The main concern of this work is to evaluate the influences of supplementary cementitious materials (fly ash, slag) and a new type of polycarboxylate superplasticizer containing viscosity modifying agents (PCE-VMA) on the performance of self-compacting concrete (SCC). The workability, hydration process, mechanical property, chloride permeability, degree of hydration and pore structure of SCC were investigated. Results indicate that the addition of fly ash and slag slows down early hydration and decreases the hydration degree of SCC, and thus leads to a decline in compressive strengths, especially within the first 7 days. The addition of slag refines pore structure and contributes to lower porosity, and thus the chloride permeability of SCC is decreased during the late hydration stage. Additionally, a new factor of calculated water–binder ratio is put forward, which can directly reflect the free water content of concrete mixture after mixing, and guide the mix proportion design of SCC.
1 July 2013 in Journal of Materials in Civil Engineering
Sludge utilization has become the focus of sludge disposal, and this paper presents a study of using sludge, low-quality fly ash, and other raw materials from the Shanghai region to make high-strength ceramsite. The proportions of the mix and the firing conditions suitable to roast the calcined high-strength sludge ceramsite are discussed. The results show that pure sludge materials alone are not suitable for making high-strength ceramsite. High-strength sludge ceramsite was made with a silt–fly ash–waste glass powder of under a firing system with a preheating temperature of 600°C, a warm-up time of 20 min, a calcination temperature of 1,150°C, and a roasting time of 15 min. The high-strength sludge ceramsite provided particle strength of 7.1 MPa, apparent density of , and water absorption of 8.2%. All properties were better than the requirements in the national standards. In addition, the high-strength sludge ceramsite provides important environmental and social benefits due to its consumption of waste and industry by-products such as river sludge and low-quality fly ash.
The breakage of capsules upon crack propagation is crucial for achieving crack healing in encapsulation-based self-healing materials. A mesomechanical model was developed in this study to simulate the process of crack propagation in a matrix and the potential of debonding. The model used the extended finite element method (XFEM) combined with a cohesive zone model (CZM) in a two-dimensional (2D) configuration. The configuration consisted of an infinite matrix with an embedded crack and a capsule nearby, all subjected to a uniaxial remote tensile load. A parametric study was performed to investigate the effect of geometry, elastic parameters and fracture properties on the fracture response of the system. The results indicated that the effect of the capsule wall on the fracture behavior of the matrix is insignificant for tc/Rc≤ 0.05. The matrix strength influenced the ultimate crack length, while the Young’s modulus ratio Ec/Em only affected the rate of crack propagation. The potential for capsule breakage or debonding was dependent on the comparative strength between capsule and interface (Sc/Sint), provided the crack could reach the capsule. The critical value of Sc,cr/Sint,crwas obtained using this model for materials design.
This study evaluates the effect of vehicle–bridge coupled vibration on the mechanical properties of fiber-reinforced magnesium phosphate cement (FR-MPC) composites and the bonding properties of repaired systems. By means of compressive and flexural bond strengths, fiber pullout, mercury intrusion porosimeter (MIP) and backscattered electron imaging (BSE) analysis, an enhanced insight was gained into the evolution of FR-MPC performance before and after vibration. Experimental results showed that the compressive strength and flexural strength of FR-MPC was increased when it was subjected to vibration. However, the effects of vibration on the flexural strength of plain magnesium phosphate cement (MPC) mortars was insignificant. The increased flexural strength of FR-MPC after vibration could be due to the high average bond strength and pull-out energy between the micro-steel fiber and the MPC matrix. Moreover, BSE analysis revealed that the interface structure between FR-MPC and an ordinary Portland cement (OPC) substrate was more compacted after vibration, which could possibly be responsible for the better bonding properties of FR-MPC. These findings are beneficial for construction project applications of FR-MPC in bridge repairing and widening.
Efflorescence is aesthetically undesirable to all cementitious materials products and mainly results from the carbonation of hydrates and salt precipitation. Alternative binders without portlandite formation theoretically have much lower efflorescence risk, but in practice, the efflorescence of ettringite-rich systems is still serious. This study reports the impacts of mineral additives on the efflorescence of ettringite-rich systems and the corresponding microstructural evolution. The effects of silica fume, limestone powder, and diatomite on efflorescence and the capillary pore structure of mortars were investigated from a multi-scale analysis. The composition and microstructure of efflorescent phases were revealed by optical microscope (O.M.), in-situ Raman spectroscopy, and Scanning Electron Microscopy (SEM). Results indicate that the addition of mineral additives can efficiently inhibit the efflorescence of reference, especially with silica fume. Similar to the ettringite-rich system, the efflorescence substances of all modifies are composed of ettringite and CaCO3, indicating that the addition of mineral admixture does not lead to chemical reactions, lower capillary absorption coefficient of mineral additives modified specimen, the denser pore structure and the lower efflorescence degree.