This article reviews the critical role of material selection and design in ensuring efficient performance and safe operation of gas turbine engines fuelled by ammonia–hydrogen. As these energy fuels present unique combustion characteristics in turbine combustors, the identification of suitable materials becomes imperative. Detailed material characterisation is indispensable for discerning defects and degradation routes in turbine components, thereby illuminating avenues for improvement. With elevated turbine inlet temperatures, there is an augmented susceptibility to thermal degradation and mechanical shortcomings, especially in the high-pressure turbine blade—a critical life-determining component. This review highlights challenges in turbine design for ammonia–hydrogen fuels, addressing concerns like ammonia corrosion, hydrogen embrittlement, and stress corrosion cracking. To ensure engine safety and efficacy, this article advocates for leveraging advanced analytical techniques in both material development and risk evaluation, emphasising the interplay among technological progress, equipment specifications, operational criteria, and analysis methods.
There has been a gradual increase in the field of parts recovery from cars that are withdrawn from use. However, the disposal of automotive shredder residue (ASR) still remains a significant problem. ASR is refuse derived fuel (RDF), which contains mainly plastics, fiber sponges, and rubbers in different proportions, and therefore a thermal treatment of selected waste samples is applied. The presented research includes thermogravimetry (TG) analysis and differential thermogravimetric (DTG) analysis, as well as a proximate and an ultimate analysis of the ASR samples. The obtained results were processed and used as an input for modelling. The numerical calculations focused on the identification of the ASR’s average composition, the raw pyrolysis process product, its dry pyrolytic gas composition, and the combustible properties of the pyrolytic gases. The TGA analysis with three heating rate levels covered the temperature range from ambient to 800 °C. The thermal decomposition of the studied samples was in three stages confirmed with three peaks observed at the temperatures 280, 470, and 670 °C. The amount of solid residue grew with the heating rates and was in the range of 27–32 wt%. The numerical calculation of the pyrolysis process showed that only 0.46 kg of dry gas were formed from 1 kg of ASR. The gas yield increased with the rising temperature, and, at the same time, its calorific value decreased from 19.22 down to 14.16 MJ/m3. This is due to the decomposition of C6+ hydrocarbons and the promotion of CO formation. The thermodynamic parameters of the combustion process for a pyrolytic gas air mixture, such as the adiabatic flame temperature and laminar flame speed, were higher than for methane and were, respectively, 2073 °C and 1.02 m/s.
The transition to clean energy is crucial for mitigating the impacts of climate change and achieving sustainable development. Reliance on fossil fuels, which are integral to manufacturing and transportation, remains a major contributor to greenhouse gas (GHG) emissions. Biomass gasification presents a renewable energy alternative that can significantly reduce emissions. However, proper disposal of municipal solid waste (MSW) and agricultural residues, such as date palm waste (DPW), is an increasing global challenge, including in Qatar. This study evaluates the economic feasibility of implementing an MSW and DPW gasification plant for clean electricity generation in Qatar. The country’s growing population and economic development have led to substantial waste production, making it an ideal location for waste-to-energy (WTE) initiatives. Using discounted cash flow (DCF) analysis, the study estimates the capital cost of a 373 MWth facility at approximately $12.07 million, with annual operating costs of about $4.09 million and revenue of $26.88 million in 2023. The results indicate a net present value (NPV) of $245.77 million, a return on investment (ROI) of 84.80%, a payback period of approximately 5 years over a 20-year project lifetime and a net reduction of 206,786 tonnes CO2 annually. These findings demonstrate the economic viability of biomass gasification in Qatar while contributing to reduced GHG emissions and advancing the country’s sustainability goals under Qatar National Vision 2030.
The transition period in the transformation of the energy industry from fossil fuels to renewable sources is based on the use of natural gas, including local deposits with high nitrogen content. The main goal of the study was investigation of nitrogen influence on methane flames in swirled combustion process in model gas turbine combustion chamber. Flame stability, heat transfer and toxic compounds emission like carbon monoxide, nitrogen oxide were studied. It was shown that when the air fuel ratio decreases, emission falls twice between the lowest and the highest equivalence ratio; adding nitrogen to fuel contributes to a significant reduction in NO levels; even 20% volumetric addition of nitrogen causes high NO emissions drop; rise of N2 share in the fuel shifts the heat release zone towards the burner outlet; additional nitrogen flux in the fuel lowers the local oxygen content and alters the flow within fuel injection zone. Carbon monoxide emissions were negligible. It was concluded that nitrogen diluted natural gas can be burned in gas turbines while maintaining low toxic emissions. This work can further enhance the utilization of non standard natural gases to help mitigate carbon neutral energy system transformation issues.
15 August 2019 in International Journal of Numerical Methods for Heat & Fluid Flow
Purpose: The aim of this study is to identify key factors limiting efficiency of pumped heat energy storage systems and determine some general features of transient behavior of solid state, sensible heat storages. Moreover, it aimed at establishing a feasible approach to transient conjugate heat transfer (CHT) analyses for such applications. Design/methodology/approach: A zero-dimensional analytical model is used to determine the system efficiency sensitivity to efficiency of its components. Analysis of argon gas flow in an exemplary configuration of layered bed thermal energy storage is presented. The analysis incorporates a unsteady reynolds averaged navier stokes model with conjugate heat transfer between gas and solid storage core. Findings: It is established that exergetic efficiency of the heat storage is one of the key factors for the system’s overall performance. Three full cycles of storage charging and discharging having 17 h physical time in total are simulated, with calculation of exergetic efficiency for each of the cycles. From standpoint of the system efficiency, it is concluded that the presented heat storage kind has limited exergetic efficiency because of severe temperature drop at the solid–fluid interface in comparison to granular kind of heat storage devices. From the methodological standpoint, it is concluded that calculating the exergetic efficiency of the heat storage by direct computational fluid dynamics (CFD) analysis requires significant amount of walltime and computational resources. Originality/value: The paper presents unconventional approach to using standard CFD tools by exploiting numerical diffusion to numerically suppress high-frequency solution oscillations. This strategy grants that the analysis, otherwise requiring impractically long computation walltime, is completed within a practical time.