Electrochromic systems for smart windows make it possible to enhance energy efficiency in the construction sector, in both residential and tertiary buildings. The dynamic modulation of the spectral properties of a glazing, within the visible and infrared ranges of wavelengths, allows one to adapt the thermal and optical behavior of a glazing to the everchanging conditions of the environment in which the building is located. This allows appropriate control of the penetration of solar radiation within the building. The consequent advantages are manifold and are still being explored in the scientific literature. On the one hand, the reduction in energy consumption for summer air conditioning (and artificial lighting, too) becomes significant, especially in "cooling dominated" climates, reaching high percentages of saving, compared to common transparent windows; on the other hand, the continuous adaptation of the optical properties of the glass to the changing external conditions makes it possible to set suitable management strategies for the smart window, in order to offer optimal conditions to take advantage of daylight within the confined space. This review aims at a critical review of the relevant literature concerning the benefits obtainable in terms of energy consumption and visual comfort, starting from a survey of the main architectures of the devices available today.

This paper holds a critical review of current research activities dealing with smart architectural glazing worldwide. Hereafter, the main trends are analyzed and critically reported, with open issues, challenges, and opportunities, providing an accurate description of technological evolution of devices in time. This manuscript deals with some well-known, highly performing technologies, such as semitransparent photovoltaics and novel photoelectrochromic devices, the readiest, probably, to reach the final stage of development, to disclose the manifold advantages of multifunctional, smart glazing. The complex, overall effects of their building integration are also reported, especially regarding energy balance and indoor visual comfort in buildings.

Environmentally sustainable cement mortars containing wheat straw (Southern Italy, Apulia region) of different length and dosage and perlite beads as aggregates were prepared and characterised by rheological, thermal, acoustic, mechanical, optical and microstructural tests. A complete replacement of the conventional sand was carried out. Composites with bare straw (S), perlite (P), and with a mixture of inorganic and organic aggregates (P/S), were characterised and compared with the properties of conventional sand mortar. It was observed that the straw fresh composites showed a decrease in workability with fibre length decrease and with increase in straw volume, while the conglomerates with bare perlite, and with the aggregate mixture, showed similar consistency to the control. The thermal insulation of the straw mortars was extremely high compared to the sand reference (85–90%), as was the acoustic absorption, especially in the 500–1000 Hz range. These results were attributed to the high porosity of these composites and showed enhancement of these properties with decrease in straw length and increase in straw volume. The bare perlite sample showed the lowest thermal insulation and acoustic absorption, being less porous than the former composites, while intermediate values were obtained with the P/S samples. The mechanical performance of the straw composites increased with length of the fibres and decreased with fibre dosage. The addition of expanded perlite to the mixture produced mortars with an improvement in mechanical strength and negligible modification of thermal properties. Straw mortars showed discrete cracks after failure, without separation of the two parts of the specimens, due to the aggregate tensile strength which influenced the impact compression tests. Preliminary observations of the stability of the mortars showed that, more than one year from preparation, the conglomerates did not show detectable signs of degradation.

Research activities in the field of innovative fixtures are continuously aiming at increasing their thermal and optical performances to offer optimal exploitation of daylight and solar gains, providing effective climate screen, according to increasing standards for indoor comfort and energy saving. Within this work, we designed an innovative aerogel-based “thermal break” for window frames, so as to consistently reduce the frame conductance. Then, we compared the performance of this new frame both with currently used and obsolete frames, present in most of the existing building stock. Energy savings for heating and cooling were assessed for different locations and confirmed the potential role played by super-insulating materials in fixtures for extremely rigid climates.