Biochar (BC) addition is a novel and promising method for biogas yield increase. Brewer’s spent grain (BSG) is an abundant organic waste with a large potential for biogas production. In this research, for the first time, we test the feasibility of increasing biogas yield and rate from BSG digestion by adding BC, which was produced from BSG via torrefaction (low-temperature pyrolysis). Furthermore, we explore the digestion of BSG with the presence BCs produced from BSG via torrefaction (low-temperature pyrolysis). The proposed approach creates two alternative waste-to-energy and waste-to-carbon type utilization pathways for BSG: (1) digestion of BSG waste to produce biogas and (2) torrefaction of BSG to produce BC used for digestion. Torrefaction extended the short utility lifetime of BSG waste turned into BC. BSG was digested in the presence of BC with BC to BSG + BC weight ratio from 0 to 50%. The study was conducted during 21 days under mesophilic conditions in n = 3 trials. The content of dry mass 17.6% in all variants was constant. The kinetics results for pure BSG (0% BC) were: reaction rate constant (k) 1.535 d⁻¹, maximum production of biogas (B₀) 92.3 dm³∙kg⁻¹_d.o.m. (d.o.m. = dry organic matter), and biogas production rate (r), 103.1 dm³∙kg⁻¹_d.o.m.∙d⁻¹. his preliminary research showed that the highest (p < 0.05) r, 227 dm³∙kg⁻¹_d.o.m.∙d⁻¹ was due to the 5% BC addition. This production rate was significantly higher (p < 0.05) compared with all other treatments (0, 1, 3, 8, 10, 20, 30, and 50% BC dose). Due to the high variability observed between replicates, no significant differences could be detected between all the assays amended with BC and the variant 0% BC. However, a significant decrease of B₀ from 85.1 to 61.0 dm³∙kg⁻¹_d.o.m. in variants with the high biochar addition (20–50% BC) was observed in relation to 5% BC (122 dm³∙kg⁻¹_d.o.m.), suggesting that BC overdose inhibits biogas production from the BSG + BC mixture. The reaction rate constant (k) was not improved by BC, and the addition of 10% and 20% BC even decreased k relatively to the 0% variant. A significant decrease of k was also observed for the doses of 10%, 20%, and 30% when compared with the 5% BC (1.89 d⁻¹) assays.

In this study, 12 organic waste materials were subjected to TG/DTG thermogravimetric analysis and DSC calorimetric analysis. These analyses provided basic information about thermochemical transformations and degradation rates during organic waste pyrolysis. Organic waste materials were divided into six basic groups as follows: paper, cardboard, textiles, plastics, hygiene waste, and biodegradable waste. For each group, two waste materials were selected to be studied. Research materials were (i) paper (receipts, cotton wool); (ii) cardboard (cardboard, egg carton); (iii) textiles (cotton, leather); (iv) plastics (polyethylene (PET), polyurethane (PU)); (v) hygiene waste (diapers, leno); and (vi) biodegradable waste (chicken meat, potato peel). Waste materials were chosen to represent the most abundant waste that can be found in the municipal solid waste stream. Based on TG results, kinetic parameters according to the Coats–Redfern method were determined. The pyrolysis activation energy was the highest for cotton, 134.5 kJ × (mol∙K)⁻¹, and the lowest for leather, 25.2 kJ × (mol∙K)⁻¹. The DSC analysis showed that a number of transformations occurred during pyrolysis for each material. For each transformation, the normalized energy required for transformation, or released during transformation, was determined, and then summarized to present the energy balance. The study found that the energy balance was negative for only three waste materials—PET (−220.1 J × g⁻¹), leather (−66.8 J × g⁻¹), and chicken meat (−130.3 J × g⁻¹)—whereas the highest positive balance value was found for potato peelings (367.8 J × g⁻¹). The obtained results may be applied for the modelling of energy and mass balance of municipal solid waste pyrolysis.

The paper presents, for the first time, the results of fuel characteristics of biochars from torrefaction (a.k.a., roasting or low-temperature pyrolysis) of elephant dung (manure). Elephant dung could be processed and valorized by torrefaction to produce fuel with improved qualities for cooking. The work aimed to examine the possibility of using torrefaction to (1) valorize elephant waste and to (2) determine the impact of technological parameters (temperature and duration of the torrefaction process) on the waste conversion rate and fuel properties of resulting biochar (biocoal). In addition, the influence of temperature on the kinetics of the torrefaction and its energy consumption was examined. The lab-scale experiment was based on the production of biocoals at six temperatures (200–300 °C; 20 °C interval) and three process durations of the torrefaction (20, 40, 60 min). The generated biocoals were characterized in terms of moisture content, organic matter, ash, and higher heating values. In addition, thermogravimetric and differential scanning calorimetry analyses were also used for process kinetics assessment. The results show that torrefaction is a feasible method for elephant dung valorization and it could be used as fuel. The process temperature ranging from 200 to 260 °C did not affect the key fuel properties (high heating value, HHV, HHV_daf, regardless of the process duration), i.e., important practical information for proposed low-tech applications. However, the higher heating values of the biocoal decreased above 260 °C. Further research is needed regarding the torrefaction of elephant dung focused on scaling up, techno-economic analyses, and the possibility of improving access to reliable energy sources in rural areas.

Economic development and population growth lead to the increased production of chicken manure, which is a problematic organic waste in terms of its amount, environmental threats, and moisture content. In this study, hydrothermal carbonization, an emerging way of waste disposal, was performed on chicken manure to produce an energy-rich material called hydrochar. The effects of hydrothermal carbonization temperature (180, 240, 300 °C) and process time (30, 90, 180 min) were summarized. Proximate and ultimate analysis, as well as low and high heating values were applied both on raw material and derived hydrochars. Additionally, the performance of the process was examined. The obtained results show that hydrothermal carbonization is a feasible method for chicken manure disposal and valorization. Although the process time did not influence the fuel properties of chicken manure considerably, a higher temperature led to a significantly higher heating value, reaching 23,880.67 ± 34.56 J × g⁻¹ at 300 °C and 180 min with an improvement of ~8329 J × g⁻¹ compared with raw chicken manure (15,551.67 J × g⁻¹). Considering the energy gain value, the hydrochar derived at 240 °C in 30 min had the best result. Moreover, the energy consumption for this process was relatively low (124.34 ± 8.29 kJ × g⁻¹). With its still feasible fuel properties and high heating value of 20,267.00 ± 617.83 kJ × g⁻¹, it was concluded that these parameters of chicken manure hydrochar are the most beneficial and present a potential alternative for conventional fuel.

The proof-of-the-concept of application of low-temperature food waste biochars for the anaerobic digestion (AD) of food waste (the same substrate) was tested. The concept assumes that residual heat from biogas utilization may be reused for biochar production. Four low-temperature biochars produced under two pyrolytic temperatures 300 °C and 400 °C and under atmospheric and 15 bars pressure with 60 min retention time were used. Additionally, the biochar produced during hydrothermal carbonization (HTC) was tested. The work studied the effect of a low biochar dose (0.05 g_BC × g_TSsubstrate⁻¹, or 0.65 g_BC × L⁻¹) on AD batch reactors’ performance. The biochemical methane potential test took 21 days, and the process kinetics using the first-order model were determined. The results showed that biochars obtained under 400 °C with atmospheric pressure and under HTC conditions improve methane yield by 3.6%. It has been revealed that thermochemical pressure influences the electrical conductivity of biochars. The biomethane was produced with a rate (k) of 0.24 d⁻¹, and the most effective biochars increased the biodegradability of food waste (FW) to 81% compared to variants without biochars (75%).

Oxytree is a fast-growing energy crop with C4 photosynthesis. In this research, for the first time, the torrefaction kinetic parameters of pruned Oxytree biomass (Paulownia clon in Vitro 112) were determined. The influence of the Oxytree cultivation method and soil class on the kinetic parameters of the torrefaction was also investigated. Oxytree pruned biomass from a first-year plantation was subjected to torrefaction within temperature range from 200 to 300 °C and under anaerobic conditions in the laboratory-scale batch reactor. The mass loss was measured continuously during the process. The relative mass loss increased from 1.22% to 19.56% with the increase of the process temperature. The first-order constant rate reaction (k) values increased from 1.26 × 10⁻⁵ s⁻¹ to 7.69 × 10⁻⁵ s⁻¹ with the increase in temperature. The average activation energy for the pruned biomass of Oxytree torrefaction was 36.5 kJ∙mol⁻¹. Statistical analysis showed no significant (p < 0.05) effect of the Oxytree cultivation method and soil class on the k value. The results of this research could be useful for the valorization of energy crops such as Oxytree and optimization of waste-to-carbon and waste-to-energy processes.