This paper describes the preparation and obtained magnetic properties of large single domain iron oxide nanoparticles. Such ferrimagnetic particles are particularly interesting for diagnostic and therapeutic applications in medicine or (bio)technology. The particles were prepared by a modified oxidation method of non-magnetic precursors following the green rust synthesis and characterized regarding their structural and magnetic properties. For increasing preparation temperatures (5 to 85 °C), an increasing particle size in the range of 30 to 60 nm is observed. Magnetic measurements confirm a single domain ferrimagnetic behavior with a mean saturation magnetization of ca. 90 Am²/kg and a size-dependent coercivity in the range of 6 to 15 kA/m. The samples show a specific absorption rate (SAR) of up to 600 W/g, which is promising for magnetic hyperthermia application. For particle preparation temperatures above 45 °C, a non-magnetic impurity phase occurs besides the magnetic iron oxides that results in a reduced net saturation magnetization.

Using magnetic nanoparticles (MNPs) for extracorporeal heating applications results in higher field strength and, therefore, particles of higher coercivity can be used, compared to intracorporeal applications. In this study, we report the synthesis and characterization of barium hexa-ferrite (BaFe₁₂O₁₉) nanoparticles as potential particles for magnetic heating. Using a precipitation method followed by high-temperature calcination, we first studied the influence of varied synthesis parameters on the particles’ properties. Second, the iron-to-barium ratio (Fe/Ba = r) was varied between 2 and 12. Vibrating sample magnetometry, scanning electron microscopy and X-ray diffraction were used for characterization. A considerable influence of the calcination temperature (T_cal) was found on the resulting magnetic properties, with a decrease in coercivity (H_C) from values above 370 kA/m for T_cal = 800–1000 °C to H_C = 45–70 kA/m for T_cal = 1200 °C. We attribute this drop in H_C mainly to the formation of entirely multi-domain particles at high T_cal. For the varying Fe/Ba ratios, increasing amounts of BaFe₂O₄ as an additional phase were detected by XRD in the small r (barium surplus) samples, lowering the particles’ magnetization. A decrease in H_C was found in the increased r samples. Crystal size ranged from 47 nm to 240 nm and large agglomerates were seen in SEM images. The reported particles, due to their controllable coercivity, can be a candidate for extracorporeal heating applications in the biomedical or biotechnological field.

The integration of electronic functionalities into textiles for use as wearable sensors, energy harvesters, or coolers has become increasingly important in recent years. A special focus is on efficient thermoelectric materials. Copper iodide as a p-type thermoelectrically active, nontoxic material is attractive for energy harvesting and energy generation because of its transparency and possible high-power factor. The deposition of CuI on polyester spacer fabrics by wet chemical processes represents a great potential for use in textile industry for example as flexible thermoelectric energy generators in the leisure or industrial sector as well as in medical technologies. The deposited material on polyester yarn is investigated by electron microscopy, x-ray diffraction and by thermoelectric measurements. The Seebeck coefficient was observed between 112 and 153 µV/K in a temperature range between 30 °C and 90 °C. It is demonstrated that the maximum output power reached 99 nW at temperature difference of 65.5 K with respect to room temperature for a single textile element. However, several elements can be connected in series and the output power can be linear upscaled. Thus, CuI coated on 3D spacer fabrics can be attractive to fabricate thermoelectric devices especially in the lower temperature range for textile medical or leisure applications.

Using magnetic nanoparticles for extracorporeal magnetic heating applications in bio-medical technology allows higher external field amplitudes and thereby the utilization of particles with higher coercivities (H_C). In this study, we report the synthesis and characterization of high coercivity cobalt ferrite nanoparticles following a wet co-precipitation method. Particles are characterized with magnetometry, X-ray diffraction, Mössbauer spectroscopy, transmission electron microscopy (TEM) and calorimetric measurements for the determination of their specific absorption rate (SAR). In the first series, Co_xFe_3−xO₄ particles were synthesized with x = 1 and a structured variation of synthesis conditions, including those of the used atmosphere (O₂ or N₂). In the second series, particles with x = 0 to 1 were synthesized to study the influence of the cobalt fraction on the resulting magnetic and structural properties. Crystallite sizes of the resulting particles ranged between 10 and 18 nm, while maximum coercivities at room temperatures of 60 kA/m for synthesis with O₂ and 37 kA/m for N₂ were reached. Magnetization values at room temperature and 2 T (M_RT,2T) up to 60 Am²/kg under N₂ for x = 1 can be achieved. Synthesis parameters that lead to the formation of an additional phase when they exceed specific thresholds have been identified. Based on XRD findings, the direct correlation between high-field magnetization, the fraction of this antiferromagnetic byphase and the estimated transition temperature of this byphase, extracted from the Mössbauer spectroscopy series, we were able to attribute this contribution to akageneite. When varying the cobalt fraction x, a non-monotonous correlation of H_C and x was found, with a linear increase of H_C up to x = 0.8 and a decrease for x > 0.8, while magnetometry and in-field Mössbauer experiments demonstrated a moderate degree of spin canting for all x, yielding high magnetization. SAR values up to 480 W/g (@290 kHz, 69 mT) were measured for immobilized particles with x = 0.3, whit the external field amplitude being the limiting factor due to the high coercivities of our particles.

Nanowire‐based plasmonic lasers are now established as nano‐sources of coherent radiation, appearing as suitable candidates for integration into next‐generation nanophotonic circuitry. However, compared to their photonic counterparts, their relatively high losses and large lasing thresholds still pose a burdening constraint on their scalability. In this study, the lasing characteristics of zinc oxide (ZnO) nanowires on silver (Ag) and aluminum (Al) substrates, operating as optically‐pumped short‐wavelength plasmonic nanolasers, are systematically investigated in combination with the size‐dependent performance of the hybrid cavity. A nanomanipulation‐assisted single nanowire optical characterization combined with high‐throughput photoluminescence spectroscopy enabled the correlation of the lasing characteristics to the metal substrate and the nanowire diameter. The results evidence that the coupling between excitons and surface plasmons is closely tied to the relationship between substrate dispersive behavior and cavity diameter. Such coupling dictates the degree to which the lasing character, be it more plasmonic‐ or photonic‐like, can define the stimulated emission features and, as a result, the device performance.