Airborne particulates are of particular significance for their human health impacts and their roles in both atmospheric radiative transfer and atmospheric chemistry. Observations of airborne particulates are typically made by environmental agencies using rather expensive instruments. Due to the expense of the instruments usually used by environment agencies, the number of sensors that can be deployed is limited. In this study we show that machine learning can be used to effectively calibrate lower cost optical particle counters. For this calibration it is critical that measurements of the atmospheric pressure, humidity, and temperature are also made.

Sunlight incident on the Earth’s atmosphere is essential for life, and it is the driving force of a host of photo-chemical and environmental processes, such as the radiative heating of the atmosphere. We report the description and application of a physical methodology relative to how an ensemble of very low-cost sensors (with a total cost of <$20, less than 0.5% of the cost of the reference sensor) can be used to provide wavelength resolved irradiance spectra with a resolution of 1 nm between 360–780 nm by calibrating against a reference sensor using machine learning. These low-cost sensor ensembles are calibrated using machine learning and can effectively reproduce the observations made by an NIST calibrated reference instrument (Konica Minolta CL-500A with a cost of around USD 6000). The correlation coefficient between the reference sensor and the calibrated low-cost sensor ensemble has been optimized to have $R^2>$ 0.99. Both the circuits used and the code have been made publicly available. By accurately calibrating the low-cost sensors, we are able to distribute a large number of low-cost sensors in a neighborhood scale area. It provides unprecedented spatial and temporal insights into the micro-scale variability of the wavelength resolved irradiance, which is relevant for air quality, environmental and agronomy applications.

Inland waters pose a unique challenge for water quality monitoring by remote sensing techniques due to their complicated spectral features and small-scale variability. At the same time, collecting the reference data needed to calibrate remote sensing data products is both time consuming and expensive. In this study, we present the further development of a robotic team composed of an uncrewed surface vessel (USV) providing in situ reference measurements and an unmanned aerial vehicle (UAV) equipped with a hyperspectral imager. Together, this team is able to address the limitations of existing approaches by enabling the simultaneous collection of hyperspectral imagery with precisely collocated in situ data. We showcase the capabilities of this team using data collected in a northern Texas pond across three days in 2020. Machine learning models for 13 variables are trained using the dataset of paired in situ measurements and coincident reflectance spectra. These models successfully estimate physical variables including temperature, conductivity, pH, and turbidity as well as the concentrations of blue–green algae, colored dissolved organic matter (CDOM), chlorophyll-a, crude oil, optical brighteners, and the ions ${\mathrm{Ca}}^{2+}$, ${\mathrm{Cl}}^{-}$, and ${\mathrm{Na}}^{+}$. We extend the training procedure to utilize conformal prediction to estimate 90% confidence intervals for the output of each trained model. Maps generated by applying the models to the collected images reveal small-scale spatial variability within the pond. This study highlights the value of combining real-time, in situ measurements together with hyperspectral imaging for the rapid characterization of water composition.

This study calibrates an affordable, solar-powered LoRaWAN air quality monitoring prototype using the research-grade Palas Fidas Frog sensor. Motivated by the need for sustainable air quality monitoring in smart city initiatives, this work integrates low-cost, self-sustaining sensors with research-grade instruments, creating a cost-effective hybrid network that enhances both spatial coverage and measurement accuracy. To improve calibration precision, the study leverages the Super Learner machine learning technique, which optimally combines multiple models to achieve robust PM (Particulate Matter) monitoring in low-resource settings. Data was collected by co-locating the Palas sensor and LoRaWAN devices under various climatic conditions to ensure reliability. The LoRaWAN monitor measures PM concentrations alongside meteorological parameters such as temperature, pressure, and humidity. The collected data were calibrated against precise PM concentrations and particle count densities from the Palas sensor. Various regression models were evaluated, with the stacking-based Super Learner model outperforming traditional approaches, achieving an average test R² value of 0.96 across all target variables, including 0.99 for PM_2.5 and 0.91 for PM_10.0. This study presents a novel approach by integrating Super Learner-based calibration with LoRaWAN technology, offering a scalable solution for low-cost, high-accuracy air quality monitoring. The findings demonstrate the feasibility of deploying these sensors in urban areas such as the Dallas-Fort Worth metroplex, providing a valuable tool for researchers and policymakers to address air pollution challenges effectively.

This study aims to provide analyses of the levels of airborne particulate matter (PM) using a two-pronged approach that combines data from in situ Internet of Things (IoT) sensor networks with remotely sensed aerosol optical depth (AOD). Our approach involved setting up a network of custom-designed PM sensors that could be powered by the electrical grid or solar panels. These sensors were strategically placed throughout the densely populated areas of North Texas to collect data on PM levels, weather conditions, and other gases from September 2021 to June 2023. The collected data were then used to create models that predict PM concentrations in different size categories, demonstrating high accuracy with correlation coefficients greater than 0.9. This highlights the importance of collecting hyperlocal data with precise geographic and temporal alignment for PM analysis. Furthermore, we expanded our analysis to a national scale by developing machine learning models that estimate hourly PM${ }_{2.5}$ levels throughout the continental United States. These models used high-resolution data from the Geostationary Operational Environmental Satellites (GOES-16) Aerosol Optical Depth (AOD) dataset, along with meteorological data from the European Center for Medium-Range Weather Forecasting (ECMWF), AOD reanalysis, and air pollutant information from the MERRA-2 database, covering the period from January 2020 to June 2023. Our models were refined using ground truth data from our IoT sensor network, the OpenAQ network, and the National Environmental Protection Agency (EPA) network, enhancing the accuracy of our remote sensing PM estimates. The findings demonstrate that the combination of AOD data with meteorological analyses and additional datasets can effectively model PM${ }_{2.5}$ concentrations, achieving a significant correlation coefficient of 0.849. The reconstructed PM${ }_{2.5}$ surfaces created in this study are invaluable for monitoring pollution events and performing detailed PM${ }_{2.5}$ analyses. These results were further validated through real-world observations from two in situ MINTS sensors located in Joppa (South Dallas) and Austin, confirming the effectiveness of our comprehensive approach to PM analysis. The US Environmental Protection Agency (EPA) recently updated the national standard for PM${ }_{2.5}$ to 9 $\mathsf{\mu }$g/m${ }^3$, a move aimed at significantly reducing air pollution and protecting public health by lowering the allowable concentration of harmful fine particles in the air. Using our analysis approach to reconstruct the fine-time resolution PM${ }_{2.5}$ distribution across the entire United States for our study period, we found that the entire nation encountered PM${ }_{2.5}$ levels that exceeded 9 $\mathsf{\mu }$g/m${ }^3$ for more than 20% of the time of our analysis period, with the eastern United States and California experiencing concentrations exceeding 9 $\mathsf{\mu }$g/m${ }^3$ for over 50% of the time, highlighting the importance of regulatory efforts to maintain annual PM${ }_{2.5}$ concentrations below 9 $\mathsf{\mu }$g/m${ }^3$.

This paper describes and demonstrates an autonomous robotic team that can rapidly learn the characteristics of environments that it has never seen before. The flexible paradigm is easily scalable to multi-robot, multi-sensor autonomous teams, and it is relevant to satellite calibration/validation and the creation of new remote sensing data products. A case study is described for the rapid characterisation of the aquatic environment, over a period of just a few minutes we acquired thousands of training data points. This training data allowed for our machine learning algorithms to rapidly learn by example and provide wide area maps of the composition of the environment. Along side these larger autonomous robots two smaller robots that can be deployed by a single individual were also deployed (a walking robot and a robotic hover-board), observing significant small scale spatial variability.