Various human activities have been the main causes of surface water pollution. The uneven distribution of industrial enterprises in the territories of the main river basins of Ukraine do not always allow the real state of the water quality to be assessed. This article has three purposes: (1) the modification of the Ukrainian method for assessing the WQI, taking into account the level of negative impact of the most dangerous chemical elements, (2) the modeling of WQI assessment using fuzzy logic and (3) the creation of an artificial neural network model for the prediction of the WQI. The fuzzy logic model used four input variables and calculated one output variable (WQI). In the final stage of the study, six ANN models were analyzed, which differed from each other in various loss function optimizers and activation functions. The optimal results were shown using an ANN with the softmax activation function and Adam’s loss function optimizer (MAPE = 9.6%; R² = 0.964). A comparison of the MAPE and R² indicators of the created ANN model with other models for assessing water quality showed that the level of agreement between the forecast and target data is satisfactory. The novelty of this study is in the proposal to modify the WQI assessment methodology which is used in Ukraine. At the same time, the phased and joint use of mathematical tools such as the fuzzy logic method and the ANN allow one to effectively evaluate and predict WQI values, respectively.

Efficient photoluminescence (PL) up-conversion in CdSe/ZnS quantum dots prepared by an organometallic approach is reported. It is demonstrated that the efficiency of photon energy up-conversion and the magnitude of the spectral shift can be controlled by (i) the thickness of the ZnS layers, (ii) the temperature dependence of the excited-state absorption coefficient, and (iii) the dependence on the excitation intensity. From the analysis of the experimental data, it is proposed that intrinsic gap states are involved as intermediate states in the PL up-conversion, rather than nonlinear two-photon absorption or Auger processes.

Thioflavin T (ThT) informed microviscosity changes can be used to monitor protein aggregation. Steady-state, time-resolved and lasing spectroscopy were used to detect transient states in α-synuclein - a protein associated with Parkinson's disease. The major focus was on the nucleation phase, where conventional ThT fluorescence assay lacks appropriate sensitivity to detect early stage oligomers. Instead, lasing spectroscopy and lasing threshold parameters, in particular, were sensitive to detecting protein oligomers. Through lasing spectroscopy, a change in microviscosity correlating with the stages of protein aggregation was observed at two wavelengths 405 and 440 nm. The two wavelengths are associated with free dye molecules and β-sheet bound ThT molecules. This provides a perspective on elucidating the early formed protein aggregation, a critical aspect in understanding the pathogenesis of neurodegenerative diseases. The insights from the presented study shows the potential of using lasing spectroscopy as a sensitive tool in studying protein aggregation dynamics.

A bus seat needs to be designed ergonomically for better seating comfort. The present study is intended to develop a cost-effective ergonomic bus seat design based on seat comfort and safety demands. As part of the proposed seat design procedure, seating comfort analysis, identifying preferred design features, and developing a seat design are included. An analysis of the bus seat back and seat pan profiles was conducted. Based on the results of the comfort analysis, the authors identified the preferred design features of bus seats during the design identification process. An improved bus seat prototype was developed based on selected design features in the design development stage. Seating comfort analyses were used to compare the achieved seat with the reference seat. The seat design developed in the present study may be applicable for various types of bus public transport.

The coherence length of the Frenkel excitons (N_coh) is one of the most critical parameters governing many key features of supramolecular J-aggregates. Determining experimentally the value of N_coh is a nontrivial task since it is sensitive to the technique/method applied, causing discrepancies in the literature data even for the same chemical compound and aggregation conditions. By using a combination of different experimental techniques including UV-vis-NIR, fluorescence emission, time-resolved photoluminescence, and transient absorption spectroscopies, we determined N_coh values for J-aggregates of a cyanine dye. We found that the absorption spectroscopy alone - a widely used technique- fails in determining right value for N_coh. The correct approach is based on the modification of photoluminescence lifetime and nonlinear response upon aggregation and careful analysis of the Stokes shift and electron-phonon coupling strength. This approach revealed that N_coh of JC-1 J-aggregates ranges from 3 to 6.

CO₂ emission limits introduced by the European Union are encouraging works on new-generation materials with reduced clinker content. Currently, fumed silica from hard coal combustion is used in cement and concrete technology in Europe and Poland. Its wide application depends mainly on its chemical and phase composition, especially the reactivity of pozzolanic acids and its high fineness similar to cement Many authors studied the influence of fly ashes from hard coal combustion, in accordance with PN-EN 450-1 and 450-2, on the properties of concrete, including the course of the carbonation process. There are no studies in the literature involving ashes from sewage sludge. The objective of the research is to assess the course of carbonation of concrete produced on the basis of fly ash from the thermal transformation of sewage sludge over time and to describe this phenomenon in a mathematical form. An additional objective was to analyze the physicochemical composition of sludge ash in accordance with the requirements of EN 450-1, ASTM-C618-03. In addition, this study also demonstrated the possibility of producing fly ash-modified standard concrete through the thermal treatment of sewage sludge. The average compressive strengths of Krakow gray concrete after curing for 28, 56, 90, and 365 days were 50.1 MPa, 50.6 MPa, 50.8 MPa, and 61.9 MPa, respectively. On the one hand, the additives introduced in the concrete mixture accelerate the carbonation process by shifting the carbonation front deep into the concrete and, on the other hand, create a denser microstructure In all cases, the largest increase in carbonation depth was observed up to the 56th day of the study, while the smallest increase was observed between 90 and 180 days. The diffusivity decreases and the rate of carbonation is reduced. The determined regression coefficients of hyperbolic models indicate the proper adjustment of the adopted hyperbolic model to the results of laboratory tests under accelerated carbonation conditions (R = 0.85–0.99), regardless of the content of fly ash from sewage sludge in ordinary concrete samples.