We examined the current groundwater (used for drinking) quality in Pakistan after implementation of Millennium Development Goals, including contaminants, their sources, and relevant health impacts. The drinking water quality parameters of most of the reported results exceeded the guidelines suggested by the World Health Organization (WHO) and National Environmental Quality Standards (NEQS). Natural sources of groundwater contamination have been activated due to anthropogenic activities like mining, and open dumping of industrial and domestic wastes which lead to poor groundwater quality. Globally, 780 million people, and 100 million people in Pakistan are exposed to unsafe water sources. Therefore, this review demonstrates the potential needs to achieve the safe drinking water goal of the Agenda 2030. The development of a proper monitoring network, installation of treatment plants, and implementation of legislations are recommended in this review.
Microbial fuel cells (MFCs) seem to have emerged in recent years to degrade the organic pollutants from wastewater. The current research also focused on phenol biodegradation using MFCs. According to the US Environmental Protection Agency (EPA), phenol is a priority pollutant to remediate due to its potential adverse effects on human health. At the same time, the present study focused on the weakness of MFCs, which is the low generation of electrons due to the organic substrate. The present study used rotten rice as an organic substrate to empower the MFC’s functional capacity to degrade the phenol while simultaneously generating bioenergy. In 19 days of operation, the phenol degradation efficiency was 70% at a current density of 17.10 mA/m2 and a voltage of 199 mV. The electrochemical analysis showed that the internal resistance was 312.58 Ω and the maximum specific capacitance value was 0.00020 F/g on day 30, which demonstrated mature biofilm production and its stability throughout the operation. The biofilm study and bacterial identification process revealed that the presence of conductive pili species (Bacillus genus) are the most dominant on the anode electrode. However, the present study also explained well the oxidation mechanism of rotten rice with phenol degradation. The most critical challenges for future recommendations are also enclosed in a separate section for the research community with concluding remarks.
Agro-waste management processes are evolving through the development of novel experimental approaches to understand the mechanisms in reducing their pollution levels efficiently and economically from industrial effluents. Agro-industrial effluent (AIE) from biorefineries that contain high concentrations of COD and color are discharged into the ecosystem. Thus, the AIE from these biorefineries requires treatment prior to discharge. Therefore, the effectiveness of a continuous flow bioreactor system (CFBS) in the treatment of AIE using hybrid waste sludge biochar (HWSB) was investigated. The use of a bioreactor with hydraulic retention time (HRT) of 1–3 days and AIE concentrations of 10–50% was used in experiments based on a statistical design. AIE concentration and HRT were optimized using response surface methodology (RSM) as the process variables. The performance of CFBS was analyzed in terms of COD and color removal. Findings indicated 76.52% and 66.97% reduction in COD and color, respectively. During biokinetic studies, the modified Stover models were found to be perfectly suited for the observed measurements with R2 values 0.9741 attained for COD. Maximum contaminants elimination was attained at 30% AIE and 2-day HRT. Thus, this study proves that the HWSB made from biomass waste can potentially help preserve nonrenewable resources and promote zero-waste attainment and principles of circular economy.
18 April 2023 in International Journal of Chemical Engineering
Microbial fuel cell (MFC) is a method that is both effective and environmentally friendly for producing renewable electricity. Several studies have shown that one of the major challenges is the generation of electrons as a result of poor exploitation of organic substrates. One of the most talked about issues in modern molecular fusion is the reutilization of biological organic waste in an MFC. In this article, the effective utilization of domestic organic waste as an organic supply for bacterial species to generate energy was highlighted. The findings that were obtained corresponded to the one-of-a-kind MFC operation in which a voltage of 110mV was generated in a time span of 12days during operation with an external resistance of 500. With an internal resistance of 117, the maximum power density and the current density were recorded 0.1047mW/m2 and 21.84mA/m2, respectively. According to the results of the biological study, strains of bacteria such as Pseudomonas aeruginosa, Acinetobacter schindleri, and Pseudomonas nitroreducens are the ones responsible for producing energy. In addition, final remarks with proposals for the future have been enclosed.