Graphene oxide (GO) and reduced graphene oxide (RGO) are known to have superior properties for various applications. This work compares the properties of GO and RGO with graphite. GO was prepared by using Improved Hummer’s method whereas the produced GO was subjected to chemical reduction with the use of hydrazine hydrate. Graphite, GO and RGO had different morphologies, quality, functionalized groups, UV-Vis absorption peaks and crystallinity. With the removal of oxygen-containing functional group during reduction for RGO, the quality of samples was decreased due to higher intensity of D band than G band was seen in Raman results. In addition, platelet-like surface can be observed on the surface of graphite as compared to GO and RGO where wrinkled and layered flakes, and crumpled thin sheets were observed on GO and RGO surface respectively. Fourier Transform Infra-Red (FTIR) analysis showed the presence of abundant oxygen-containing functional groups in GO as compared to RGO and graphite. The characteristic peaks at 26.62°, 9.03° and 24.10° for graphite, GO and RGO, respectively, can be detected from X-Ray diffraction (XRD). Furthermore, the reduction also caused red shift at 279nm from 238nm, as obtained from ultraviolet visible (UV-Vis) analysis. The results proved that GO was successfully oxidized from graphite whereas RGO was effectively reduced from GO.
This article reviews the recent advances made in polyolefin and natural polymer blends used for packaging applications, with a focus on their degradation. Nondegradable polymers are now considered as a serious environmental problem, and they have become an enormous challenge to waste management. Hence, the degradable polymers are practical solutions to reduce the municipal solid waste (MSW) caused by the use of nondegradable polymers. These degradable options can be produced from three kinds of natural sources:- (1) polysaccharides—starch, cellulose, chitin and chitosan; (2) proteins—soya, wheat gluten, collagen/gelatine; and (3) speciality polymers—such as lignin, natural rubber. One major challenge to producing a degradable blend with the desired properties is merging the hydrophilic characteristics of natural polymers with the hydrophobic characteristics of polyolefin. The aim of this review is to offer a complete overview of polyolefin/natural polymer blends researched for packaging applications.