Herein, the amino-capped TiO2 nanoparticles were synthesized using tetrabutyl titanate and amino polymers by a two-step sol-gel and hydrothermal method technique for the fabrication of functional cotton fabric. The prepared TiO2 nanoparticles and the treated cotton fabric were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), field emission scanning electron microcopy (FE-SEM) photocatalytic and antibacterial measurement. The results indicate the typical characteristic anatase form of the amino-capped TiO2 NPs with an average crystallite size of 14.9 nm. The treated cotton fabrics exhibit excellent antibacterial property and good photocatalytic degradation of methylene blue.
We developed a dual-strategy of Fe doping and CeO2 decoration to optimize the electronic structure and reaction energy barrier of Ni2P to achieve energy-efficient and chlorine-free hydrogen production by coupling the HER with HzOR in seawater.
Epoxy is an important resin matrix and has been widely applied in laminated composites as a coating or adhesive material. In this article, the phenolic was applied to modify the mechanical properties of epoxy resin. The phenolic modified epoxy resins with various phenolic content were prepared via a polytetrafluoroethylene mould, and the phenolic modified epoxy-based plain woven laminated composites (PWLCs) were manufactured via vacuum assisted resin transfer method for further study of phenolic modified epoxy resins’ mechanical properties. The compression tests were performed perpendicularly to thickness at 2 mm/min to investigate the mechanical performances of phenolic modified epoxy resins and epoxy-based PWLCs. The results showed that the addition of phenolic into epoxy could improve the mechanical performances of epoxy resins and epoxy-based composites at room temperature, and the phenolic influenced epoxy-based PWLC more than epoxy matrix at room temperature. However, at high temperatures, the addition of phenolic decreased the mechanical performances of epoxy resins and epoxy-based composites, and the adverse effect of phenolic became more serious with the increase of phenolic content at high temperature. In addition, the thermogravimetric analyses were also conducted from 30 °C to 800 °C on phenolic modified epoxy resins and the results showed that the phenolic modified epoxy resin had an earlier loss in weight than unmodified epoxy resin. The earlier loss in weight meant that the addition of phenolic into epoxy resin led to the formation of unstable molecules at high temperature.
Herein, ZnO nanoparticles (NPs) were synthesized using zinc acetate and an amino hyperbranched polymer. The methods of transmission electron microscope (TEM) and X-ray Diffraction (XRD) were applied to the characterization of ZnO NPs. Polypropylene (PP)/ZnO fiber was prepared using 1–5 wt% ZnO NPs via melt spinning. The ultraviolet light (UV)-degradation behavior, antibacterial activity and mechanical properties of PP fibers were characterized. The PP fiber filled with ZnO NPs presents better mechanical properties and the resistance to UV light degradation. For the best effect, the contents of ZnO NPs were set 4 wt% in PP fiber. FTIR analysis shows significant photo-degradation of PP induced by UV irradiation and a remarkable reduction in the UV degradation of the fiber filled with ZnO NPs. It is also observed that the ZnO NPs-filled fiber has good antibacterial actives against Escherichia coli and staphylococcus aureus.