New biofuels are in demand and necessary to address the climate problems caused by the gases generated by fossil fuels. Biohydrogen, which is a clean biofuel with great potential in terms of energy capacity, is currently impacting our world. However, to produce biohydrogen, it is necessary to implement novel processes, such as Pressure Swing Adsorption (PSA), which raise the purity of biohydrogen to 99.99% and obtain a recovery above 50% using lower energy efficiency. This paper presents a PSA plant to produce biohydrogen and obtain a biofuel meeting international criteria. It focuses on implementing controllers on the PSA plant to maintain the desired purity stable and attenuate disturbances that affect the productivity, recovery, and energy efficiency generated by the biohydrogen-producing PSA plant. Several rigorous tests were carried out to observe the purity behavior in the face of changes in trajectories and combined perturbations by considering a discrete observer-based LQR controller compared with a discrete PID control system. The PSA process controller is designed from a simplified model, evaluating its performance on the real nonlinear plant considering perturbations using specialized software. The results are compared with a conventional PID controller, giving rise to a significant contribution related to a biohydrogen purity stable (above 0.99 in molar fraction) in the presence of disturbances and achieving a recovery of 55% to 60% using an energy efficiency of 0.99% to 7.25%.

Pressure swing adsorption (PSA) technology is used in various applications. PSA is a cost-effective process with the ability to produce high-purity bio-hydrogen (99.99%) with high recovery rates. In this article, a PSA process for the production of bio-hydrogen is proposed; it uses two columns packed with type 5A zeolite, and it has a four-step configuration (adsorption, depressurization, purge, and repressurization) for bio-hydrogen production and regeneration of the beds. The aim of this work is to design and use an active fault-tolerant control (FTC) controller to raise and maintain a stable purity of 0.9999 in molar fraction (99.99%), even with the occurrence of actuator faults. To validate the robustness and performance of the proposed discrete FTC, it has been compared with a discrete PID (proportional–integral–derivative) controller in the presence of actuator faults and trajectory changes. Both controllers achieve to maintain stable purity by reducing the effect of faults; however, the discrete PID controller is not robust to multiple faults since the desired purity is lost and fails to meet international standards to be used as bio-fuel. On the other hand, the FTC scheme reduces the effects of individual and multiple faults by striving to maintain a purity of 0.9999 in molar fraction and complying with international standards to be used as bio-fuel.

An experimental validation of fractional-order PID (FOPID) controllers, which were applied to a two coupled tanks system, is presented in this article. Two FOPID controllers, a continuous FOPID (cFOPID) and a discrete FOPID (dFOPID), were implemented in real-time. The gains tuning process was accomplished by applying genetic algorithms while considering the cost function with respect to the tracking error and control effort. The gains optimization process was performed directly to the two-tanks non-linear model. The real-time implementation used a National Instruments PCIe-6321 card as a data acquisition system; for the interface, we used a Simulink Matlab and Simulink Desktop Real-Time Toolbox. The performance of the fractional controllers was compared with the performance of classical PID controllers.

Inexpensive equipment for the deposition of semiconductor thin films by SILAR was designed. Using a low-cost embedded system, a prototype controlled through a human–machine interface (HMI) was constructed. Simple, open-source software was used. The use of an HMI and programming based on state machines showed an improvement in the system control, program flow, and efficiency. The system development consists of three stages: structural design, electronics, and programming of the control and HMI. This system controls the variables of the SILAR process, such as immersion time in chemical solutions, sequence of substrates, and the number of cycles. In order to test the automated SILAR prototype, copper oxide thin films on glass substrates were processed. The copper oxide thin films have been characterized by X-ray diffraction (XRD), UV-VIS, and SEM to investigate the structural, optical, and morphological properties, respectively.

A Ti6Al4V alloy was plasma-oxidized at 600 °C during 1, 2, 3, 5 and 8 h and corroded in an artificial saliva solution. Electrochemical evaluation was performed by using potentiodynamic polarization curves, linear polarization resistance (LPR), and electrochemical impedance spectroscopy (EIS) measurements during 100 h. Corroded specimens were characterized by using Raman spectroscopy and scanning electronic microscopy (SEM). All tests indicated that the highest corrosion resistance was obtained for specimen oxidized during 3 h since the noblest free corrosion potential, lowest passive and corrosion current density values, as well as the highest polarization resistance values were obtained under these circumstances. EIS measurements indicated that the highest impedance and phase angle values obtained for this specimen exhibited a high capacitive behavior typical of a very compact passive film.