Perovskite solar cells represent one of the recent success stories in photovoltaics. The device efficiency has been steadily increasing over the past years, but further work is needed to enhance the performance, for example, through the reduction of defects to prevent carrier recombination. SCAPS-1D simulations were performed to assess efficiency limits and identify approaches to decrease the impact of defects, through the selection of an optimal hole-transport material and a hole-collecting electrode. Particular attention was given to evaluation of the influence of bulk defects within light-absorbing CH₃NH₃SnI₃ layers. In addition, the study demonstrates the influence of interface defects at the TiO₂/CH₃NH₃SnI₃ (IL1) and CH₃NH₃SnI₃/HTL (IL2) interfaces across the similar range of defect densities. Finally, the optimal device architecture TiO₂/CH₃NH₃SnI₃/Cu₂O is proposed for the given absorber layer using the readily available Cu₂O hole-transporting material with PCE = 27.95%, FF = 84.05%, V_OC = 1.02 V and J_SC = 32.60 mA/cm², providing optimal performance and enhanced resistance to defects.

The advantages of IR spectroscopy include relatively fast analysis and sensitivity, which facilitate its wide application in the pharmaceutical, chemical and polymer sectors. Thus, IR spectroscopy provides an excellent opportunity to monitor the degradation and concomitant evolution of the molecular structure within a perovskite layer. As is well-known, one of the main limitations preventing the industrialization of perovskite solar cells is the relatively low resistance to various degradation factors. The aim of this work was to study the degradation of the surface of a perovskite thin film CH₃NH₃PbI_3-xCl_x caused by atmosphere and light. To study the surface of CH₃NH₃PbI_3-xCl_x, a scanning electron microscope, infrared (IR) spectroscopy and optical absorption were used. It is shown that the degradation of the functional layer of perovskite proceeds differently depending on the acting factor present in the surrounding atmosphere, whilst the chemical bonds are maintained within the perovskite crystal structure under nitrogen. However, when exposed to an ambient atmosphere, an expansion of the NH₃⁺ band is observed, which is accompanied by a shift in the N–H stretching mode toward higher frequencies; this can be explained by the degradation of the perovskite surface due to hydration. This paper shows that the dissociation of H₂O molecules under the influence of sunlight can adversely affect the efficiency and stability of the absorbing layer. This work presents an approach to the study of perovskite structural stability with the aim of developing alternative concepts to the fabrication of stable and sustainable perovskite solar cells.

One of the important aspects for degradation of the life quality is the ever increasing volume and range of industrial wastes. Polymer wastes, such as automotive tire rubber, are a source of long-term environmental pollution. This paper presents an approach to simplifying the rubber waste recycling process using cryogenic temperatures. The temperature of cryogenic treatment is ranged from 77 K to 280 K. Liquid nitrogen was used as a cryoagent for laboratory tests. Experimental and numerical studies have been carried out to determine the optimal conditions for the recycling process. Numerical studies were performed using the COMSOL Multiphysics cross-platform software. The optimal force of mechanical shock for the destruction of a tire which turned into a glassy state after cryoexposure was determined experimentally. The chemical and physical properties of the final product (crumb rubber) have been studied by scanning electron microscopy and energy dispersive X-ray spectroscopy. The analysis shows that the morphology and elemental composition of the samples remain practically unchanged, demonstrating environmental friendliness of the proposed process.

Aluminum–carbon nanotube (Al–CNT) composites represent a cutting-edge class of materials characterized by their exceptional mechanical, thermal, and electrical properties, making them highly promising for aerospace, automotive, electronics, and energy applications. This review systematically examines the impact of various fabrication methods, including conventional powder metallurgy, diffusion and reaction coupling, as well as adhesive and reaction bonding on the microstructure and performance of Al–CNT composites. The analysis emphasizes the critical role of CNT dispersion, interfacial bonding, and the formation of reinforcing phases, such as Al₄C₃ and Al₂O₃, in determining the mechanical strength, wear resistance, corrosion resistance, and thermal stability of these materials. The challenges of CNT agglomeration, high production costs, and difficulties in controlling interfacial interactions are highlighted alongside potential solutions, such as surface modifications and reinforcement strategies. The insights presented aim to guide future research and innovation in this rapidly evolving field.

Ensuring water resources for livestock production in Kazakhstan presents a multifaceted challenge. Pastoral systems in Southern Kazakhstan are facing a critical groundwater shortage, with 56.5% of pastures currently unused due to limited water access, jeopardizing around 2 million head of livestock and the region’s food security. This study presents the first comprehensive groundwater assessment in over 40 years, integrating hydrochemical analysis (55 samples) and field surveys conducted in the Almaty and Zhetysu regions. Key findings include: the total water demand for livestock is estimated at 53,735 thousand m³/year, with approximately 40% of samples exceeding WHO guidelines for total mineralization. It was determined that 45% of exploitable groundwater reserves in the Almaty region and 15–17% in the Zhetysu region are suitable for irrigation. This study also provides updated hydrogeological data, identifying three priority aquifer systems. A novel Groundwater Sustainability Index for pastoral zones of Central Asia is introduced, demonstrating that strategic aquifer development could expand watered pastureland by 30–40%. These findings directly inform Kazakhstan’s Agricultural Development Plan through 2030 and provide a replicable framework for sustainable water management in arid regions. With 69,836 rural residents currently lacking access to safe water, our results underscore the urgent need for infrastructure investment to meet SDG 6 targets (ensure availability and sustainable management of water and sanitation for all).

Groundwater is a strategically important source of drinking water supply in the arid and rural regions of Kazakhstan. The objective of this study is to assess the quality of groundwater at 11 water intakes located in the Kordai, Shu, and Merke Districts of the Shu transboundary basin in the Zhambyl Region. A comprehensive assessment of physicochemical parameters was performed, including concentrations of nitrates, sulfates, chlorides, iron, manganese, and other constituents, with subsequent comparison against regulatory limits defined by Order No. 26 of the Ministry of Health of the Republic of Kazakhstan (dated 20 February 2023), GOST standards, and ST RK ISO standards. The findings revealed that a number of water intakes exceeded the maximum allowable concentrations for specific indicators, especially in areas subject to significant anthropogenic pressure. The most vulnerable sources were identified near settlements characterized by intensive agricultural practices and inadequate wastewater treatment systems. Spatial comparison of the results enabled the identification of potentially contaminated areas as well as aquifer zones suitable for drinking water supply. The study emphasizes the importance of regular groundwater monitoring and spatial analysis techniques (GIS) to enhance the reliability and comprehensiveness of water quality assessments. The data obtained in this study can serve as a basis for informed decision-making in the area of water resource protection and contribute to the achievement of United Nations Sustainable Development Goal 6 (SDG 6)—to ensure availability and sustainable management of water and sanitation for all.