For decades, significant work has been conducted regarding plastic waste by dealing with rejected materials in waste masses through their accumulation, sorting and recycling. Important political and technical challenges are involved, especially with respect to landfilled waste. Plastic is popular and, notwithstanding decrease policies, it will remain a material widely used in most economic sectors. However, questions of plastic waste recycling in the contemporary world cannot be solved without knowing the material, which can be achieved by careful sampling, analysis and quantification. Plastic is heterogeneous, but usually all plastic waste is jointly handled for recycling and incineration. Separation before processing waste through the analytical approach must be applied. Modern landfill mining and site clean-up projects in contemporary waste management systems require comprehensive material studies ranging from the macro-characterization of waste masses to a more detailed analysis of hazardous constituents and properties from an energy calorific standpoint—where, among other methods, thermogravimetric research coupled with life cycle assessment (LCA) and economic assessment is highly welcomed.
The main components of landfill gas are methane and carbon dioxide. Emissions of methane, a strong greenhouse gas, can be minimized by in situ oxidation in the bioactive cover layer. Typically, organic-rich porous materials such as compost are used for this process. In this study, the material for a biocover was obtained from the same landfill by landfill mining. The objective was to study the spatial distribution of gases and the efficiency of methane degradation in the biocover. The methane and carbon dioxide emissions were measured at 29 measuring points six times on the surface and once at a depth of 0.5 m. The highest values of both gases from the surface were recorded in July 2015: 1.0% for CO2 and 2.1% for CH4. Deeper in the cover layer, higher values of methane concentration were recorded. The results showed that (a) methane from the waste deposit was entering the biocover, (b) the migration of methane to the atmosphere was low, (c) fluctuations in the composition of gases are seasonal, and (d) the trend in the concentration of CH4 over time was an overall decrease. The described cover design reduces the CH4 emissions in landfills using elements of circular economy—instead of wasting natural soils and synthetic liners for the construction of the final cover layer, functional waste-derived materials can be used.
Industrial and strategic significance of platinum group elements (PGEs)—Os, Ir, Ru, Rh, Pd, Pt—makes them irreplaceable; furthermore, some PGEs are used by investors as “safe heaven” assets traded in the commodity markets. This review analyzes PGEs from various aspects: their place in the geosphere, destiny in the anthroposphere, and opportunity in the economy considering interactions among the exploration, recycling of urban ores, trade markets, speculative rhetoric, and changes required for successful technological progress towards the implementation of sustainability. The global market of PGEs is driven by several concerns: costs for extraction/recycling; logistics; the demand of industries; policies of waste management. Diversity of application and specific chemical properties, as well as improper waste management, make the recycling of PGEs complicated. The processing approach depends on composition and the amount of available waste material, and so therefore urban ores are a significant source of PGEs, especially when the supply of elements is limited by geopolitical or market tensions. Recycling potential of urban ores is particularly important in a long-term view disregarding short-term economic fluctuations, and it should influence investment flows in the advancement of innovation.
12 December 2019 in Research for Rural Development
Global resource limits and increasing demand for non-fossil energy sources have expanded the research on alternative fuels. Among them, algal biomass is designated as a third-generation feedstock with promising opportunities and the capability to be utilized for energy production in the long term. The paper presents the potential for converting beach wrack containing macroalgal biomass into gaseous fuel as a sustainable option for energy production, simultaneously improving the organic waste management that the coastline is facing. Beach wrack collected in the northern Baltic Sea region was converted by gasification technology applicable for carbon-based feedstock thermal recovery, resulting in syngas production as the main product and by-product biochar. Proximate and ultimate analysis, trace and major element quantification, detection of calorific values for macroalgal biomass, and derived biochar and syngas analysis were carried out. A higher heating value for beach wrack was estimated to be relatively low, 5.38 MJ/kg as received (or 14.70 MJ/kg on dry basis), but produced syngas that contained enough high content of CH4 (42%). Due to macroalgal biomass specifics (e.g., high moisture content and sand admixture), an adjusted gasification process, i.e., the combination of thermochemical procedures, such as mild combustion and pyrolytic biomass conversion, might be a better choice for the greater economic value of biowaste valorization.