High anthropogenic activities are constantly causing increased soil degradation and thus soil health and safety are becoming an important issue. The soil quality is deteriorating at an alarming rate in the neighborhood of smelters as a result of heavy metal deposition. Organic biowastes, also produced through anthropogenic activities, provide some solutions for remediation and management of degraded soils through their use as a substrate. Biowastes, due to their high content of organic compounds, have the potential to improve soil quality, plant productivity, and microbial activity contributing to higher humus production. Biowaste use also leads to the immobilization and stabilization of heavy metals, carbon sequestration, and release of macro and micronutrients. Increased carbon sequestration through biowaste use helps us in mitigating climate change and global warming. Soil amendment by biowaste increases soil activity and plant productivity caused by stimulation in shoot and root length, biomass production, grain yield, chlorophyll content, and decrease in oxidative stress. However, biowaste application to soils is a debatable issue due to their possible negative effect of high heavy metal concentration and risks of their accumulation in soils. Therefore, regulations for the use of biowastes as fertilizer or soil amendment must be improved and strictly employed to avoid environmental risks and the entry of potentially toxic elements into the food chain. In this review, we summarize the current knowledge on the effects of biowastes on soil remediation, plant productivity, and soil organic carbon sequestration.

Pyrolysis is a recognized alternative for the sustainable management of contaminated organic waste, as it yields energy-rich gas, oil, and a carbon-rich biochar product. Low-volatility compounds, however, such as heavy metals (HMs; As, Cd, Cu, Cr, Ni, Pb, and Zn) typically accumulate in biochars, limiting their application potential, especially for soil improvement. The distribution of HMs in pyrolysis products is influenced by treatment temperature and the properties of both the HMs and the feedstock. There is a significant knowledge gap in our understanding of the mass balances of HMs in full-scale industrial pyrolysis systems. Therefore, the fate of HMs during full-scale relevant pyrolysis (500–800 °C) of seven contaminated feedstocks and a clean wood feedstock were investigated for the first time. Most of the HMs accumulated in the biochar (fixation rates (FR) >70%), but As, Cd, Pb, and Zn partly partitioned into the flue gas at temperatures ≥ 600 °C, as demonstrated by FRs of <30% for some of the feedstocks. Emission factors (EFs, mg per tonne biochar produced) for particle-bound HMs (<0.45 µm) were 0.04–7.7 for As, 0.002–0.41 for Cd, 0.01–208 for Pb, and 0.09–342 for Zn. Only minor fractions of the HMs were found in the condensate (0–11.5%). To investigate the mobility of HMs accumulated in the biochars, a novel leaching test for sustained pH drop (at pH 4, 5.5 and 7) was developed. It was revealed that increasing pyrolysis temperature led to stronger incorporation of HMs in the sludge-based biochar matrix: after pyrolysis at 800 °C, at pH 4, <1% of total Cr, Cu, Ni, and Pb and < 10% of total As and Zn contents in the biochars were leached. Most interestingly, the high HM mobility observed in wood-based biochars compared to sewage-sludge-based biochars indicates the need to develop specific environmental-management thresholds for soil application of sewage-sludge biochars. Accordingly, more research is needed to better understand what governs the mobility of HMs in sewage-sludge biochars to provide a sound basis for future policy-making.

Selenium (Se) is a nonmetal that is essential for humans and other animals, and is considered beneficial for plants. The bioavailability of Se strongly influences its content in the food chain. Soils are the main source of Se, and their Se content primarily influences its availability, along with other soil properties. A field survey was conducted on soils of Southeast Europe, specifically in Croatia (Osijek), Bosnia and Herzegovina (Sarajevo, Banja Luka, Mostar, and Prud), and Serbia (Novi Sad). Soil samples were taken from the arable soil layer (0–30 cm depth), and two types of Se availability were measured: Se extracted using pure HNO₃ (Se_Tot) and Se readily extracted in water (SeH₂O). Only soils from the Mostar area had Se concentrations above deficit levels (0.5 mg kg⁻¹), with the highest values of cation exchange capacity (CEC), soil organic matter (SOM) measured as loss of ignition (LOI), total C, total N, Zn_Tot and Cd_Tot. The connections between the chemical characteristics of the soil and SeH₂O were investigated. Principal component analysis (PCA) explained 73.7% of the variance in the data set in the first three principal components (PCs). Using the provided data, we developed a partial least squares (PLS) regression model that predicted the amount of SeH₂O in the soil, with an accuracy ranging from 77% to 90%, depending on the input data. The highest loadings in the model were observed for LOI, CEC, total C, total N, and Se_Tot. Our results indicate the need for biofortification in these key agricultural areas to supplement the essential dietary requirements of humans and livestock. To efficiently and economically implement biofortification measures, we recommend utilizing regression models to accurately predict the availability of Se.

Barium (Ba) can be found in nature as Ba minerals, such as barite (BaSO₄), hollandite (Ba₂Mn₈O₁₆), and witherite (BaCO₃), and is primarily located in rock-forming minerals, such as potassium-feldspars, micas, apatite, and calcite. Commercial applications for Ba include the production of pesticides, explosives, drilling fluids, and detergents. In addition, Ba is utilized as a pigment in paints, filler in rubber and paper, and as a contrast material for gastrointestinal tract X-ray inspection. In saline soils with high chloride concentrations, Ba forms soluble barium chloride (BaCl₂) and becomes more mobile. However, Ba ions are not highly adsorbed in acidic environments, and Ba precipitates become more soluble in acidic soils. Barium is recognized to negatively affect most organisms when it is present in large concentrations. By consuming drinking water and food sources that contain Ba, such as fish and marine life, the general population gets exposed to Ba. Humans with high levels of Ba may experience cardiac arrhythmia, vomiting, diarrhea, hypokalemia, severe hypertension, and even death. While reverse osmosis filtering systems can be used to remove Ba from aqueous media, including drinking water sources, immobilization and phytoremediation methods can help to reduce Ba contamination in soil. The present review provides an insight into the origin, geochemistry, health risks, remediation techniques, and risk management of Ba in complex environmental matrices, such as soil and aquatic ecosystems.