This study focuses on polyamide 6/organo-modified montmorillonite (PA6/OMMT) nanocomposites as potential liner materials, given the growing interest in enhancing the performance of type IV composite overwrapped hydrogen storage pressure vessels. The mechanical properties of PA6/OMMT composites with varying filler concentrations were investigated across a temperature range relevant to hydrogen storage conditions (−40 °C to +85 °C). Liner collapse, a critical issue caused by rapid gas discharge, was analyzed using an Ishikawa diagram to identify external and internal factors. Mechanical testing revealed that higher OMMT content generally increased stiffness, especially at elevated temperatures. The Young’s modulus and first yield strength exhibited non-linear temperature dependencies, with 1 wt. per cent OMMT content enhancing yield strength at all tested temperatures. Dynamic mechanical analysis (DMA) indicated that OMMT improves the storage modulus, suggesting effective filler dispersion, but it also reduces the toughness and heat resistance, as evidenced by lower glass transition temperatures. This study underscores the importance of optimizing OMMT content to balance mechanical performance and thermal stability for the practical application of PA6/OMMT nanocomposites in hydrogen storage pressure vessels.

In the automotive sector, the zero emissions area has been dominated by battery electric vehicles. However, prospective users cite charging times, large batteries, and the deployment of charging stations as a counter-argument. Hydrogen will offer a solution to these areas, in the future. This research focuses on the development of a prototype three-wheeled vehicle that is named Neumann H2. It integrates state-of-the-art energy storage systems, demonstrating the benefits of solar-, battery-, and hydrogen-powered drives. Of crucial importance for the R&D platform is the system’s ability to record its internal states in a time-synchronous format, providing valuable data for researchers and developers. Given that the platform is equipped with the ROS2 Open-Source interface, the data are recorded in a standardized format. Energy management is supported by artificial intelligence of the “Reinforcement Learning” type, which selects the optimal energy source for operation based on different layers of high-fidelity maps. In addition to powertrain control, the vehicle also uses artificial intelligence to detect the environment. The vehicle’s environment-sensing system is essentially designed to detect, distinguish, and select environmental elements through image segmentation using camera images and then to provide feedback to the user via displays.

This study investigates the hydrogen permeability of injection-molded polyamide 6 (PA6) nanocomposites reinforced with organo-modified montmorillonite (OMMT) at varying concentrations (1, 2.5, 5, and 10 wt. %) for potential use as Type IV composite-overwrapped pressure vessel (COPV) liners. While previous work examined their mechanical properties, this study focuses on their crystallinity, morphology, and gas barrier performance. The precise inorganic content was determined using thermal gravimetry analysis (TGA), while differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and scanning electron microscopy (SEM) were used to characterize the structural and morphological changes induced by varying filler content. The results showed that generally higher OMMT concentrations promoted γ-phase formation but also led to increased agglomeration and reduced crystallinity. The PA6/OMMT-1 wt. % sample stood out with higher crystallinity, well-dispersed clay, and low hydrogen permeability. In contrast, the PA6/OMMT-2.5 and -5 wt. % samples showed increased permeability, which corresponded to WAXD and SEM evidence of agglomeration and DSC results indicating a lower degree of crystallinity. PA6/OMMT-10 wt. % showed the most-reduced hydrogen permeability compared to all other samples. This improvement, however, is attributed to a tortuous path effect created by the high filler loading rather than optimal crystallinity or dispersion. SEM images revealed significant OMMT agglomeration, and DSC analysis confirmed reduced crystallinity, indicating that despite the excellent barrier performance, the compromised microstructure may negatively impact mechanical reliability, showing PA6/OMMT-1 wt. % to be the most balanced candidate combining both mechanical integrity and hydrogen impermeability for Type IV COPV liners.

The present study explores the potential improvement of the mechanical properties of bio-based polyamide 11 (PA11) for demanding industrial application using natural and surface-treated mica at 1, 2 and 5 wt%. Suppressed water uptake by up to 4% was revealed with an unfavorable effect of the surface treatment. Impact strength decreased with filler content from 39.6 kJ m⁻² to between 22–10 kJ m⁻², while stiffness and resistance towards deformation improved: flexural modulus rose from 518.5 MPa to 596 MPa at 5 wt%-treated small particle, and elastic modulus changed from 542.7 MPa to 705.6 MPa. Particle size dependent trends were observed in crystallinity by Differential Scanning Calorimetry (DSC). Surface treatment promoted the presence of a mesophase form, which was also presented by Scanning Electron Microscopy (SEM). Dynamic Mechanical Analysis (DMA) revealed increased internal friction, temperature-dependent modifications in the elastic properties and a glass transition temperature of 36.6 °C. X-ray Diffraction (XRD) proved an unusual decrease in basal spacing of mica from 9.92 to 9.82 Å due to silanization; however, the compounding process provoked some increase again up to 10.03 Å. Results highlight a viable pathway to modify the properties of PA11 with a primarily role in the filler concentration and dimensions over the surface characteristics.