through chemical, physical and biological methods. Since existing reviews mainly concentrated on the individual applications of selenium nanoparticles such as in diagnosis and therapeutics, the present review mainly highlights the potential activity of selenium nanoparticles in the biomedical domain, making them a potential theragnostic agent. Specifically, this review will present detailed information on the bioimaging and therapeutic activity, together with the role of selenium nanoparticles in the current scenario of the ongoing pandemic (SARS-CoV-2). It will also focus on procedures for their synthesis and properties that make them potential candidates for applications in various domains. Finally, we provide a detailed future outlook.
Bioinspired metallic nanoparticles (BMN) have revolutionized the biomedical domain and are still developing rapidly. Hence, this review on BMN elaborates the properties, biosynthesis, biomedical applications, and its role in combating the SARS-CoV-2.
New magnetic iron oxide (Fe3O4)/activated charcoal (AC)/β-cyclodextrin (CD)/sodium alginate (Alg) polymer nanocomposite materials were prepared by direct mixing of the polymer matrix with the nanofillers. The obtained materials were utilized as nano-adsorbents for the elimination of methylene blue (MB), a hazardous water-soluble cationic dye, from aqueous solutions, and showed excellent regeneration capacity. The formation of the nanocomposites was followed by high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectrometry (EDX), Fourier-transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and adsorption of N2 at −196 °C. The rate of adsorption was investigated varying several factors, namely contact time, pH, amount of adsorbent and MB concentration on the adsorption process. Studies dealing with equilibrium and kinetics were carried out in batch conditions. The obtained results indicated that the removal rate of MB was 99.53% in 90 min. Langmuir’s isotherm fitted better to the equilibrium data of MB. Fe3O4/AC/CD/Alg polymer beads shows amazing adsorption capacities in the elimination of cationic dyes (2.079 mg/g for polymer gel beads and 10.63 mg g−1 for dry powder beads), in comparison to other adsorbent materials. The obtained adsorbent is spherical with hydrophobic cross-linked surface properties that enable an easy recovery without any significant weight loss of in the adsorbent used.