In the last twenty years, research activity around the environmental applications of metal–organic frameworks has bloomed due to their CO₂ capture ability, tunable properties, porosity, and well-defined crystalline structure. Thus, hundreds of MOFs have been developed. However, the impact of their production on the environment has not been investigated as thoroughly as their potential applications. In this work, the environmental performance of various synthetic routes of MOF nanoparticles, in particular ZIF-8, is assessed through a life cycle assessment. For this purpose, five representative synthesis routes were considered, and synthesis data were obtained based on available literature. The synthesis included different solvents (de-ionized water, methanol, dimethylformamide) as well as different synthetic steps (i.e., hours of drying, stirring, precursor). The findings revealed that the main environmental weak points identified during production were: (a) the use of dimethylformamide (DMF) and methanol (MeOH) as substances impacting environmental sustainability, which accounted for more than 85% of the overall environmental impacts in those synthetic routes where they were utilized as solvents and as cleaning agents at the same time; (b) the electricity consumption, especially due to the Greek energy mix which is fossil-fuel dependent, and accounted for up to 13% of the overall environmental impacts in some synthetic routes. Nonetheless, for the optimization of the impacts provided by the energy use, suggestions are made based on the use of alternative, cleaner renewable energy sources, which (for the case of wind energy) will decrease the impacts by up to 2%.

In the 21st century, sustainable development is high on the international agenda, with the implementation of green walls contributing significantly to achieving environmental and social benefits, mainly in the frame of sustainable improvement of the building sector. The installation of a greening system can provide engineered solutions for stormwater management and climate change mitigation at both the urban and building level. This facilitates improving indoor comfort conditions and reducing energy needs. In order to improve the features of products and to facilitate the implementation of a proper technical standard, this paper proposes a critical bibliographic analysis of more recent scientific works. Moreover, by means of a numerical model of an existing single-family apartment, placed in the Mediterranean climate zone, a building envelope refurbishment with a living wall is carried out. A parametric analysis provides evidence for the application of different plants’ types and insulation materials. The results are analyzed considering the energy needs, the thermo-hygrometric comfort, and the outdoor surface temperature variation of the building envelope, emphasizing that a multi-criteria design approach is needed for green vertical systems. The paper provides data and an approach useful for designers and researchers in the evaluation and optimization of the performance of greening systems.

Metal–organic frameworks (MOFs) could be utilized for a wide range of applications such as sorption, catalysis, chromatography, energy storage, sensors, drug delivery, and nonlinear optics. However, to date, there are very few examples of MOFs exploited on a commercial scale. Nevertheless, progress in MOF-related research is currently paving the way to new industrial opportunities, fostering applications and processes interconnecting fundamental chemistry with engineering and relevant sectors. Yet, the fabrication of porous MOF materials within resistant structures is a key challenge impeding their wide commercial use for processes such as adsorptive separation. In fact, the integration of nano-scale MOF crystallic structures into bulk components that can maintain the desired characteristics, i.e., size, shape, and mechanical stability, is a prerequisite for their wide practical use in many applications. At the same time, it requires sophisticated shaping techniques that can structure nano/micro-crystalline fine powders of MOFs into diverse types of macroscopic bodies such as monoliths. Under this framework, this review aims to bridge the gap between research advances and industrial necessities for fostering MOF applications into real life. Therefore, it critically explores recent advances in the shaping and production of MOF macro structures with regard to the binding materials that have received little attention to date, but have the potential to give new perspectives in the industrial applicability of MOFs. Moreover, it proposes future paths that can be adopted from both academy and industry and can further boost MOF exploitation.

The coronavirus disease 2019 (COVID-19), which is mainly transmitted through droplets without overlooking other sources of transmission, rendered attention on the air quality in indoor areas and more specifically in healthcare settings. The improvement of indoor air quality (IAQ) is ensured by frequent changes of the air that must be carried out in healthcare areas and with assistance from special devices that undertake the filtration of the air and its purification through special filters and lamps. In this research, the performance of air purifiers is assessed in terms of the limitation of PM_2.5, PM₁₀, VOCs and CO₂ in a postgraduate clinic of the Dentistry School of the National and Kapodistrian University of Athens in parallel with mechanical ventilation. Our findings indicate that the use of mechanical ventilation plays a key role on the results, retaining good IAQ levels within the clinic and that air purifiers show a positive impact on IAQ by mainly reducing the levels of PM_2.5 and secondly of TVOC.

Building materials, due to their mass and energy-consuming production processes, drastically increase the embodied energy of construction. This study assesses circularity processes for the construction industry with a life cycle assessment (LCA) of a case study located in a large cosmopolitan city. The research concludes that a significant decrease in environmental impacts results from a shift to recycled materials in the construction phase, as well as from changing the landfill disposal method to recycling. In particular, it was found that the use of recycled building materials (such as recycled cement, metal, concrete, or glass) during the construction phase and recycling disposal methods lead to an overall decrease of impact up to 65%. This work also underlines the importance of circularity in renewable energy production systems. In both wind and solar systems, most of the environmental impact caused during the production phase are paid back during the second year of their life due to the energy gains of the renewable energy system. However, the recovery of metal depletion requires 667 years. This result provides evidence of the emerging need for integrating circular processes regarding recycling and reusing materials in construction and also in the energy-generating sector.