The influence of roughness and the way it affects the adhesion properties and surface free energy (SFE) of polysiloxanes hydrophobised basalt fibres–reinforced cement mortars were determined in this article. The physical properties of mortars were investigated in the experimental part, which also explored the impact of hydrophobisation and basalt fibres (BF) addition on SFE, frost resistance, contact angle (CA), and roughness. A device capable of calculating all parameters was used to indicate the surface roughness and 3D topography. Prior to and after conducting surface and weight hydrophobisation, the contact angle of mortars was specified. Subsequently, it was used for carrying out SFE calculation by means of Neumann’s method, enabling us to characterize the adhesion properties and wettability of mortars. The research indicated that the surface roughness was substantially decreased, in turn raising the frost resistance. The corrosion resistance drops when the surface roughness, water absorption, and number of fibres in the mortar increase. The SEM images presenting the structure of polysiloxane coating and mortars were provided.
This paper examines the effect of uniaxially aligned carbon nanotube (CNT) on flexural and free vibration analysis of CNT-reinforced functionally graded plate. The mathematical model includes expansion of Taylor’s series up to the third degree in the thickness co-ordinate. Since there is a parabolic variation in transverse shear strain deformation across the thickness co-ordinate, the shear correction factor is not necessary. A nine-node two-dimensional (2D) C0 isoparametric element containing seven nodal unknowns per node was developed in the finite element code. The final material properties of CNT-reinforced functionally graded plate are estimated using the extended rule of mixture. The effect of CNT distribution, boundary condition, volume fraction and loading pattern are studied by developing a finite element code. An additional finite element code was developed for the study of the influence of concentrated mass on free vibration analysis of CNT-reinforced functionally graded plate.
The article presents a proposal of a model of fatigue destruction of hydrophobised ceramic brick, i.e., a basic masonry material. The brick surface was hydrophobised with two inorganic polymers: a nanopolymer preparation based on dialkyl siloxanes (series 1–5) and an aqueous silicon solution (series 6–10). Nanosilica was added to the polymers to enhance the stability of the film formed on the brick surface. To achieve an appropriate blend of the polymer liquid phase and the nano silica solid phase, the mixture was disintegrated by sonication. The effect of the addition of nano silica and sonication on changes in the rheological parameters, i.e., viscosity and surface tension, was determined. Material fatigue was induced by cyclic immersion of the samples in water and drying at a temperature of 100 °C, which caused rapid and relatively dynamic movement of water. The moisture and temperature effect was determined by measurement of changes in surface hardness performed with the Vickers method and assessment of sample absorbability. The results provided an approximate picture of fatigue destruction of brick and hydrophobic coatings in relation to changes in their temporal stability. Additionally, SEM images of hydrophobic coatings in are shown.
The article is dedicated to the research and development of intensive methods for curing products by capturing and binding CO2. It aims to improve and increase the productivity of technologies for the production of artificially carbonated building materials and products. Soda production wastes, limestone dust and finely dispersed limestone dust were used as the research objects. Secondary raw materials have been investigated using modern methods of phase composition and granulometry test. Intensive methods of production of accelerated carbonation of systems consisting of soda wastes were tested using multi-parameter optimization methods. The effects of recycled lime materials on the strength and hydrophysical properties of the obtained material were determined. The secondary raw materials effect depended on the composition of the raw mixture, molding conditions, CO2 concentration applied to the carbonate curing chamber, and the duration of exposure to environments with high CO2 content. It was found that the most effective way of providing accelerated carbonation curing of construction materials and products is a combined carbonation method, combining the principles of dynamic and static methods. It was concluded that the optimal CO2 concentration in the gas-air mixtures used for carbonate curing is 30%–40%.
The present paper is the first study on the hygrothermal analysis (i.e., effect of temperature and moisture loadings) of laminated composite skew conoids with reasonable depth and thickness. In order to solve the hygrothermal problem of laminated composite skew conoids, the cubic variation in displacement field, along with cross curvature effects of the shell, were considered. In the present analysis, the shear correction factor is not needed due to the parabolic variation of transverse shear strain. The zero transverse shear stress conditions at the top and bottom of the shell were imposed in the mathematical model. The novelty of our model is reflected by the simultaneous addition of twist curvature in the strain field, as well as the curvature in the displacement field allowing the reasonably thick and deep laminated composite rhombic conoid. The conoid behavior differs from the usual shells, like cylindrical or spherical ones, due to its inherent twist curvature with the complex geometry and different location of maximum deflection. The finite element (FE) implementation of the present realistic mathematical model was carried out using a nine-noded curved isoparametric element with seven unknowns at each node. The C0 FE implementation of the present mathematical model was done and coded in FORTRAN. The present model results were compared and found in good agreement with other solutions published in the literature. Hygrothermal analysis was performed for skew conoids having a different skew angle, temperature, moisture concentration, curvatures, ply orientation, thickness ratio, and boundary conditions.