In this paper, the production of a second-generation bioethanol from lignocellulosic vineyard cutting wastes was investigated in order to define the optimal operating conditions of the autohydrolysis pretreatment, chlorite delignification and simultaneous saccharification and fermentation (SSF). The autohydrolysis of vine-shoot wastes resulted in liquors containing mainly a mixture of monosaccharides, degradation products and spent solids (rich in cellulose and lignin), with potential utility in obtaining valuable chemicals and bioethanol. The autohydrolysis of the vine-shoot wastes was carried out at 165 and 180 °C for 10 min residence time, and the resulted solid and liquid phases composition were analysed. The resulted liquid fraction contained hemicellulosic sugars as a mixture of alpha (α) and beta (β) sugar anomers, and secondary by-products. The solid fraction was delignified using the sodium chlorite method for the separation of lignin and easier access of enzymes to the cellulosic sugars, and then, converted to ethanol by the SSF process. The maximum bioethanol production (6%) was obtained by autohydrolysis (165 °C), chlorite delignification and SSF process at 37 °C, 10% solid loading, 72 h. The principal component analysis was used to identify the main parameters that influence the chemical compositions of vine-shoot waste for different varieties.

In this study, the effect of common non-steroidal anti-inflammatory drugs on Lycopersicon esculentum rhizosphere microbiota was monitored. The experiments were performed with artificially contaminated soil with ibuprofen (0.5 mg·kg⁻¹), ketoprofen (0.2 mg·kg⁻¹) and diclofenac (0.7 mg·kg⁻¹). The results evidenced that the rhizosphere microbiota abundance decreased especially under exposure to diclofenac (187–201 nmol·g⁻¹ dry weight soil) and ibuprofen (166–183 nmol·g⁻¹ dry weight soil) if compared with control (185–240 nmol·g⁻¹ dry weight soil), while the fungal/bacteria ratio changed significantly with exposure to diclofenac (<27%) and ketoprofen (25%) and lower in the case of diclofenac (75%), but their percentage changed with exposure to diclofenac, ketoprofen and ibuprofen. Such changes in abundance, structure and the metabolic activity of Lycopersicon esculentum rhizosphere microbiota under exposure to common non-steroidal anti-inflammatory drugs suggest that there is a probability to also change the ecosystem services provided by rhizosphere microbiota.

Radon (Rn) is a hazardous radioactive gas that poses significant health risks in enclosed indoor environments. This study investigates the potential of silver-exchanged clinoptilolite-rich natural zeolite (NZ-Ag⁺) for the removal of Rn from air. Natural zeolite (NZ) was thermally treated and further modified to enhance its adsorption characteristics. The thermally treated NZ (200 °C) was first exchanged in Na⁺ form, since Na⁺ is more easily exchanged in clinoptilolite with hydrated Ag⁺ ions than the other exchangeable cations. The modification with Ag⁺ was carried out at room temperature using ultrasonic processing to obtain (NZ-Ag⁺). The materials were characterized in terms of chemical composition, cation exchange capacity, mineralogy, total surface area, pore volume, and thermal behavior. Rn adsorption experiments were performed using a closed-circuit system, and the efficiency of NZ-Ag⁺ was compared with that of NZ. The results indicate that NZ-Ag⁺ exhibits superior Rn adsorption capacity, achieving up to 50% higher retention efficiency compared to NZ. The improved performance is attributed to enhanced adsorption facilitated by silver ion clusters interacting with radon atoms. These results suggest that silver-exchanged zeolite represents a promising material for radon mitigation in air filtration systems, with potential applications in residential and occupational settings.

Gold nanoparticles (AuNPs) have a wide-ranging application and are widespread in samples with complex matrices; thus, efficient analytical procedures are necessary to identify and characterize this analyte. A sensitive analytical method for determination of AuNPs content in biological tissues, based on microwave-assisted acid wet digestion and graphite furnace atomic absorption spectrometry (GFAAS) validated in accordance with the requirements of Eurachem guideline and ISO 17025 standard, is presented in this study. The digestion procedure was optimized, and the figures of merit such as selectivity, limit of detection (0.43 µg L⁻¹), limit of quantification (1.29 µg L⁻¹, corresponding to 12.9 µg kg⁻¹ in tissue sample, considering the digestion), working range, linearity, repeatability ((RSD_r 4.15%), intermediate precision (RSD_R 8.07%), recovery in accuracy study (97%), were methodically evaluated. The measurement uncertainty was assessed considering the main sources of uncertainties and the calculated relative expanded uncertainty (k = 2) was 12.5%. The method was applied for the determination of AuNPs in six biological tissues (liver, small intestine, heart, lungs, brain and kidneys) and the found concentrations were generally at low levels, close or lower than LOQ.

A sound theoretical ground is required for sustainability related concepts reconciliation and operationalization. The current study investigates the opportunities to conceive a homogenous sustainability model derived from theoretical ecology, using as a prototype the “organization” concept from the Chemical Organizations Theory (COT). A sustainability problematization and a literature examination try to capture and link some useful perspectives and sustainability connected concepts. Some of the most influential methods and tools are reviewed, in particular among those relating to the triple bottom line framework and to the ecological footprint family, together with concepts close to the core sustainability definition, like resilience and circularity. Theoretical ecology provides candidate goal functions based on self-organization gradients, such as fitness functions and thermodynamic orientors. The COT formalism provides a higher abstraction level and the algorithms for patterns identification in a reactions network. The sustainability problematization reveals the motifs of a possible model of “total ecosystem”, which subordinates the anthropic cultural (social–economic) system to the thermodynamic, chemical, biological, and cultural determinisms regulating biological and cultural species of an ecological network.

Freshwater resources constitute a fundamental component of coupled natural–human systems, underpinning ecosystem functioning, biogeochemical cycling, and socio-economic development. Anthropogenic climate change (i.e., climate change attributable to human activity, as distinct from natural climatic variability), driven primarily by greenhouse gas emissions and land-use change, is exerting significant pressure on the global hydrological cycle, resulting in increased hydroclimatic variability, intensification of extreme hydrometeorological events, and progressive degradation of freshwater quality and availability. This review synthesizes recent scientific evidence on climate-induced impacts on water systems together with emerging adaptation and resilience strategies. The analysis is based on a systematic assessment of 100 peer-reviewed studies indexed in the Web of Science Core Collection (2010–2025) and synthesized following a PRISMA-informed (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) narrative review protocol. Beyond confirming well-established trends in precipitation regimes, cryospheric decline, increasing evapotranspiration, and the growing frequency of droughts and floods, this review quantifies the magnitude of these changes across the reviewed literature, including an approximately 134% increase in flood-related disasters since 1980 and a 29% increase in drought duration since 2000. More importantly, it provides an integrated synthesis that links physical climate impacts with adaptation strategies and socio-ecological resilience frameworks within a unified analytical perspective, thereby complementing previous domain-specific reviews that have generally examined these dimensions separately. Prominent adaptation pathways identified across the reviewed literature include nature-based solutions, integrated water resources management frameworks, and the deployment of digital water technologies. In parallel, resilience is increasingly conceptualized as the adaptive capacity of socio-hydrological systems to absorb disturbances, reorganize, and transform under changing climatic conditions. The findings highlight the need to strengthen integrated and cross-sectoral water governance, enhance climate-informed decision-making, and expand monitoring and data infrastructures to improve long-term water security and socio-ecological resilience under accelerating climate change.