We study macroion correlation effects on the thermodynamics of highly charged colloidal suspensions using a mean-field theory and primitive model computer simulations. We suggest a simple way to include the macroion correlations into the mean-field theory as an extension of the renormalized jellium model of Trizac and Levin [Phys. Rev. E 69, 031403 (2004)]. The effective screening parameters extracted from our mean-field approach are then used in a one-component model with macroions interacting via a Yukawa-like potential to predict macroion distributions. We find that inclusion of macroion correlations leads to a weaker screening and hence smaller effective macroion charge and lower osmotic pressure of the colloidal dispersion as compared to other mean-field models. This result is supported by comparison to primitive model simulations and experiments for charged macroions in the low-salt regime, where the macroion correlations are expected to be significant.

New biofuels are in demand and necessary to address the climate problems caused by the gases generated by fossil fuels. Biohydrogen, which is a clean biofuel with great potential in terms of energy capacity, is currently impacting our world. However, to produce biohydrogen, it is necessary to implement novel processes, such as Pressure Swing Adsorption (PSA), which raise the purity of biohydrogen to 99.99% and obtain a recovery above 50% using lower energy efficiency. This paper presents a PSA plant to produce biohydrogen and obtain a biofuel meeting international criteria. It focuses on implementing controllers on the PSA plant to maintain the desired purity stable and attenuate disturbances that affect the productivity, recovery, and energy efficiency generated by the biohydrogen-producing PSA plant. Several rigorous tests were carried out to observe the purity behavior in the face of changes in trajectories and combined perturbations by considering a discrete observer-based LQR controller compared with a discrete PID control system. The PSA process controller is designed from a simplified model, evaluating its performance on the real nonlinear plant considering perturbations using specialized software. The results are compared with a conventional PID controller, giving rise to a significant contribution related to a biohydrogen purity stable (above 0.99 in molar fraction) in the presence of disturbances and achieving a recovery of 55% to 60% using an energy efficiency of 0.99% to 7.25%.

This paper shows the implementation of the Moth–Flame Optimization algorithm in a Cascade-H multilevel inverter with five and seven levels to determine the optimal switching sequence of the inverter’s semiconductor devices. The algorithm was coded in Matlab software, and the obtained switching sequences were implemented in a Cascade-H multilevel inverter laboratory prototype, where the output voltage waveform was obtained using a digital oscilloscope. The experimental Total Harmonic Distortion was obtained using a power quality analyzer. The experimental results show the improvement of the Total Harmonic Distortion in the voltage output. These results were compared with other papers in the literature with different metaheuristic methods concerning the same modulation. These findings demonstrate the feasibility of employing the Moth–Flame Optimization Algorithm to significantly reduce the Total Harmonic Distortion, obtaining a lower value than most analyzed papers.

Herein, we report the synthesis of Au nanoparticles (AuNPs) in chitosan (CTS) solution by chemically reducing HAuCl₄. CTS was further functionalized with glycidyl methacrylate (chitosan-g-glycidyl methacrylate/AuNP, CTS-g-GMA/AuNP) to improve the mechanical properties for cellular regeneration requirements of CTS-g-GMA/AuNP. Our nanocomposites promote excellent cellular viability and have a positive effect on cytokine regulation in the inflammatory and anti-inflammatory response of skin cells. After 40 days of nanocomposite exposure to a skin wound, we showed that our films have a greater skin wound healing capacity than a commercial film (TheraForm^®), and the presence of the collagen allows better cosmetic ave aspects in skin regeneration in comparison with a nanocomposite with an absence of this protein. Electrical percolation phenomena in such nanocomposites were used as guiding tools for the best nanocomposite performance. Our results suggest that chitosan-based Au nanocomposites show great potential for skin wound repair.

The structure of charge-stabilized colloidal dispersions has been studied through a one-component model using a Yukawa potential with density-dependent parameters examined with integral equation theory and Monte Carlo simulations. Partial thermodynamic consistency was guaranteed by considering the osmotic pressure of the dispersion from the approximate mean-field renormalized jellium and Poisson-Boltzmann cell models. The colloidal structures could be accurately described by the Ornstein-Zernike equation with the Rogers-Young closure by using the osmotic pressure from the renormalized jellium model. Although we explicitly show that the correct effective pair-potential obtained from the inverse Monte Carlo method deviates from the Yukawa shape, the osmotic pressure constraint allows us to have a good description of the colloidal structure without losing information on the system thermodynamics. Our findings are corroborated by primitive model simulations of salt-free colloidal dispersions.

In this work, electrical resistivity tomography was carried out together with physical hydrogeology techniques to evaluate the karst aquifer in the northwest region of the Yucatán Peninsula in a study area near the western edge of the Ring of Cenotes of the Chicxulub Crater. In addition, based on a systematic compilation of open-access data of water levels reported for the peninsular aquifer, maps of groundwater isolines and groundwater flows were generated using IDW interpolation, Empirical Bayesian Kriging, and the Flow Net method. From these results, a shallow aquifer is observed, with the presence of heterogeneities such as possible dissolution conduits and/or flooded caverns, approximately 20 m below ground level, formed by the dissolution processes of limestone rocks. On a regional scale, the geomorphological influence of the Ring of Cenotes on groundwater flows was observed. In general, the flow directions observed from these maps coincide with those conceptualized for this region of the peninsular aquifer. Nevertheless, some differences were observed depending on the interpolation method used. Our results contribute to hydrogeological studies carried out in the periphery of this ring, where the vulnerability of the aquifer to anthropogenic contamination has been highlighted due to the intrinsic features of the karst environment.