In the last twenty years, research activity around the environmental applications of metal–organic frameworks has bloomed due to their CO₂ capture ability, tunable properties, porosity, and well-defined crystalline structure. Thus, hundreds of MOFs have been developed. However, the impact of their production on the environment has not been investigated as thoroughly as their potential applications. In this work, the environmental performance of various synthetic routes of MOF nanoparticles, in particular ZIF-8, is assessed through a life cycle assessment. For this purpose, five representative synthesis routes were considered, and synthesis data were obtained based on available literature. The synthesis included different solvents (de-ionized water, methanol, dimethylformamide) as well as different synthetic steps (i.e., hours of drying, stirring, precursor). The findings revealed that the main environmental weak points identified during production were: (a) the use of dimethylformamide (DMF) and methanol (MeOH) as substances impacting environmental sustainability, which accounted for more than 85% of the overall environmental impacts in those synthetic routes where they were utilized as solvents and as cleaning agents at the same time; (b) the electricity consumption, especially due to the Greek energy mix which is fossil-fuel dependent, and accounted for up to 13% of the overall environmental impacts in some synthetic routes. Nonetheless, for the optimization of the impacts provided by the energy use, suggestions are made based on the use of alternative, cleaner renewable energy sources, which (for the case of wind energy) will decrease the impacts by up to 2%.

Metal–organic frameworks (MOFs) could be utilized for a wide range of applications such as sorption, catalysis, chromatography, energy storage, sensors, drug delivery, and nonlinear optics. However, to date, there are very few examples of MOFs exploited on a commercial scale. Nevertheless, progress in MOF-related research is currently paving the way to new industrial opportunities, fostering applications and processes interconnecting fundamental chemistry with engineering and relevant sectors. Yet, the fabrication of porous MOF materials within resistant structures is a key challenge impeding their wide commercial use for processes such as adsorptive separation. In fact, the integration of nano-scale MOF crystallic structures into bulk components that can maintain the desired characteristics, i.e., size, shape, and mechanical stability, is a prerequisite for their wide practical use in many applications. At the same time, it requires sophisticated shaping techniques that can structure nano/micro-crystalline fine powders of MOFs into diverse types of macroscopic bodies such as monoliths. Under this framework, this review aims to bridge the gap between research advances and industrial necessities for fostering MOF applications into real life. Therefore, it critically explores recent advances in the shaping and production of MOF macro structures with regard to the binding materials that have received little attention to date, but have the potential to give new perspectives in the industrial applicability of MOFs. Moreover, it proposes future paths that can be adopted from both academy and industry and can further boost MOF exploitation.

The assessment of indoor environmental quality in historic buildings converted to museums is a significant tool in deep energy renovation processes, as it provides insights for the microclimatic conditions in the interiors of the building where vast numbers of visitors walk every year and where artifacts that are vulnerable to pollution are exhibited. In this work, aiming to contribute to the development of an energy retrofitting protocol applied in the Mediterranean region (HAPPEN MedZeb protocol) for museums hosted in historic buildings by providing useful data, an experimental campaign to evaluate the indoor environmental quality of a museum housed in a historic building located in Athens took place from February 2019 to April 2021 and was divided into two periods. The findings revealed high concentrations of volatile organic compounds as well as poor thermal comfort levels since the sensors recorded low acceptable percentages of T values within the limits from 7 to 33% for the entire experimental period. Based on the findings, recommendations for retrofitting interventions are made.

Students are often described as an under-reported and under-supported group of the population falling into energy poverty. Although the main drivers of energy poverty are well documented, up to this date little attention is given to housing tenure as a cause of energy poverty. This study aims to support the understanding of the motivations and barriers faced by property owners that rent accommodation to students for making energy efficiency improvements to their rented properties. With this understanding recommendations for alleviating energy poverty experienced by students living in the private rented sector can be formulated. The research conducted is based on qualitative methods; focus group discussions and interviews. Data were collected from almost 30 student landlords in seven EU countries between October 2017 and January 2018. Findings show that grants and financial incentives are key for the questioned proprietors to move to energy efficiency improvements of their property but bureaucracy burdens are a major barrier for moving forward with them. In addition, the need for stronger information campaigns on energy efficiency issues is revealed. Eventually, a number of financial, consumer protection, energy efficiency and informational measures for alleviating energy poverty experienced by students living in private rented accommodation are proposed.

Smart meters, one of the crucial enablers of the smart-grid concept and cornerstones in smart planning for cities, offer the opportunity for consumers to address their energy consumption effectively through timely and accurate data on their energy usage. However, previous studies have shown that smart meters may not lead to the desired energy savings unless actively used by households. To this end, the research presented in this paper investigates the penetration of smart meters at community level and explores how such a metering system can help people to understand and manage their energy use better. It examines the awareness about smart meters, looks into their presence in current accommodation and focuses on the views people have about smart meters. For this purpose, a questionnaire was prepared and distributed to a group of individuals residing in the wide area of Ancona province in Italy. Although the deployment of modern second-generation smart meters started in 2017 replacing the outdated smart meters massively installed in the 2000s, the results show low-to-moderate levels of awareness of modern smart meters among the respondents and a low presence of second-generation metering devices in their current accommodation. However, the general view expressed by the participants about smart meters is positive. The findings demonstrate that respondents are in need not only of a gauge that measures energy consumption but also of a tool that assists them to manage effectively their energy use.