In the coming years, as a result of changing climate policies and finite fossil fuel resources, energy producers will be compelled to introduce new fuels with lower carbon footprints. One of the solutions is hydrogen, which can be burned or co-fired with methane in energy generation systems. Therefore, this study presents a thermodynamic and emission analysis of a gas turbine fueled by a mixture of CH₄ and H₂, as well as pure hydrogen. Numerical studies were conducted for the actual operating parameters of the LM6000 gas turbine in both simple and combined cycles. Aspen Hysys and Chemkin-Pro 2023R1 commercial software were used for the calculations. It was demonstrated that with a constant turbine inlet temperature set at 1723 K, the thermal efficiency increased from 39.4% to 40.2% for the gas turbine cycle and from 49% to 49.4% for the combined cycle gas turbine. Nitrogen oxides emissions were calculated using the reactor network, revealing that an increase in H₂ content above 20%vol. in the fuel leads to a significant rise in nitric oxides emissions. In the case of pure H₂, emissions are more than three times higher than for CH₄. The main reason for this increase in emissions was identified as the greater presence of H, O, and OH radicals in the reaction zone, causing an acceleration in the formation of nitric oxides.

There has been a gradual increase in the field of parts recovery from cars that are withdrawn from use. However, the disposal of automotive shredder residue (ASR) still remains a significant problem. ASR is refuse derived fuel (RDF), which contains mainly plastics, fiber sponges, and rubbers in different proportions, and therefore a thermal treatment of selected waste samples is applied. The presented research includes thermogravimetry (TG) analysis and differential thermogravimetric (DTG) analysis, as well as a proximate and an ultimate analysis of the ASR samples. The obtained results were processed and used as an input for modelling. The numerical calculations focused on the identification of the ASR’s average composition, the raw pyrolysis process product, its dry pyrolytic gas composition, and the combustible properties of the pyrolytic gases. The TGA analysis with three heating rate levels covered the temperature range from ambient to 800 °C. The thermal decomposition of the studied samples was in three stages confirmed with three peaks observed at the temperatures 280, 470, and 670 °C. The amount of solid residue grew with the heating rates and was in the range of 27–32 wt%. The numerical calculation of the pyrolysis process showed that only 0.46 kg of dry gas were formed from 1 kg of ASR. The gas yield increased with the rising temperature, and, at the same time, its calorific value decreased from 19.22 down to 14.16 MJ/m³. This is due to the decomposition of C₆₊ hydrocarbons and the promotion of CO formation. The thermodynamic parameters of the combustion process for a pyrolytic gas air mixture, such as the adiabatic flame temperature and laminar flame speed, were higher than for methane and were, respectively, 2073 °C and 1.02 m/s.

The combustion of gaseous fuels in condensing boilers contributes to the greenhouse gas and toxic compound emissions in exhaust gases. Hydrogen, as a clean energy carrier, could play a key role in decarbonizing the residential heating sector. However, its significantly different combustion behavior compared to hydrocarbon fuels requires thorough investigation prior to implementation in heating systems. This study presents experimental and theoretical analyses of the co-combustion of natural gas with hydrogen in low-power-output condensing boilers (second and third generation), with hydrogen content of up to 50% by volume. The results show that mixtures of hydrogen and natural gas contribute to increasing heat transfer in boilers through convection and flue gas radiation. They also highlight the benefits of using the heat from the condensation of vapors in the flue gases. Other studies have observed an increase in efficiency of up to 1.6 percentage points compared to natural gas at 50% hydrogen content. Up to a 6% increase in the amount of energy recovered by water vapor condensation was also recorded, while exhaust gas losses did not change significantly. Notably, the addition of hydrogen resulted in a substantial decrease in the emission of nitrogen oxides (NOx) and carbon monoxide (CO). At 50% hydrogen content, NO_x emissions decreased several-fold to 2.7 mg/m³, while CO emissions were reduced by a factor of six, reaching 9.9 mg/m³. All measured NO_x values remained well below the current regulatory limit for condensing gas boilers, which is 33.5 mg/m³. These results highlight the potential of hydrogen blending as a transitional solution on the path toward cleaner residential heating systems.

This academic paper revolves around the results of research on the change in emission parameters of the used heating boiler following the introduction of the overheated water stream, which had an impact on different emission parameters. The research results provide an insight into the hard coal combustion process, which had a significant impact on the change in the chemical composition of exhaust gases: it contributed to the lower mass concentration of the emitted dust and black carbon (PM) as well as nitric oxides (NOx) while, at the same time, playing a significant role in increasing the mass concentration of the emitted carbon oxide (CO). Two types of devices were used for the purposes of conducting the research at hand: a boiler with an automatic fuel feeding system with one combustion chamber and a boiler with a combustion chamber and an afterburning chamber fitted over it. Apart from the measurements of mass concentration of the emitted harmful substances, the research also focused on measurements of temperature inside the combustion and afterburning chambers, as well as the temperature of exhaust gases and their oxygen content. As part of the research, water steam was introduced to the combustion and afterburning chambers at the flow rate of 0.71 kg/h and 3.60 kg/h for boilers operating at a minimum power of 30% and a nominal power of 100%. An original steam generator with an overheated water steam production range from 0.71 kg/h to 3.60 kg/h was used to create and feed the water steam. The efficiency of the combustion process was calculated using the obtained results for each operating configuration of a given boiler.

Gas turbines are widely used in power generation due to their reliability, flexibility, and high efficiency. As the energy sector transitions towards low-carbon alternatives, hydrogen and ammonia are emerging as promising fuels. This study investigates the thermodynamic and combustion performance of a GE LM6000 gas turbine fueled by methane/hydrogen and methane/ammonia fuel blends under varying levels of oxygen enrichment (21%, 30%, and 40% $O_2$ by volume). Steady-state thermodynamic simulations were conducted using Aspen HYSYS, and combustion modeling was performed using ANSYS Chemkin-Pro, assuming a constant thermal input of 102 MW. Results show that increasing hydrogen content significantly raises flame temperature and burning velocity, whereas ammonia reduces both due to its lower reactivity. Net power output and thermal efficiency improved with higher fuel substitution, peaking at 43.46 MW and 42.7% for 100% $N{H}_3$. However, $N{O}_{\mathrm{x}}$ emissions increased with higher hydrogen content and oxygen enrichment, while $N{H}_3$ blends exhibit more complex emission trends. The findings highlight the trade-offs between efficiency and emissions in future low-carbon gas turbine systems.

The decarbonization of energy-intensive industrial sectors requires the implementation of low-carbon fuels and advanced combustion technologies. This study investigates the co-combustion of hydrogen and natural gas in an industrial diffusion burner, with particular emphasis on pollutant emissions...