The presence of pharmaceutical compounds in the whole environment is a growing concern. These compounds might be present in the effluents of wastewater treatment plants and, hence, irrigation with treated sewage may be a source of groundwater pollution. The volcanic aquifer that lies NE of Gran Canaria (Spain) was studied to address the relationship of the occurrence of pharmaceutical compounds and a golf course that has been irrigated with regenerated water since 1973. Of the 14 analyzed groundwater samples, five wells were chosen to perform annual monitoring. Irrigation water and soil leachate were also evaluated. The target analytes were atenolol, metamizole, fluoxetine, ibuprofen, nicotine, permethrin, caffeine, and their metabolite paraxanthine. The environmental risk is limited as the concentrations of the pharmaceuticals measured in the sampled wells were always below 60 ng·L⁻¹ (lower than the detected caffeine and nicotine concentrations). Wide variations for the same wells were measured among sampling campaigns, and also among the different wells. The study points to the importance of sample conservation during transport and the need to perform analyses immediately, or to follow an in-situ extraction procedure to carry concentrated samples under better conditions.

Water and food security are of global concern. Improving knowledge on crops’ potential uptake of pharmaceutical compounds (PhCs) is necessary to guarantee consumer health and improve the public’s perception of reclaimed water reuse. This study aimed to determine how water management (bottom-up applied for being supplied by Subsurface Drip Irrigation) and the plant rhizosphere effect on the uptake of PhCs. Five PhCs were mixed: atenolol, carbamazepine, dicoflenac, ibuprofen and valsartan. A total of 5 treatments were considered: 3 concentrations of PhCs in agricultural volcanic soil: 0.1, 10 and 100 µg·L⁻¹; 0.1 µg·L⁻¹ in sterilized soil; and a blank with three plant replications at 30, 45, and 60 days after emerging. The maximum quantity of the added PhCs was 100 µg·kg soil⁻¹. A variant of the QuEChERS method was followed to extract PhCs from samples. The limits of quantification were between 10 ng·L⁻¹ and 100 ng·L⁻¹ in extracts. No PhCs over the limits of detection were detected (0.06–0.6 µg·kg⁻¹ of dry plant sample). Hence, the described water reuse methodology poses a negligible consumer risk, which contrasts with hydroponic systems in which this risk has been shown. The results are discussed in terms of the effects of irrigation system, water management and the soil-plant barrier.

The geometry and the hydraulic properties of the unsaturated zone is often difficult to evaluate from traditional soil sampling techniques. Soil samples typically provide only data of the upper layers and boreholes are expensive and only provide spotted information. Non-destructive geophysical methods and among them, electrical resistivity tomography can be applied in complex geological environments such as volcanic areas, where lavas and unconsolidated pyroclastic deposits dominate. They have a wide variability of hydraulic properties due to textural characteristics and modification processes suh as compaction, fracturation and weathering. To characterize the subsurface geology below the golf course of Bandama (Gran Canaria) a detailed electrical resistivity tomography survey has been conducted. This technique allowed us to define the geometry of the geological formations because of their high electrical resistivity contrasts. Subsequently, undisturbed soil and pyroclastic deposits samples were taken in representative outcrops for quantifying the hydraulic conductivity in the laboratory where the parametric electrical resistivity was measured in the field. A statistical correlation between the two variables has been obtained and a 3D model transit time of water infiltration through the vadose zone has been built to assess the vulnerability of the aquifers located below the golf course irrigated with reclaimed water.