Anastasiia Shabalina

Dr. Anastasiia Shabalina


Research Focus & Metrics

Academic Career Length

5Years (2022-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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31 October 2024 in Nanomaterials
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ASAnastasiia Shabalina
Anastasiia Shabalina
Valeriy Anatolevich KozlovValeriy Anatolevich Kozlov
Valeriy Anatolevich Kozlov
IPIvan Popov
Ivan Popov
Sergey V. GudkovSergey V. Gudkov
Sergey V. Gudkov
Development of new antibacterial materials for solving biomedical problems is an extremely important and very urgent task. This review aims to summarize recent articles (from the last five and mostly the last three years) on the nanoparticle/polymer composites for biomedical applications. Articles on polymeric nanoparticles (NPs) and hydrogel-based systems were not reviewed, since we focused our attention mostly on the composites of polymeric matrix with at least one inorganic filler in the form of NPs. The fields of application of newly developed antibacterial NPs/polymer composites are described, along with their composition and synthetic approaches that allow researchers to succeed in preparing effective composite materials for medical and healthcare purposes.

21 November 2022 in Nanomaterials
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ASAnastasiia Shabalina
Anastasiia Shabalina
AGAlexandra Golubovskaya
Alexandra Golubovskaya
EFElena D. Fakhrutdinova
Elena D. Fakhrutdinova
Sergei KulinichSergei Kulinich
Sergei Kulinich
OVO. V. Vodyankina
O. V. Vodyankina
Valery A. SvetlichnyiValery A. Svetlichnyi
Valery A. Svetlichnyi
Laser methods are successfully used to prepare complex functional nanomaterials, especially for biomedicine, optoelectronics, and heterogeneous catalysis. In this paper, we present complex oxide and composite nanomaterials based on Bi and Si produced using laser ablation in liquid followed by subsequent powder annealing. Two synthesis approaches were used, with and without laser post-treatment of mixed (in an atomic ratio of 2:1) laser-generated Bi and Si colloids. A range of methods were used to characterize the samples: UV-Vis diffusion reflection, IR and Raman spectroscopy, synchronous thermal analysis, X-ray diffraction, transmission electron microscopy, as well as specific surface-area evaluation. We also followed the dynamics of phase transformations, as well as composition, structure and morphology of annealed powders up to 800 °C. When heated, the non-irradiated series of samples proceeded from metallic bismuth, through β-Bi2O3, and resulted in bismuth silicates of various stoichiometries. At the same time, in their laser-irradiated counterparts, the formation of silicates proceeded immediately from the amorphous Bi2SiO5 phase formed after laser treatment of mixed Bi and Si colloids. Finally, we show their ability to decompose persistent organic molecules of Rhodamine B and phenol under irradiation with a soft UV (375 nm) source.

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Sergey AnikeevSergey Anikeev
Sergey Anikeev
MKMaria Kaftaranova
Maria Kaftaranova
VHValentina Hodorenko
Valentina Hodorenko
SIStanislav Ivanov
Stanislav Ivanov
NANadezda Victorovna Artyukhova
Nadezda Victorovna Artyukhova
VGVictor E. Gunther
Victor E. Gunther
Alloys based on TiNi are widely used in various fields of technology and medicine. In the present work, we report on the preparation of TiNi-alloy-based wire with the shape-memory effect, which was used for compression clips for surgery. The composition and structure of the wire and its martensitic and physical–chemical properties were studied using SEM, TEM, optic microscopy, profilometry, mechanical tests, etc. The TiNi alloy was found to consist of B2 and B19′ and secondary-phase particles of Ti2Ni, TiNi3 and Ti3Ni4. Its matrix was slightly enriched in Ni (50.3 at.% of Ni). A homogeneous grain structure was revealed (an average grain size of 19 ± 0.3 μm) with equal quantities of grain boundaries of special and general types. The surface oxide layer provides improved biocompatibility and promotes the adhesion of protein molecules. Overall, the obtained TiNi wire was concluded to exhibit martensitic, physical and mechanical properties suitable for its use as an implant material. The wire was then used for manufacturing compression clips with the shape-memory effect and applied in surgery. The medical experiment that involved 46 children demonstrated that the use of such clips in children with double-barreled enterostomies permitted improvement in the results of surgical treatment.

11 October 2022 in Metals
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MKMaria Kaftaranova
Maria Kaftaranova
VHValentina Hodorenko
Valentina Hodorenko
Sergey AnikeevSergey Anikeev
Sergey Anikeev
NANadezda Victorovna Artyukhova
Nadezda Victorovna Artyukhova
ASAnastasiia Shabalina
Anastasiia Shabalina
VGVictor Gunther
Victor Gunther
This work is devoted to the physical and mechanical properties of porous alloys based on TiNi alloyed with different amounts of Cu additive. We show that by doping a porous TiNi alloy with copper instead of nickel, it is possible to obtain characteristics acceptable for use in implantology and superior to those of known porous TiNi alloys. Cu addition in the range from 1 to 10 at.% is shown to optimize the properties of tested alloys. There is a decrease in the minimal martensitic transformation stress τMsmin from 37 to 17 MPa when compared to initial unalloyed TiNi. Alloys with 3 and 6 at.% of Cu are found to be optimal for use in medical practice. Along with a wide temperature range of reversible deformations that cover the range of operating temperatures (273–313 K), such alloys demonstrate their martensitic transformation stress values below 28 MPs. This permits to model implantable structures of complex configuration from such materials under a certain temperature regime.

13 June 2025 in Horticulturae
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ASAnastasiia Shabalina
Anastasiia Shabalina
Valeriy Anatolevich KozlovValeriy Anatolevich Kozlov
Valeriy Anatolevich Kozlov
MPMark Paskhin
Mark Paskhin
IPIvan Popov
Ivan Popov
Sergey V. GudkovSergey V. Gudkov
Sergey V. Gudkov
Photoconversion covers (PCCs) are specialized materials designed to modify light conditions in greenhouses, thereby enhancing plant growth and development. Recently, extensive research and development efforts have focused on improving and characterizing both components of PCCs: the cover material and the photoconversion agent (phosphor(s)). Given that the true impact of PCCs on plant growth can only be assessed through greenhouse experiments, while surveying recent publications from 2020 to 2024, in this review, we specifically tried to focus on such experiments. A total of 58 studies on PCCs for greenhouse applications were analyzed. Of those, 26 studies introduced novel materials, including phosphors and PCCs, with the potential to enhance plant growth, although greenhouse experiments were not conducted to evaluate their performance. The remaining 32 studies provided experimental data on PCC efficiency in promoting plant growth through plant-based experiments. To summarize and compare the findings from these greenhouse experiments, in this work, we systematically classify plant growth parameters and examine their application across the surveyed studies.

Verified
Journal Article
Open access
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ASAnastasiia Shabalina
Anastasiia Shabalina
Sergey AnikeevSergey Anikeev
Sergey Anikeev
Sergei KulinichSergei Kulinich
Sergei Kulinich
NANadezda Victorovna Artyukhova
Nadezda Victorovna Artyukhova
VVVitaly Vlasov
Vitaly Vlasov
VGVictor E. Gunther
Victor E. Gunther
TiNi alloys are very widely used materials in implant fabrication. When applied in rib replacement, they are required to be manufactured as combined porous-monolithic structures, ideally with a thin, porous part well-adhered to its monolithic substrate. Additionally, good biocompatibility, high corrosion resistance and mechanical durability are also highly demanded. So far, all these parameters have not been achieved in one material, which is why an active search in the field is still underway. In the present study, we prepared new porous-monolithic TiNi materials by sintering a TiNi powder (0–100 µm) on monolithic TiNi plates, followed by surface modification with a high-current pulsed electron beam. The obtained materials were evaluated by a set of surface and phase analysis methods, after which their corrosion resistance and biocompatibility (hemolysis, cytotoxicity, and cell viability) were evaluated. Finally, cell growth tests were conducted. In comparison with flat TiNi monoliths, the newly developed materials were found to have better corrosion resistance, also demonstrating good biocompatibility and potential for cell growth on their surface. Thus, the newly developed porous-on-monolith TiNi materials with different surface porosity and morphology showed promise as potential new-generation implants for use in rib endoprostheses.