In this paper, the areca fiber was extracted by physical and chemical treatment, and then the areca fiber/natural latex composite was prepared by natural latex impregnation technology. In order to combine areca fiber and natural rubber latex better, three silane coupling agents with different action mechanism were selected: Si−69, KH550, and KH570 which were used to treat the areca fiber/natural latex compound. The results show that the silane coupling agent can change the surface of the fiber from hydrophilic surface to organophilic surface, making the bonding of areca fiber to natural latex more closely. At the same time, the mechanical properties, physical and mechanical properties, swelling properties, and dynamic viscoelastic properties of the tightly bonded areca fiber/nature latex composites were improved. After observing the micro-structure through a scanning electron microscope, it was found that the three silane coupling agents could effectively bind areca fiber and natural latex to enhance the performance of the composite material, of which Si−69 performed best, and the tensile strength and tear strength of the composite increased by 21.19% and 12.90% respectively.
In this study, the two key factors affecting the thermal performance of the insert rubber and stress distribution on the tire sidewall were analyzed extensively through various performance tests and simulations to promote the development of run-flat tires. Four compounds and two structures of insert rubber were designed to investigate the effects of heat accumulation and stress distribution on durability testing at zero pressure. It was concluded that the rigidity and tensile strength of the compound were negatively correlated with temperature. The deformation was a key factor that affects energy loss, which could not be judged solely by the loss factor. The stress distribution, however, should be considered in order to avoid early damage of the tire caused by stress concentration. On the whole, the careful balance of mechanical strength, energy loss, and structural rigidity was the key to the optimal development of run-flat tires. More importantly, the successful implementation of the simulations in the study provided important and useful guidance for run-flat tire development.
The mixer is the most widely used batch mixing equipment in the rubber industry. The rotor is a core component and has a great impact on the mixing effect of the equipment. The current rotor structure design is done empirically, being tightly dependent on practical experience. This paper proposes a method for optimizing the rotor structure by using optimization algorithms combined with numerical simulation technology. Using MATLAB software, a parametric design program for synchronous rotors and a set of optimization programs for the particle swarm optimization (PSO) algorithm were written. The global distribution index was used as the fitness function to optimize the synchronous rotor configuration. A comparative analysis of the rotors before and after optimization shows that the optimization process is feasible, and the results are reliable. This provides new ideas for the design and development of mixer rotors.
In the cracking process of waste tires, pyrolysis carbon black (CBp), as a solid product, accounts for about 35% of the total tire rubber content. Here, the treated CBp has been gradually applied to the tire formula to improve the recycling efficiency of waste tires. This study elucidated the influence of adding CBp during the tire mixing process on soft friction and metal wear. Compared with industrial carbon black (I-CB), the friction coefficient of CBp was smaller at different mixing stages, and the ripple caused by adhesion friction was not evident. After the modified CBp (M-CBp) was obtained by implementing the surface activation of common CBp (C-CBp), the friction coefficient between M-CBp and metal increased by 10%, while the filler dispersion and comprehensive mechanical properties showed an upward trend. The wear rate of metal was higher than that observed after adding I-CB during the same mixing mode; thus, it was necessary to strengthen the wear resistance of the inner-wall surface of the mixing chamber. The –OH group on the M-CBp surface can also participate in the silane coupling reaction and aggravate the metal wear of the mixer chamber wall. Through a comparison of results, the mixing friction coefficient can reflect the strength of filler–rubber interaction, which in turn can preliminarily represent the dispersion effect and comprehensive properties, reveal the reason behind the poor performance of CBp, and highlight the need for modification from the perspective of tribology.
In the process of rubber extrusion, the feed structure directly affects the extrusion quality, extrusion uniformity, screw lateral force, and feed power consumption. Until now, the feed structure was mainly based on empirical designs, and there was no theoretical model for the optimal design of a feed structure. This paper focused on the squeezing mechanical analysis and model establishment of the feeding process in which viscoelastic rubber strips are passed through feed-wedge clearance in cold-feed extruders. The screw flight rotation squeezing process was simplified into a disc rotation squeezing process; the instantaneous squeezing velocity in the disc rotation squeezing model was derived according to feed wedge clearance geometry and the disc rotating speed. By transforming rotation squeezing into differential slab squeezing, mathematical expressions of the velocity distribution, pressure distribution, total squeezing force, and power consumption in the feeding process were derived in a rectangular coordinate system under isothermal and quasi-steady assumptions and certain boundary conditions by using balance equations and a Newtonian viscous constitutive relation. Theoretical calculations and experimental values showed the same trend. Through comparison, it was found that the power consumption (P3) caused by sliding friction is about 200–900 W according to theoretical calculations, while the experimental test results show it to be about 300–700 W. Additionally, the difference between theoretical pressure value and the experimental pressure value can be controlled within 5–15%. This could reflect the main factors that affect the feeding process, so could be used for analyses of actual feeding problems, and to contribute to rough quantitative descriptions of the feeding process, finite element simulation, and the optimization of the feeding structure.
Silica and carbon black are the most important reinforcing systems in rubber formula. In the process of continuous optimization of the formula, silica gradually replaces carbon black by its characteristics. In view of the wear problem of the components of the mixer chamber caused by the increase in the proportion of silica in the formula, this research applied carbon matrix composite (CMC) materials to wear-resistant plate materials, and compared them with common wear-resistant (CWR) plate materials to explore the impact of replacing CWR plate with CMC on improving wear resistance and mixing effect. The results showed that compared with the CWR plate, CMC wear-resistant plate showed characteristics of a high friction coefficient and low wear rate (reduced by about 23%) in the mixing process of silica compound. However, the friction behavior of carbon black compound and carbon matrix composite wear-resistant plate showed an opposite trend, where the friction coefficient and wear rate increased simultaneously, especially the wear rate that increased by about 35%. The main reasons for the experimental results were related to the characteristics, elemental composition and surface morphology of carbon matrix composite, silica and carbon black. The experimental results also indicated that the carbon matrix composite wear-resistant plate is more suitable for a silica mixing process, and the increasing friction coefficient with decreasing wear rate of wear-resistant plate can further improve the importance of effective friction in mixing and prolonging the service life of wear-resistant plate.