Non-destructive monitoring methods and continuous monitoring systems based on them are crucial elements of modern systems for the management and maintenance of assets which include reinforced concrete structures. The purpose of our study was to summarise the data on the most common sensors and systems for the non-destructive monitoring of reinforced concrete structures developed over the past 20 years. We considered systems based on electrochemical (potentiometry, methods related to polarisation) and physical (electromagnetic and ultrasonic waves, piezoelectric effect, thermography) examination methods. Special focus is devoted to the existing sensors and the results obtained using these sensors, as well as the advantages and disadvantages of their setups or other equipment used. The review considers earlier approaches and available commercial products, as well as relatively new sensors which are currently being tested.

Spherical zinc is well known as an effective pigment for the corrosion protection of carbon steel. However, a high proportion of spherical Zn in a coating leads to difficulties in fabricating the coating solution and increased cost. In this work, the influence of flake ZnAl alloy in silicate coatings on the corrosion protection properties of steel substrates was investigated. The electrochemical behaviour of coatings containing different flake ZnAl alloy content immersed in NaCl solution (3.5 wt%) was evaluated using an electrochemical impedance spectroscopy (EIS) method. A salt spray test was performed to evaluate corrosion on the coating surface. Pull-off tests of the coatings before and after the salt spray process were performed, and the surface morphology was analysed to determine the degradation of corrosion resistance. The results show that silicate coating containing flake ZnAl alloy (25 wt%) possesses the highest total resistance (1417 Ω) and the longest time to the appearance of white rust (720 h). The surface morphology of the coating containing 25 wt% flake ZnAl alloy was found to include corrosion products with the most compacted surface, which effectively prevents the penetration of electrolytes to the interface between the coating and the steel.

The marine environment is highly corrosive for mild and low alloy steels. This study aimed to enhance the corrosion resistance of the AH36 steel in a saline medium by coating it with a copper particles reinforced polyaniline (PANI) layer. PANI and Cu particles were grown on the steel surface by electrodepositing methods. Firstly, PANI was electropolymerized in the presence of oxalic acid, followed by the electrodeposition of Cu particles at different deposition times. The coating showed a well-distribution of Cu particles in the polymer matrix and excellent adhesion. Furthermore, the Cu particles and PANI-coated steels exhibited corrosion resistance significantly in the saline medium compared to the bare substrate and pristine PANI-coated samples. The improved corrosion protection of a Cu@PANI coating on the AH36 steel could contribute to forming a physical barrier by filling Cu particles on the PANI pores.

A calcareous deposit is a by-product of the cathodic polarization in seawater environments. This study presents the results of evaluating the anticorrosion and anti-macro-biofouling effectiveness of a calcareous deposit layer on the surface of the cathodically polarized AH36 structural steel in tropical seawater. The polarization is induced with initial current densities at which the calcareous deposit layer formed with both aragonite and brucite for 12 months continuously. The protective properties of the layer were compared with those of the passive layer from corrosion products under the same environmental conditions. The macro-biofouling in the tropical seawater is observed in the closed and open surfaces of the steel. The comparison of the anticorrosion property shows that, to some degree, the calcareous deposit layer contributes to surface passivation, as in the case of the corrosion product layer. In addition, the composition of the brucite and aragonite in the calcareous layer in the study plays a role as a macro-biofouling growth-limiting factor.

Ethanol extraction was employed to isolate a range of compounds from waste products derived from coconut fiber production (coconut dust) in Ben Tre, Vietnam. Phytochemical screening confirmed the presence of flavonoids, tannins, polyphenols, saponins, alkaloids, flobatannins, and anthraquinones among the extracted substances. FT-IR spectroscopy analysis supported the identification of oxygen and nitrogen atoms within functional groups (e.g., O–H, N–H, C–O) and aromatic rings, characteristic of typical corrosion inhibitors. Mass spectrometry investigations indicated that when St3 steel was exposed to an alkaline solution lacking chlorides, a passive film composed of FeOOH formed on the surface. However, upon the addition of NaCl at a concentration of 1.00 mol/dm3, FeCl, FeCl2Cl–, and FeCl3Cl– compounds were detected across the analyzed surface, while peaks corresponding to FeOO– were absent. Remarkably, areas with the highest concentration of particles corresponded to regions exhibiting visible corrosion damage under magnification. The addition of 2.00 g/dm3 of coconut dust extract to the chloride solution prevents the formation of Fe and Cl compounds on the steel surface. Consequently, only peaks characteristic of FeOO– and organic fragments containing oxygen atoms from the extract were observed. Based on these results, it can be assumed that coconut dust extract has the potential to inhibit local (pitting) corrosion of low-carbon steel (St3) when exposed to aqueous alkaline solutions simulating concrete pore liquid containing chlorides. The addition of 2.00 g/dm3 of the extract has been shown to prevent pitting formation at a chloride concentration of 1.00 mol/dm3. Conversely, in the absence of the extract, visible local corrosion damage was observed upon magnification. These findings provide a basis for further exploration of the protective properties of coconut dust extract as an environment-friendly corrosion inhibitor for mild steel in concrete environments containing chlorides.

Предложена конструкция биметаллического пакетного датчика для моделирования коррозии стальной арматуры в бетоне, вызванной гальваническими микропарами, в присутствии хлоридов. Проанализированы пары металлов низкоуглеродистая сталь/медь, низкоуглеродистая сталь/никель, низкоуглеродистая сталь/серебро. Наибольшая чувствительность получена для пары низкоуглеродистая сталь/серебро. Однако с учетом доступности материалов (стоимости), в качестве оптимального решения с перспективой массового изготовления датчиков, принята пара низкоуглеродистая сталь/медь. Изучено влияние толщины пластин металлов и диэлектрика в диапазоне от 0,1 до 5 мм на чувствительность датчика. Наибольшая чувствительность устройства достигается при толщине пластин металлов и диэлектрика 0,1-0,2 мм. Применение более тонких пластин (фольги) повышает риск замыкания устройства и его выхода из строя при подготовке к работе. Проведена апробация датчика, состоящего из 10 пар пластин, в водной вытяжке из бетона в присутствии хлоридов. Установлено значение пороговой концентрации хлорид-ионов ≥0,1 моль/дм³, при которой наблюдается активно-пассивный переход. При дальнейшем увеличении концентрации хлорид-ионов наблюдается возрастание плотности тока на датчике. Плотность тока на датчике, соответствующая пассивному состоянию, составляет 8,6 мкА/см² при толщине электролита над поверхностью 20 мм. При наибольшей изученной концентрации хлоридов 1,00 моль/дм³ превышение плотности тока на датчике относительно пассивного состояния достигает 5,3 раз. Потенциал пластин датчика в состоянии измерения (замыкания через электролит) при увеличении концентрации хлоридов смещается в область более отрицательных значений. Полученные результаты согласуются с данными оценки скорости коррозии по методу поляризационного сопротивления. Биметаллический пакетный датчик может быть использован для создания систем мониторинга коррозии стальной арматуры в бетоне в присутствии хлорид-ионов. Для цитирования: Као Ньят Линь, Шевцов Д.С., Нгуен Ван Чи, Нонг Куок Куанг, Нгуен Ван Хоа, Зяблов А.Н., Зарцын И.Д. Разработка биметаллического пакетного датчика для мониторинга коррозии стальной арматуры в железобетонных конструкциях. Изв. вузов. Химия и хим. технология. 2023. Т. 66. Вып. 8 С. 121-128. DOI: 10.6060/ivkkt.20236608.6881.