The effects of surface pretreatment (water and alkali) and modification with silane on moisture sorption, water resistance, and reaction to fire of hemp fiber reinforced polylactic acid (PLA) composites at two fiber loading contents (30 and 50 wt.%) are investigated in this work. Moisture adsorption was evaluated at 30, 50, 75 and 95% relative humidity, and water resistance was determined after a 28-day immersion period. The cone calorimetry technique was used to investigate response to fire. The fiber surface treatment resulted in the removal of cell wall components, which increased fiber individualization and homogeneity as shown in scanning microscopic pictures of the composite cross-section. Although the improved fiber/matrix bonding increased the composite’s water resistance, the different fiber treatments generated equal moisture adsorption results for the 30 wt.% reinforced composites. Overall, increasing the fiber amount from 30 to 50 wt.% increased the composite sensitivity to moisture/water, mainly due to the availability of more hydroxyl groups and to the development of a higher pore volume, but fire protection improved due to a reduction in the rate of thermal degradation induced by the reduced PLA content. The new Oswin’s model predicted the composite adsorption isotherm well. The 30 wt.% alkali and silane treated hemp fiber composite had the lowest overall adsorption (9%) while the 50 wt.% variant produced the highest ignition temperature (181 ± 18 °C).

In Estonia, hardwoods form approximately 50% of all forest area, where the main species are birch (30%), gray alder (9%), aspen (6%) and black alder (4%). Birch has been extensively used by the veneer-based industry, but species like black alder, gray alder and aspen have not been commonly used by the veneer-based products industry due to the lower quality of this resource. The aim of this research is to determine the effect of different lay-up schemes and usages of gray alder, black alder and aspen on the mechanical properties of plywood, by replacing birch veneer in the plywood core with alternative wood species. The main veneer and plywood characteristics will be evaluated according to the current standards, e.g., veneer strength perpendicular to grain, plywood bonding and bending strength, and modulus of elasticity. All processing parameters will be kept similar to those used generally by birch plywood manufacturers. The results showed that birch and black alder plywood panels had generally the highest bending strength properties, followed by grey alder and aspen. It was also found that, for proper gluing, birch veneers had the lowest glue consumption, 152 g/m², and aspen had the highest glue consumption, 179 g/m². It was found that when lower density wood was used in the plywood, the product density increased. Low density wood veneers had higher glue consumption, and also higher compaction in thickness than birch veneers under the same pressure. Overall, it was shown that the wood species used in this study have slightly lower strength properties, but with proper lay-up schemes, these wood species could be successfully used by the veneer-based products industry.

This research investigates an effective alkali (NaOH) treatment and fire-retardant coating to produce biocomposites from frost-retted hemp fiber and PLA. The fiber surface treatment with various NaOH concentrations was investigated throughout a range of soaking times. The results show that the extracted non-cellulosic fiber content increases with treatment duration and NaOH concentration, while the fraction of targeted components removed remains nearly unchanged after soaking for 1, 2, and 4 h with a 5 wt.% NaOH solution. At the composite level, the treatment with 5 wt.% NaOH solution for 1 h emerged as the most efficient, with tensile strength, Young’s modulus, flexural strength, and flexural modulus of 89.6 MPa, 9.1 GPa, 121.6 MPa, and 9.6 GPa, respectively, using 30 wt.% fibrous reinforcement. The fire performance of the examined batches of biocomposites improved significantly with the novel fire-retardant (Palonot F1) coating. However, the tensile strength notably decreased, while the flexural properties showed only a slight reduction. In most cases, the biocomposites with the alkali-treated hemp fiber had delayed ignition during the 5 min exposure to the cone heater. The findings in this work contribute to studies that will be required to give design guidelines for sustainable building options.

This research concentrates on the effect of moisture absorption and UV radiation on the mechanical and physical properties of wood-plastic composites (WPC). The goal is also to evaluate the importance of wood flour fraction size on the mechanical properties of WPC and their influence on the accelerated weathering results. Wood flour reinforced composites with three different fractions of wood flour made from birch (Betula) chips were prepared. Additionally, Bleached-Chemi-Thermo-Mechanical aspen (Populus tremula) pulp (Aspen BCTMP) was used. Thermoplastics (LLDPE-g-MAH, PP) were used to prepare composites. Wood flour and BCTMP surface were treated with two different coupling agents: 3-aminopropyltriethoxysilane (APTES) and polyvinyalcohol (PVA). The WPC specimens were prepared by injection molding. Accelerated weathering tests were carried out to evaluate the influence of weathering on the mechanical and physical properties of composites. Three-point bending test and Charpy impact test were used to test mechanical properties. The test results showed that using wood flour as a filler material in composites made the WPC material more rigid and brittle. Due to the water absorption and swelling of WPC, the flexural modulus (MOE) and strength decreased and impact strength increased by making the material weaker with increasing the deflection of the WPC. The UV radiation decreased the composites flexural strength and MOE, while impact strength was increased. After the accelerated weathering cycles, cracks and voids were found on the surface of the WPC materials. After the UV radiation treatment, also the WPC colour was lightened.

Thermoplastic cellulose esters are promising materials for bioplastic packaging. For that usage, it is important to understand their mechanical and surface wettability properties. In this study, a series of cellulose esters are prepared, such as laurate, myristate, palmitate, and stearate. The aim of the study is to investigate the tensile and surface wettability properties of the synthesized cellulose fatty acid esters to understand their suitability as a bioplastic packaging material. Cellulose fatty acid esters are first synthesized from microcrystalline cellulose (MCC), then dissolved in pyridine solution, and after the solvent cast into thin films. The cellulose fatty acid ester acylation process is characterized by the FTIR method. Cellulose esters hydrophobicity is evaluated with contact angle measurements. The mechanical properties of the films are tested with the tensile test. For all the synthesized films, FTIR provides clear evidence of acylation by showing the presence of characteristic peaks. Films’ mechanical properties are comparable to those of generally used plastics such as LDPE and HDPE. Furthermore, it appears that with an increase in the side-chain length, the water barrier properties showed improvement. These results show that they could potentially be suitable materials for films and packaging materials.

In recent years, research in the field of insulation materials in buildings has been focusing increasingly more upon ecological properties of these materials. Hemp is an annual bast fibre plant, which delivers fibres, shives, and seeds. Bast fibres are used as a raw material for thermal insulations while shives have been mainly used in animal bedding and construction. The aim of this research was to evaluate the mechanical and physical properties of the industrial hemp fibre- and bast-based insulation materials and compare them with wood-based materials. For producing hemp fibreboards, the hemp shives were ground with separative milling by a semi-industrial disintegrator to the average particle size of 0.136 mm. Urea–formaldehyde (UF) resin was used as the adhesive for hemp particleboards and fibreboards made by the dry method. Fibreboards made by the wet method were bonded without using any binders. Some fibreboards made by the dry method were covered with kraft paper on both sides using UF resin and PVA glue. Properties of particleboards and fibreboards were tested with the determination of density, swelling, resistance to axial withdrawal of screws, tensile strength perpendicular to the plane of the board, bending strength, and air permeability. The results showed that fibreboards made by the dry method were stronger and tougher than fibreboards made by the wet method. The only shortcoming of the former was their low water resistance as samples dissolved in water. Hemp particleboards were lighter and less dense than wood particleboards. However, the mechanical properties of the hemp particleboards were inferior to those of wood particleboards. In addition, the levels of water absorption and swelling of the hemp particleboards were higher than those of the wood particleboards.