Self-powered sensor development is moving towards miniaturization and requires a suitable power source for its operation. The piezoelectric nanogenerator (PENG) is a potential candidate to act as a partial solution to suppress the burgeoning energy demand. The present work is focused on the development of the PENG based on flexible polymer-ceramic composite films. The X-ray spectra suggest that the BTO particles have tetragonal symmetry and the PVDF-BTO composite films (CF) have a mixed phase. The dielectric constant increases with the introduction of the particles in the PVDF polymer and the loss of the CF is much less for all compositions. The BTO particles have a wide structural diversity and are lead-free, which can be further employed to make a CF. An attempt was made to design a robust, scalable, and cost-effective piezoelectric nanogenerator based on the PVDF-BTO CFs. The solvent casting route was a facile approach, with respect to spin coating, electrospinning, or sonication routes. The introduction of the BTO particles into PVDF enhanced the dielectric constant and polarization of the composite film. Furthermore, the single-layered device output could be increased by strategies such as internal polarization amplification, which was confirmed with the help of the polarization-electric field loop of the PVDF-BTO composite film. The piezoelectric nanogenerator with 10 wt% BTO-PVDF CF gives a high electrical output of voltage 7.2 V, current 38 nA, and power density of 0.8 μW/cm² at 100 MΩ. Finally, the energy harvesting using the fabricated PENG is done by various actives like coin dropping, under air blowing, and finger tapping. Finally, low-power electronics such as calculator is successfully powered by charging a 10 μF capacitor using the PENG device.

Carbon quantum dots (CQDs) have recently emerged as innovative theranostic nanomaterials, enabling fast and effective diagnosis and treatment. In this study, a facile hydrothermal approach for N-doped biomass-derived CQDs preparation from Citrus clementina peel and amino acids glycine (Gly) and arginine (Arg) has been presented. The gradual increase in the N-dopant (amino acids) nitrogen content increased the quantum yield of synthesized CQDs. The prepared CQDs exhibited good biocompatibility, stability in aqueous, and high ionic strength media, similar optical properties, while differences were observed regarding the structural and chemical diversity, and biological and antioxidant activity. The antiproliferative effect of CQD@Gly against pancreatic cancer cell lines (CFPAC-1) was observed. At the same time, CQD@Arg has demonstrated the highest quantum yield and antioxidant activity by DPPH scavenging radical method of 81.39 ± 0.39% and has been further used for the ion sensing and cellular imaging of cancer cells. The obtained results have demonstrated selective response toward Fe³⁺ detection, with linear response ranging from 7.0 µmol dm⁻³ to 50.0 µmol dm⁻³ with R² = 0.9931 and limit of detection (LOD) of 4.57 ± 0.27 µmol dm⁻³. This research could be a good example of sustainable biomass waste utilization with potential for biomedical analysis and ion sensing applications.

This paper presents the fabrication of a polycrystalline sample of the above electronic system by a mixed-oxide technique. The X-ray diffraction pattern show the evolution of perovskite phase (including some impurity phase). The rhombohedral symmetry and crystallite size of 42 nm were also found from the XRD. The distribution of grains in the microstructure suggests the formation of high density ceramics. The role of grains, grain boundaries and interface on resistive (impedance, electrical modulus and electrical transport) and insulating (dielectric) has been investigated over a wide range of frequencies (103-106 Hz) and temperatures (25-400 °C) using spectroscopy (dielectric, modulus and impedance) techniques. The Nyquist plot illustrates the presence of effects such as grain and grain boundary over selected temperatures. Analysis of conductivity spectra reveals that the electrical transport process of the material is influenced by charge transfer by hopping. The complex modulus spectrum also describes the dielectric relaxation of the material. The study of field dependent polarization reveals the existence of ferroelectricity in the material.

This review highlights that screen-printed gas sensors are cost-effective and scalable, ideal for environmental, industrial, and healthcare applications.