Investigations described in this paper are related to study the waste and biomass treatment using thermal plasma as the heat source. Advantages of plasma based technologies over conventional incineration includes higher temperatures, independence of additional fuel, shorter residence times. Experimental data of high temperature pyrolysis of same biomass samples, such as pine pieces, by means of water vapor plasma torch are described. Pyrolysis and gasification experiments were performed at water vapor jet temperature changes from 800 to 1400 K. Energy expenditure in thermal gasification technology of solid fuel and plasma processes is compared. Experimental results show that thermal plasma could be used in high temperature solid fuel pyrolysis and waste treatment technologies.
As the industry develops and energy demand increases, wind turbines are increasingly being used to generate electricity, resulting in an increasing number of obsolete turbine blades that need to be properly recycled or used as a secondary raw material in other industries. The authors of this work propose an innovative technology not yet studied in the literature, where the wind turbine blades are mechanically shredded and micrometric fibers are formed from the obtained powder using plasma technologies. As shown by SEM and EDS studies, the powder is composed of irregularly shaped microgranules and the carbon content in the obtained fiber is lower by up to seven times compared with the original powder. Meanwhile, the chromatographic studies show that no hazardous to the environment gases are formed during the fiber production. It is worth mentioning that this fiber formation technology can be one of the additional methods for recycling wind turbine blades, and the obtained fiber can be used as a secondary raw material in the production of catalysts, construction materials, etc.
Al2O3 and Al2O3-ZrO2 coatings were deposited on stainless steel using atmospheric plasma spraying. The influence of arc current and zirconia addition on the surface morphology of the coating, phase composition and tribological properties under dry sliding conditions were investigated. The addition of zirconia reduced the surface roughness of the coatings. The X-ray diffraction measurements indicated that the Al2O3 coatings were composed of β-Al2O3, α-Al2O3, and γ-Al2O3 phases. The addition of zirconia led to the formation of tetragonal and monoclinic phases of zirconia in the as-sprayed coatings. The friction coefficients of Al2O3 and Al2O3-ZrO2 coatings were similar and varied in the range of 0.72–0.75. The specific wear rates of the as-sprayed coatings were reduced with the increase of arc current. It was obtained that the wear rates of the Al2O3-ZrO2 coatings were at least three times lower compared to Al2O3 coatings.
In this study, Cr2O3, Cr2O3-SiO2-TiO2 and Cr2O3-SiO2-TiO2-graphite coatings were formed by atmospheric plasma spraying. The influence of SiO2-TiO2 and SiO2-TiO2-graphite reinforcements on the surface morphology, elemental composition, structure and tribological properties of chromia coatings was determined. The friction coefficients and specific wear rates were investigated by a ball-on-flat configuration using 1 N and 3 N loads under dry-lubrication conditions. The addition of SiO2-TiO2-graphite resulted in the lowest surface roughness and the most homogenous surface of the coatings. The X-ray diffraction (XRD) measurements demonstrated that all as-sprayed coatings consisted of an eskolaite chromium oxide phase. The results showed that the Cr2O3-SiO2-TiO2 coating demonstrated the lowest friction coefficient values. The SiO2-TiO2 and SiO2-TiO2-graphite additives reduced the specific wear rates of Cr2O3 coatings by 30% and 45%, respectively. Additionally, the wear resistance was improved almost 45 times in comparison to the steel substrate.
In this study, alumina coatings were formed using atmospheric plasma spraying, increasing the torch power from 29.4 to 45.1 kW. The surface morphology of the coatings was determined using scanning electron microscopy; the elemental composition was examined using energy-dispersive X-ray spectroscopy (EDS); phase composition was investigated using X-ray diffraction; and surface roughness was determined using a profilometer. The steel surface temperature was measured using a type-K thermocouple, and the plasma jet temperature, at a distance of 70 mm, using a type-B thermocouple. Alumina particle velocity was calculated by analyzing high-speed camera footage using ImageJ software. The results indicate that plasma jet temperature, speed, and in-flight particle velocity increased with plasma torch power. Furthermore, the amount of γ-Al2O3 phase in the coating increased, and the α-Al2O3 decreased with increasing plasma power. The surface roughness (Rq) of the Al2O3 coatings decreased from 7.13 to 5.54 μm, with an increase in torch power. The EDS measurements indicate that the increase in torch power did not affect the elemental composition of as-sprayed coatings. The results provide a wider understanding of an atmospheric plasma spray technique, optimizing and controlling the parameters using air as a primary gas.
Modern industrial systems and biomass-fired furnaces require surface treatments that can withstand aggressive chemical, thermal, and corrosive environments. This study investigates the corrosion and thermal resistance of plasma-sprayed Al2O3-TiO2 coatings produced using a DC air–hydrogen plasma spray process. Coatings of compositions of Al2O3, Al2O3-3 wt.% TiO2, Al2O3-13 wt.% TiO2, and Al2O3-40 wt.% TiO2 were deposited on steel substrates with a Ni/Cr bond layer by plasma spraying. The coatings were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) to evaluate their morphology, elemental composition, and crystalline phases. Electrochemical tests were performed in a naturally aerated 0.5 mol/L NaCl solution and cyclic thermal–chemical exposure tests (500 °C using 35% KCl) to assess their corrosion kinetics and thermal stability. The results indicate that pure Al2O3 and low TiO2 (3 wt.%) coatings exhibit fine barrier properties, while coatings with a higher TiO2 content develop additional phases (e.g., Ti3O5, Al2TiO5) that improve thermal resistance but reduce chemical durability.