In this study, wear properties of Monel 400 after laser alloying with boron are described. Surfaces were prepared by covering them with boron paste layers of two different thicknesses (100 µm and 200 μm) and re-melting using diode laser. Laser beam power density was equal to 178.3 kW/cm2. Two laser beam scanning velocities were chosen for the process: 5 m/min and 50 m/min. Surfaces alloyed with boron were investigated in terms of wear resistance, and the surface of untreated Monel 400 was examined for comparison. Wear tests were performed using counterspecimen made from steel 100Cr6 and water as a lubricant. Both quantitative and qualitative analysis of surfaces after wear test are described in this paper. Additionally, microstructures and properties of obtained laser alloyed surfaces are presented. It was found that the wear resistance increased from four to tens of times, depending on parameters of the laser boriding process. The wear mechanism was mainly adhesive for surfaces alloyed with initial boron layer 100 µm thick and evolves to abrasive with increasing boron content and laser beam scanning velocity. Iron particles detached from counterspecimens were detected on each borided surface after the wear test, and it was found that the harder the surface the less built-ups are present. Moreover, adhered iron particles oxidized during the wear test.
The fascinating tribological phenomenon of carbon nanotubes (CNTs) observed at the nanoscale was confirmed in our numerous macroscale experiments. We designed and employed CNT-containing nanolubricants strictly for polymer lubrication. In this paper, we present the experiment characterising how the CNT structure determines its lubricity on various types of polymers. There is a complex correlation between the microscopic and spectral properties of CNTs and the tribological parameters of the resulting lubricants. This confirms indirectly that the nature of the tribological mechanisms driven by the variety of CNT–polymer interactions might be far more complex than ever described before. We propose plasmonic interactions as an extension for existing models describing the tribological roles of nanomaterials. In the absence of quantitative microscopic calculations of tribological parameters, phenomenological strategies must be employed. One of the most powerful emerging numerical methods is machine learning (ML). Here, we propose to use this technique, in combination with molecular and supramolecular recognition, to understand the morphology and macro-assembly processing strategies for the targeted design of superlubricants.
Slip risk on surfaces used by humans or active in mechanisms is studied to mitigate its effects or harness its beneficial outcomes. This article presents pioneering research on the risk of surfaces created using 3D printing technology. The study examines three materials (Polylactic Acid, PLA; Polyethylene Terephthalate Glycol, PET-G; and Thermoplastic Polyurethane, TPU), considering three print head movement directions relative to the British Portable Skid Resistance Tester (BSRT) measurement direction. In addition, surface roughness tests were performed. Dry tests showed that the structure created by the printing direction perpendicular to the movement direction is the safest in terms of slip risk. The SRVs of the measured samples on a qualitative scale were classified on this scale as materials with low or extremely low slip risk (ranging from 55 to 90 SRV dry and 35 to 60 SRV wet). Referring to the influence of the type of material on the SRV, it was found that the safest material in terms of reducing the risk of slipping in dry conditions is TPU and, in wet conditions, PLA. During wet tests, the best properties that reduce the risk of slippage in most cases are shown by the printing direction on a horizontal plane at an angle of 45° to the direction of movement. Statistical analysis showed that the printing direction and roughness do not have a statistically significant effect on the SRV, but the type of material and the type of method (dry and wet) and their interaction have a significant effect.
Modern internal combustion engines are designed to meet new emission standards and reduce fuel consumption. The wide application of direct fuel injection is associated with the problem of injector contamination. It leads to a deterioration of the engine’s environmental performance. The paper aims to evaluate the effect of applying gasoline–butanol blends and appropriate additives on the formation of injector deposits. The research involved testing the engine on a dynamometer, evaluating the injector tips visually at 1000× magnification, and registering the fuel spray using high-speed imaging techniques with a laser and halogen lighting source. The effect of engine operating with the reference fuel was to coke the injector tip with a linear pattern. It increased the linear injection time to keep the engine’s operating point constant over the 48 h test. The application of 20% (v/v) butanol reduced deposit formation. The best scavenging results were obtained by extending the engine operating time by the next 24 h and using a cleaning procedure. The procedure included a cleaning additive in addition to butanol. Among the cases analyzed, a combination of butanol and DCA (Deposit Control Additive) was the best method for injector patency restoration.
The sliding layer created during operation of the expanded graphite–steel combination has had a huge impact on the effectiveness of the friction process, and thus on the sustainable development of society. Knowledge of the factors determining the properties of the sliding layer will make it possible to reduce friction resistance in the future through the proper design and selection of sliding pairs for given applications. This paper studies the effect of the moisture content of expanded graphite on the formation of a sliding layer on a stainless steel surface. The tests were carried out in static contact for 30 s and dynamic contact for 15 and 30 min, for loads of 10, 20, and 30 N and speeds of 25 and 50 mm/s. To determine the changes in surface geometry due to material transfer, the Ra roughness value of the surface of stainless steel samples was measured. In order to realize the purpose of the work and evaluate the effect of moist rings on the resulting sliding layer, the results of the surface roughness of stainless steel samples working with dry and moist graphite rings were compiled. The obtained results show that the presence of water in the stainless steel-expanded graphite friction node affects the formation of a sliding layer. The resulting layer reduces the surface roughness of the cooperating materials and prevents their accelerated wear. After 5 min of work with the water-soaked graphite counter-sample, depending on the applied friction conditions, a reduction in the surface roughness of the stainless steel sample was achieved in the range of 11–18% compared to the initial value. After 30 min of operation, the surface roughness decreased by 3 to 25%. Pilot studies have shown that operating conditions influence the formation of a sliding layer in the stainless steel-expanded graphite tribological contact. This confirms the validity of conducting further research in this area.
The aim of the research was to evaluate the influence of the initial roughness of a steel pin cooperating with a graphite ring—dry and wet—on the mechanism of sliding layer formation. A ring–pin friction pair was used for the study, where the rings were made of expanded graphite, while the pins were made of acid-resistant steel. In the first case, the steel pin interacted with a dry graphite ring, and in the second case, the graphite rings were moist. To determine the effect of initial surface roughness, the pins were divided into three roughness groups. To determine changes in surface geometry due to material transfer, the Ra and Rz parameters were measured. This project investigated how the initial roughness value of the steel surface pin cooperating with expanded graphite influences the formation of the sliding layer. Increasing the initial roughness of the steel surface interacting with the graphite contributes to faster layer formation and reduced roughness. The state of the expanded graphite—dry and wet—influences the formation of the sliding layer of graphite—a wet graphite component causes a faster smoothing of the steel surface. The running time of the wear apparatus has an effect on the resulting layer. The highest roughness group is the most favorable from the viewpoint of sliding layer formation.